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US4353972A Expired / Lapsed US ⏱️ 0.0 years remaining

Light-sensitive photographic material comprising polymeric mordant layer

Assignee: Agfa Gevaert AG
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Filing: 1980-10-14
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Granted: 1982-10-12
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Expires: 2000-10-14
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Abstract

Abstract As mordant for mordanting diffusing anionic dyes in image receiving layers of photographic dye diffusion materials the invention makes use of addition polymers having at least 10 mole % of recurring structural units of formula I ##STR1## in which Q represents nitrogen or phosphorus; R 1 , R 2 , R 3 each represents a carbocyclic or alkyl group or two of these substituents complete a 5- or 6-membered heterocyclic ring R 4 represents hydrogen or alkyl, X⊖ is an anion.

Inventors

  • 👤 Gunter Helling
  • 👤 Kaspar Wingender
  • 👤 Wolfgang Himmelmann
  • 👤 Manfred Beck

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 07:36
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03C1/825; G03C1/835; G03C8/00; G03C8/42; G03C8/52; G03C8/56

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 140 words
A photographic material comprising a layer support having coated thereon at least one image-receiving layer which contains a polymeric mordant for acidic dyes, in which the polymeric mordant is a polymer obtained by addition polymerisation of a mixture of monomers containing at least 10 mole % of a monomer that on addition polymerisation provides recurring structural units of formula I in which Q is a nitrogen or phosphorus atom; R 1 , R 2 and R 3 are the same or different and represent alkyl radicals of 1 to 12 carbon atoms or carbocyclic radicals selected from the group consisting of cycloalkyl, aralkyl and aryl radicals or two of the substituents R 1 , R 2 and R 3 together with the Q complete a 5- or 6-membered heterocyclic ring. R 4 represents hydrogen or methyl X.sup.⊖ represents an anion.
Claim 2
Dependent Claim 140 words
A photographic material comprising a layer support having coated thereon at least one image-receiving layer which contains a polymeric mordant for acidic dyes, in which the polymeric mordant is a polymer obtained by addition polymerisation of a mixture of monomers containing at least 10 mole % of a monomer that on addition polymerisation provides recurring structural units of formula I in which Q is a nitrogen or phosphorus atom; R 1 , R 2 and R 3 are the same or different and represent alkyl radicals of 1 to 12 carbon atoms or carbocyclic radicals selected from the group consisting of cycloalkyl, aralkyl and aryl radicals or two of the substituents R 1 , R 2 and R 3 together with the Q complete a 5- or 6-membered heterocyclic ring. R 4 represents hydrogen or methyl X.sup.⊖ represents an anion.
Claim 3
Dependent Claim 29 words
A photographic material as claimed in claim 1 in which R 1 , R 2 and R 3 are the same or different and represent methyl, ethyl or benzyl.
Claim 4
Dependent Claim 30 words
A photographic material as claimed in claim 1 in which the image-receiving layer which contains the polymeric mordant contains also mordanted therein one or more acidic dyes in image distribution.
Claim 5
Dependent Claim 39 words
A photographic material as claimed in claim 1 having in contact with the image-receiving layer a light sensitive recording element comprising at least one light sensitive silver halide emulsion layer and associated thereto in uniform distribution a color-providing compound.
Claim 6
Dependent Claim 211 words
A photographic material comprising a layer support and at least one image-receiving layer containing as a polymeric mordant for acid dyes obtained by addition polymerisation of a mixture of monomers and corresponding to the following formula (--A--).sub.x (--M--).sub.y (--V--).sub.z in which A is ##STR8## in which Q 1 is a nitrogen or phosphorus atom; R 1 , R 2 and R 3 are the same or different and represent alkyl radicals of 1 to 12 carbon atoms or carbocyclic radicals selected from the group consisting of cycloalkyl, aralkyl and aryl radicals or two of the substituents R 1 , R 2 and R 3 together represent a group necessary for completing a 5- or 6-membered heterocyclic ring selected from the group consisting of pyrrolidine, piperidine and morpholine rings; R 4 represents hydrogen or methyl: V represents the residue of a polymerised monomer containing at least two polymerisable ethylenically unsaturated groups; M represents the residue of a polymerised monomer containing one polymerisable ethylenically unsaturated group; x, y and z represent the figures indicating the proportions of the monomers in the polymer, such that x stands for 10 to 99 mole % y stands for 0 to 90 mole % z stands for 0 to 5 mole %; X - represents an anion.
Claim 7
Dependent Claim 211 words
A photographic material comprising a layer support and at least one image-receiving layer containing as a polymeric mordant for acid dyes obtained by addition polymerisation of a mixture of monomers and corresponding to the following formula (--A--).sub.x (--M--).sub.y (--V--).sub.z in which A is ##STR8## in which Q 1 is a nitrogen or phosphorus atom; R 1 , R 2 and R 3 are the same or different and represent alkyl radicals of 1 to 12 carbon atoms or carbocyclic radicals selected from the group consisting of cycloalkyl, aralkyl and aryl radicals or two of the substituents R 1 , R 2 and R 3 together represent a group necessary for completing a 5- or 6-membered heterocyclic ring selected from the group consisting of pyrrolidine, piperidine and morpholine rings; R 4 represents hydrogen or methyl: V represents the residue of a polymerised monomer containing at least two polymerisable ethylenically unsaturated groups; M represents the residue of a polymerised monomer containing one polymerisable ethylenically unsaturated group; x, y and z represent the figures indicating the proportions of the monomers in the polymer, such that x stands for 10 to 99 mole % y stands for 0 to 90 mole % z stands for 0 to 5 mole %; X - represents an anion.
Claim 8
Dependent Claim 119 words
A photographic material as claimed in claim 5 in which the mordant is a polymer obtained by addition polymerisation and in which V is the radical of a monomer, polymerisable by addition polymerisation, having at least two ethylenically unsaturated radicals of the following formula III ##STR9## in which n represents an integer greater than 1, preferably 2, 3 or 4: R 5 represents a di- or polyvalent organic radical which is composed of alkylene groups, arylene groups, aralkylene groups, cycloalkylene groups, a polyvalent organic radical, composed of the corresponding polyvalent analogues thereof, ester groups, sulfonyl ester groups, amide groups, sulfonamide groups, ether oxygen atoms and thioether sulfur atoms, and R 6 represents a hydrogen atom or a methyl radical.

References Cited (Backward Citations)

US3709690A Cited
DE2551786C3 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-10-11 1986-04-12 1986-10-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-10-11 1990-04-12 1990-10-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-10-11 1994-04-12 1994-10-12 $7700.00 Window Closed / Lapsed

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