US4356278A
Expired / Lapsed
US
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Heat-hardenable resins suitable for cathodic deposition
Assignee: Allnex Austria GmbH
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Filing: 1978-10-23
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Granted: 1982-10-26
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Expires: 1998-10-23
Abstract
Abstract Heat-hardenable synthetic resins which are water soluble upon partial or total neutralization comprising the reaction products of epoxy groups containing unsaturated diene polymers and amine compounds, graft polymerized with alpha, beta-ethylenically unsaturated monomers which are free from epoxy reactive groups, the homopolymers of the monomers having a glass transition temperature of over 320° K. A process of preparing the heat-hardenable resins is also described. The synthetic resins can be employed as binders for cathodically depositable aqueous coating compositions to provide coatings which will cure at relatively low temperatures and relatively short curing times to provide smooth and hard films having good resistance to water, chemicals, and corrosion; and which adhere well to the coated surface.
Inventors
- 👤 Wolfgang Daimer
- 👤 Heiner Verdino
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 10:34
CPC Classifications
C; C09; C09D; C09D163/00; C09D163/08; C08; C08F; C08F279/00; C08F279/02; C09D151/00; C09D151/04; C09D5/00; C09D5/44; C09D5/4403
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
67 words
Aqueous composition suitable for cathodic deposition in an electrodeposition system comprising the neutralized product of the reaction product of an unsaturated diene polymer carrying at least one 1,2-epoxy group per molecule, an amine compound containing amine functionality reactive with an epoxy group, and an alpha,beta-ethylenically unsaturated monomer free from epoxy reactive groups; the homopolymers of said monomer having a glass transition temperature of above about 320° K.
Claim 2
Dependent Claim
67 words
Aqueous composition suitable for cathodic deposition in an electrodeposition system comprising the neutralized product of the reaction product of an unsaturated diene polymer carrying at least one 1,2-epoxy group per molecule, an amine compound containing amine functionality reactive with an epoxy group, and an alpha,beta-ethylenically unsaturated monomer free from epoxy reactive groups; the homopolymers of said monomer having a glass transition temperature of above about 320° K.
Claim 3
Dependent Claim
31 words
The aqueous coating composition of claim 1 wherein the diene polymer has an iodine number of between about 300 and 470, and an oxirane oxygen content of 1 to 12 percent.
Claim 4
Dependent Claim
17 words
The aqueous coating composition of claim 2 wherein said reaction product contains moieties of esterified monocarboxylic acids.
Claim 5
Dependent Claim
34 words
The aqueous coating composition of claim 1 wherein the diene polymer is a polymer of a monomer selected from the group consisting of butadiene, pentadiene, and isoprene, and has a molecular weight below 5000.
Claim 6
Dependent Claim
15 words
The aqueous coating composition of claim 1 wherein the amine compound is an aliphatic amine.
Claim 7
Dependent Claim
14 words
The aqueous coating composition of claim 1 wherein the amine compound is an alkanolamine.
Claim 8
Dependent Claim
31 words
The aqueous coating composition of claim 1 wherein the amine compound is a polyamine and the primary and secondary amine functionality reactive with oxirane groups is not substantially more than 2.
Claim 9
Dependent Claim
14 words
The aqueous coating composition of claim 7 wherein the polyamine includes tertiary amine groups.
Claim 10
Dependent Claim
30 words
The aqueous coating composition of claim 1 wherein said monomer is a member of the group consisting of (meth)acrylnitrile, methylmethacrylate, isopropylmethacrylate, tert.butylmethacrylate, styrene, vinyltoluol, indene, and vinylcarbazol, and mixtures thereof.
Claim 11
Dependent Claim
121 words
The process for producing heat-hardenable synthetic resins comprising reacting at a temperature of from about 80° to 220° C. an alpha,beta-ethylenically unsaturated monomer free from epoxy reactive groups, the homopolymers of said monomer having a glass transition temperature of above about 320° K.; a diene polymer containing at least one 1,2-epoxy group and an amine compound containing amine functionality reactive with an epoxy group, said amine functionality reactive with an epoxy group being not substantially more than two and said reaction product containing basic functionality neutralizable with an inorganic or organic acid to provide an aqueous solution of said resin, and thereafter forming an aqueous solution of said heat-hardenable synthetic resin by neutralizing said resin with an inorganic or organic acid.
Claim 12
Dependent Claim
121 words
The process for producing heat-hardenable synthetic resins comprising reacting at a temperature of from about 80° to 220° C. an alpha,beta-ethylenically unsaturated monomer free from epoxy reactive groups, the homopolymers of said monomer having a glass transition temperature of above about 320° K.; a diene polymer containing at least one 1,2-epoxy group and an amine compound containing amine functionality reactive with an epoxy group, said amine functionality reactive with an epoxy group being not substantially more than two and said reaction product containing basic functionality neutralizable with an inorganic or organic acid to provide an aqueous solution of said resin, and thereafter forming an aqueous solution of said heat-hardenable synthetic resin by neutralizing said resin with an inorganic or organic acid.
References Cited (Backward Citations)
US3455965A
Cited
US3957903A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-10-25 | 1986-04-26 | 1986-10-26 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-10-25 | 1990-04-26 | 1990-10-26 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-10-25 | 1994-04-26 | 1994-10-26 | $7700.00 | Window Closed / Lapsed |