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US4355133A
Expired / Lapsed
US
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Polyester of 6-hydroxy-2-naphthoic acid, 4-hydroxy benzoic acid, 1,4-cyclohexanedicarboxylic acid, and aromatic diol capable of readily undergoing melt processing to form articles possessing high impact properties
Assignee: Celanese Corp
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Filing: 1981-07-27
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Granted: 1982-10-19
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Expires: 2001-07-27
Abstract
Abstract A novel polyester is provided which has been found to exhibit an optically anisotropic melt phase which enables it readily to undergo melt processing to form quality molded articles possessing unusually high impact properties, etc. The polyester of the present invention contains recurring 6-oxy-2-naphthoyl, 4-oxybenzoyl, and 1,4-dicarboxycyclohexane moieties in addition to a moiety derived from an aromatic diol in the proportions indicated. The hydrogen atoms present upon the aromatic rings optionally may be at least partially substituted (as described). The polyester is capable of forming the desired anisotropic melt at a temperature below approximately 350° C., and in a particularly preferred embodiment at a temperature below approximately 320° C.
Inventors
- 👤 Anthony J. East
- 👤 Gordon W. Calundann
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 21:53
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/02; C08G63/60; C08G63/605
Claims Analysis
Total Claims: 25
Claim 1
Independent Claim
167 words
A melt processable polyester capable of forming an anisotropic melt phase at a temperature below approximately 350° C. consisting essentially of the recurring moieties I, II, III, and IV which optionally may include substitution of at least some of the hydrogen atoms present upon an aromatic ring wherein: ##STR9## wherein at least approximately 90 percent of said III units are in the trans-configuration, and IV is a dioxyaryl moiety of the formula --O--Ar--O-- where Ar is a divalent radical comprising at least one aromatic ring, with said optional substitution if present being selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, a phenyl group, and mixtures of the foregoing, and wherein said polyester comprises approximately 10 to 70 mole percent of moiety I, approximately 10 to 60 mole percent of moiety II, approximately 10 to 45 mole percent of moiety III, and approximately 10 to 45 mole percent of moiety IV.
Claim 2
Dependent Claim
167 words
A melt processable polyester capable of forming an anisotropic melt phase at a temperature below approximately 350° C. consisting essentially of the recurring moieties I, II, III, and IV which optionally may include substitution of at least some of the hydrogen atoms present upon an aromatic ring wherein: ##STR9## wherein at least approximately 90 percent of said III units are in the trans-configuration, and IV is a dioxyaryl moiety of the formula --O--Ar--O-- where Ar is a divalent radical comprising at least one aromatic ring, with said optional substitution if present being selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, a phenyl group, and mixtures of the foregoing, and wherein said polyester comprises approximately 10 to 70 mole percent of moiety I, approximately 10 to 60 mole percent of moiety II, approximately 10 to 45 mole percent of moiety III, and approximately 10 to 45 mole percent of moiety IV.
Claim 3
Dependent Claim
24 words
A melt processable polyester according to claim 1 which is capable of forming an anisotropic melt phase at a temperature below approximately 320° C.
Claim 4
Dependent Claim
27 words
A melt processable polyester according to claim 1 which is capable of undergoing melt processing at a temperature in the range of approximately 230° to 320° C.
Claim 5
Dependent Claim
17 words
A melt processable polyester according to claim 1 wherein each moiety is substantially free of ring substitution.
Claim 6
Dependent Claim
16 words
A melt processable polyester according to claim 1 wherein said dioxyaryl moiety IV is symmetrically disposed.
Claim 7
Dependent Claim
26 words
A melt processable polyester according to claim 1 wherein said dioxyaryl moiety IV is selected from the group consisting of: ##STR10## and mixtures of the foregoing.
Claim 8
Dependent Claim
15 words
A melt processable polyester according to claim 1 wherein said dioxyaryl moiety IV is ##STR11##
Claim 9
Dependent Claim
34 words
A melt processable polyester according to claim 1 which exhibits an inherent viscosity of at least approximately 1.0 dl./g. when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 10
Dependent Claim
34 words
A melt processable polyester according to claim 8 which exhibits an inherent viscosity of at least approximately 2.0 dl./g. when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 11
Dependent Claim
37 words
A melt processable polyester according to claim 8 which exhibits an inherent viscosity within the range of approximately 3.0 to 9.0 dl./g. when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 12
Dependent Claim
11 words
A molded article comprising the melt processable polyester of claim 1.
Claim 13
Dependent Claim
27 words
A molding compound comprising the melt processable polyester of claim 1 which incorporates approximately 1 to 60 percent by weight of a solid filler and/or reinforcing agent.
Claim 14
Dependent Claim
167 words
A melt processable polyester capable of forming an anisotropic melt phase at a temperature below approximately 320° C. consisting essentially of the recurring moieties I, II, III, and IV which optionally may include substitution of at least some of the hydrogen atoms present upon an aromatic wherein: ##STR12## wherein at least approximately 95 percent of said III units are in the trans-configuration, and IV is a symmetrical dioxyaryl moiety of the formula --O--Ar--O-- where Ar is a divalent radical comprising at least one aromatic ring, with said optional substitution if present being selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, a phenyl group, and mixtures of the foregoing, and wherein said polyester comprises approximately 15 to 30 mole percent of moiety I, approximately 20 to 40 mole percent of moiety II, approximately 20 to 30 mole percent of moiety III, and approximately 20 to 30 mole percent of moiety IV.
Claim 15
Dependent Claim
167 words
A melt processable polyester capable of forming an anisotropic melt phase at a temperature below approximately 320° C. consisting essentially of the recurring moieties I, II, III, and IV which optionally may include substitution of at least some of the hydrogen atoms present upon an aromatic wherein: ##STR12## wherein at least approximately 95 percent of said III units are in the trans-configuration, and IV is a symmetrical dioxyaryl moiety of the formula --O--Ar--O-- where Ar is a divalent radical comprising at least one aromatic ring, with said optional substitution if present being selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, a phenyl group, and mixtures of the foregoing, and wherein said polyester comprises approximately 15 to 30 mole percent of moiety I, approximately 20 to 40 mole percent of moiety II, approximately 20 to 30 mole percent of moiety III, and approximately 20 to 30 mole percent of moiety IV.
Claim 16
Dependent Claim
27 words
A melt processable polyester according to claim 13 which is capable of undergoing melt processing at a temperature in the range of approximately 230° to 320° C.
Claim 17
Dependent Claim
17 words
A melt processable polyester according to claim 13 wherein each moiety is substantially free of ring substitution.
Claim 18
Dependent Claim
26 words
A melt processable polyester according to claim 13 wherein said dioxyaryl moiety IV is selected from the group consisting of: ##STR13## and mixtures of the foregoing.
Claim 19
Dependent Claim
15 words
A melt processable polyester according to claim 13 wherein said dioxyaryl moiety IV is ##STR14##
Claim 20
Dependent Claim
49 words
A melt processable polyester according to claim 17 which comprises approximately 20 mole percent of moiety I, approximately 30 mole percent of moiety II, approximately 25 mole percent of moiety III, and approximately 25 mole percent of moiety IV, and wherein each moiety is substantially free of ring substitution.
Claim 21
Dependent Claim
34 words
A melt processable polyester according to claim 13 which exhibits an inherent viscosity of at least approximately 1.0 dl./g. when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 22
Dependent Claim
34 words
A melt processable polyester according to claim 13 which exhibits an inherent viscosity of at least approximately 2.0 dl./g. when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 23
Dependent Claim
37 words
A melt processable polyester according to claim 13 which exhibits an inherent viscosity within the range of approximately 3.0 to 9.0 dl./g. when dissolved in a concentration of 0.1 percent by weight in pentafluorophenol at 60° C.
Claim 24
Dependent Claim
11 words
A molded article comprising the melt processable polyester of claim 13.
Claim 25
Dependent Claim
27 words
A molding compound comprising the melt processable polyester of claim 13 which incorporates approximately 1 to 60 percent by weight of a solid filler and/or reinforcing agent.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-10-18 | 1986-04-19 | 1986-10-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-10-18 | 1990-04-19 | 1990-10-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-10-18 | 1994-04-19 | 1994-10-19 | $7700.00 | Window Closed / Lapsed |