US4353997A
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Compositions based on water-curable, silane modified copolymers of alkylene-alkyl acrylates
Assignee: Union Carbide Corp
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Filing: 1981-04-02
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Granted: 1982-10-12
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Expires: 2001-04-02
Abstract
Abstract The disclosure of this application is directed to a water-curable composition comprising a water-curable, silane modified alkylene-alkyl acrylate copolymer, a mineral filler and a halogenated flame retardant additive. These compositions are useful as extrudates about wires and cables providing insulation or jacketing thereon characterized by resistance to deformation and by flame retardancy.
Inventors
- 👤 Michael J. Keogh
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 20:19
CPC Classifications
H; H01; H01B; H01B3/00; H01B3/18; H01B3/30; H01B3/46; C; C08; C08F; C08F8/00; C08F8/42; C08G; C08G77/00; C08G77/60; C08G81/00; C08G81/02; C08G81/024; C08K; C08K13/00; C08K13/02; C08K5/00; C08K5/16; C08K5/34; C08K5/3412; C08K5/3415; C08K5/3417; C08L; C08L83/00; C08L83/16; H01B3/44
Claims Analysis
Total Claims: 31
Claim 1
Independent Claim
71 words
A water-curable composition comprising a water-curable, silane modified alkylene-alkyl acrylate copolymer, a mineral filler and a halogenated flame retardant additive wherein the mineral filler is present in an amount of about one to 100 percent by weight based on the weight of said copolymer and said halogenated flame retardant additive is present in an amount of about one to about 100 percent by weight based on the weight of said copolymer.
Claim 2
Dependent Claim
71 words
A water-curable composition comprising a water-curable, silane modified alkylene-alkyl acrylate copolymer, a mineral filler and a halogenated flame retardant additive wherein the mineral filler is present in an amount of about one to 100 percent by weight based on the weight of said copolymer and said halogenated flame retardant additive is present in an amount of about one to about 100 percent by weight based on the weight of said copolymer.
Claim 3
Dependent Claim
47 words
A water-curable composition as defined in claim 1 wherein the mineral filler is present in an amount of about 20 to about 60 percent by weight and wherein the halogenated flame retardant additive is present in an amount of about 10 to about 60 percent by weight.
Claim 4
Dependent Claim
14 words
A water-curable composition as defined in claim 1 wherein the mineral filler is talc.
Claim 5
Dependent Claim
18 words
A water-curable composition as defined in claim 3 wherein the talc is coated with a compatible hydrophobic material.
Claim 6
Dependent Claim
20 words
A water-curable composition as defined in claim 4 wherein the hydrophobic material is a metal salt of a fatty acid.
Claim 7
Dependent Claim
22 words
A water-curable composition as defined in claim 5 wherein the metal salt of a fatty acid is calcium stearate or zinc stearate.
Claim 8
Dependent Claim
23 words
A water-curable composition as defined in claim 1 wherein the mineral filler is an oxide, hydroxide, carbonate or sulfate of magnesium or calcium.
Claim 9
Dependent Claim
20 words
A water-curable composition as defined in claim 7 wherein the said mineral filler is coated with a compatible hydrophobic material.
Claim 10
Dependent Claim
20 words
A water-curable composition as defined in claim 8 wherein the hydrophobic material is a metal salt of a fatty acid.
Claim 11
Dependent Claim
18 words
A water-curable composition as defined in claim 9 wherein the hydrophobic material is calcium stearate or zinc stearate.
Claim 12
Dependent Claim
18 words
A water-curable composition as defined in claim 1 wherein the alkylene-alkyl acrylate copolymer is an ethylene-ethyl acrylate copolymer.
Claim 13
Dependent Claim
19 words
A water-curable composition as defined in claim 1 wherein the alkylene-alkyl acrylate copolymer is an ethylene-ethyl acrylate-t-butyl acrylate copolymer.
Claim 14
Dependent Claim
15 words
A water-curable composition as defined in claim 1 wherein the silane is derived from acetooxyethyltrimethoxysilane.
Claim 15
Dependent Claim
16 words
A water-curable composition as defined in claim 1 wherein the halogenated flame retardant additive is decabromodiphenyloxide.
Claim 16
Dependent Claim
17 words
A water-curable composition as defined in claim 1 wherein the halogenated flame retardant additive is ethylene bis-(tetrabromophthalimide).
Claim 17
Dependent Claim
19 words
A water-curable composition as defined in claim 1 wherein the halogenated flame retardant additive is an aromatic bromine compound.
Claim 18
Dependent Claim
31 words
A water-curable composition comprising a water-curable, silane modified ethylene-ethyl acrylate copolymer, talc, as a mineral filler, and a halogenated flame retardant additive, wherein the amounts are as defined in claim 1.
Claim 19
Dependent Claim
40 words
A water-curable composition comprising a water-curable, silane modified ethylene-ethyl acrylate copolymer, an oxide, hydroxide, carbonate or sulfate of magnesium or calcium, as a mineral filler, and a halogenated flame retardant additive wherein the amounts are as defined in claim 1.
Claim 20
Dependent Claim
15 words
A water-curable composition as defined in claim 1 containing calcium carbonate as a mineral filler.
Claim 21
Dependent Claim
10 words
The crosslinked product of the composition defined in claim 1.
Claim 22
Dependent Claim
22 words
A wire or cable having as a coating thereon the composition or the crosslinked product of the composition defined in claim 1.
Claim 23
Dependent Claim
27 words
A water-curable composition as defined in claim 1 wherein the mineral filler is a mixture of talc and an oxide, hydroxide, carbonate, sulfate of magnesium or calcium.
Claim 24
Dependent Claim
16 words
A water-curable composition as defined in claim 22 wherein the alkylenealkylacrylate copolymer is an ethylene-ethylacrylate copolymer.
Claim 25
Dependent Claim
10 words
A molded article produced from the composition of claim 1.
Claim 26
Dependent Claim
20 words
A water-curable composition as defined in claim 1 wherein the mineral filler is a mixture of talc and antimony oxide.
Claim 27
Dependent Claim
30 words
A water-curable composition as defined in claim 1 wherein the mineral filler is a mixture of antimony oxide and an oxide, hydroxide, carbonate or sulfate of a magnesium or calcium.
Claim 28
Dependent Claim
30 words
A water-curable composition as defined in claim 1 wherein the mineral filler is a mixture of talc, antimony trioxide and an oxide, hydroxide, carbonate or sulfate of magnesium or calcium.
Claim 29
Dependent Claim
251 words
A water-curable composition comprising a water-curable silane modified alkylene-alkyl acrylate copolymer containing: alpha olefin units having the formula; ##STR17## wherein A is hydrogen or an alkyl radical having one to 16 carbon atoms, these alpha olefin units being present in the copolymer to the extent of at least 50 percent by weight; at least 0.1 percent by weight of polymerized units containing the radical having the formula: ##STR18## wherein: B is an oxygen atom, a sulfur atom or ##STR19## C 1 is a carbon atom in the main polymer chain, R is hydrogen or a monovalent hydrocarbon radical having one to 18 carbon atoms; Q is a divalent hydrocarbon radical having 1 to 18 carbon atoms and is bonded to --B-- and --D-- through carbon atoms; D is a silicon containing radical having the formula: ##STR20## wherein V is hydrogen, a monovalent hydrocarbon radical of one to 18 carbon atoms or a hydrolyzable group; and Z is a hydrolyzable group; and polymerized units having the formula: ##STR21## wherein C 1 is a carbon atom in the main polymer chain and W is an alkoxy radical having one to 18 carbon atoms, a mineral filler and a halogenated flame retardant additive wherein the mineral filler is present in an amount of about one to 100 percent by weight based on the weight of said copolymer and said halogenated flame retardant additive is present in an amount of about one to about 100 percent by weight based on the weight of said copolymer.
Claim 30
Dependent Claim
251 words
A water-curable composition comprising a water-curable silane modified alkylene-alkyl acrylate copolymer containing: alpha olefin units having the formula; ##STR17## wherein A is hydrogen or an alkyl radical having one to 16 carbon atoms, these alpha olefin units being present in the copolymer to the extent of at least 50 percent by weight; at least 0.1 percent by weight of polymerized units containing the radical having the formula: ##STR18## wherein: B is an oxygen atom, a sulfur atom or ##STR19## C 1 is a carbon atom in the main polymer chain, R is hydrogen or a monovalent hydrocarbon radical having one to 18 carbon atoms; Q is a divalent hydrocarbon radical having 1 to 18 carbon atoms and is bonded to --B-- and --D-- through carbon atoms; D is a silicon containing radical having the formula: ##STR20## wherein V is hydrogen, a monovalent hydrocarbon radical of one to 18 carbon atoms or a hydrolyzable group; and Z is a hydrolyzable group; and polymerized units having the formula: ##STR21## wherein C 1 is a carbon atom in the main polymer chain and W is an alkoxy radical having one to 18 carbon atoms, a mineral filler and a halogenated flame retardant additive wherein the mineral filler is present in an amount of about one to 100 percent by weight based on the weight of said copolymer and said halogenated flame retardant additive is present in an amount of about one to about 100 percent by weight based on the weight of said copolymer.
Claim 31
Dependent Claim
52 words
A composition as defined in claim 28 containing a water-curable, silane modified copolymer as defined by formula wherein B is oxygen, Q is --CH 2 --CH 2 -- or --CH 2 --CH 2 --CH 2 --, Z and V are methoxy, ethoxy or butoxy and A is an alkyl radical or hydrogen.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-10-11 | 1986-04-12 | 1986-10-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-10-11 | 1990-04-12 | 1990-10-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-10-11 | 1994-04-12 | 1994-10-12 | $7700.00 | Window Closed / Lapsed |