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US4353971A
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Squarylium dye and diane blue dye charge generating layer mixture for electrophotographic light sensitive elements and processes
Assignee: Pitney Bowes Inc
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Filing: 1980-12-08
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Granted: 1982-10-12
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Expires: 2000-12-08
Abstract
Abstract Dual layer organic photoconductive elements which are stable and sensitive over a broad range of the spectrum, including near the infrared band, and the process for preparing same. The charge-generating layer comprises a mixture of a charge-generating dye, such as a diane blue dye, and a squarylium dye as a near-infrared sensitizer.
Inventors
- 👤 Mike S. H. Chang
- 👤 Peter G. Edelman
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 15:42
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/06; G03G5/0601; G03G5/0618; C; C09; C09B; C09B57/00; C09B57/007; G03G5/0609; G03G5/0611; G03G5/0622; G03G5/0644; G03G5/0661; G03G5/0664; G03G5/0675; G03G5/0679
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
118 words
A photoconductive element which is extremely sensitive to exposure to light rays in the near-infrared region of the spectrum, said element comprising an electroconductive support, a charge-generating layer comprising a mixture of at least one squarylium dye and at least one diane blue dye in which the weight percent of squarylium dye relating to the total weight of said dye mixture ranges between about 0.05% and 50.0%, said squarylium dye being selected from the group consisting of: ##STR3## in which R is a methyl or ethyl radical, and a charge transport layer comprising a conventional organic chemical capable of transporting electrical charges generated by said charge generating layer in areas of said element exposed to said light rays.
Claim 2
Dependent Claim
118 words
A photoconductive element which is extremely sensitive to exposure to light rays in the near-infrared region of the spectrum, said element comprising an electroconductive support, a charge-generating layer comprising a mixture of at least one squarylium dye and at least one diane blue dye in which the weight percent of squarylium dye relating to the total weight of said dye mixture ranges between about 0.05% and 50.0%, said squarylium dye being selected from the group consisting of: ##STR3## in which R is a methyl or ethyl radical, and a charge transport layer comprising a conventional organic chemical capable of transporting electrical charges generated by said charge generating layer in areas of said element exposed to said light rays.
Claim 3
Dependent Claim
16 words
A photoconductive element according to claim 1 in which said diane blue dye comprises Chlorodiane Blue.
Claim 4
Dependent Claim
25 words
A photoconductive element according to claim 2 in which said weight percent of squarylium dye ranges between about 1% and 5% of said dye mixture.
Claim 5
Dependent Claim
17 words
A photoconductive element according to claim 1 in which said electroconductive support comprises a metallized plastic film.
Claim 6
Dependent Claim
26 words
A photoconductive element according to claim 1 in which said electroconductive support carries an adhesive resinous layer which bonds said charge-generating layer to said electroconductive support.
Claim 7
Dependent Claim
27 words
A photoconductive element according to claim 1 in which said organic chemical of the charge-transport layer is selected from the group consisting of triaryl pyrazolines and hydrazones.
Claim 8
Dependent Claim
127 words
Process for producing a photoconductive element which is extremely sensitive to light rays in the near-infrared region of the spectrum, said element comprising an electroconductive support, a charge-generating layer and a charge transport layer comprising a conventional organic chemical capable of transporting electrical charges conducted by said charge generating layer in areas of said element exposed to said light rays, comprising the step of producing said charge generating layer by mixing together a squarylium dye and a diane blue dye in a coating composition in which the weight percent of squarylium dye relative to the total weight of said dye mixture ranges between about 0.05% and 50.0%, said squarylium dye being selected from the group consisting of: ##STR4## and applying said composition as a uniform thin layer.
Claim 9
Dependent Claim
127 words
Process for producing a photoconductive element which is extremely sensitive to light rays in the near-infrared region of the spectrum, said element comprising an electroconductive support, a charge-generating layer and a charge transport layer comprising a conventional organic chemical capable of transporting electrical charges conducted by said charge generating layer in areas of said element exposed to said light rays, comprising the step of producing said charge generating layer by mixing together a squarylium dye and a diane blue dye in a coating composition in which the weight percent of squarylium dye relative to the total weight of said dye mixture ranges between about 0.05% and 50.0%, said squarylium dye being selected from the group consisting of: ##STR4## and applying said composition as a uniform thin layer.
Claim 10
Dependent Claim
14 words
Process according to claim 7 in which said diane blue dye comprises Chlorodiane Blue.
Claim 11
Dependent Claim
23 words
Process according to claim 7 in which said weight percent of squarylium dye ranges between about 1% and 5% of said dye mixture.
Claim 12
Dependent Claim
35 words
Process according to claim 7 in which said coating composition comprises from about 1.0% to about 3.0% by weight of said dye mixture in a volatile vehicle which is evaporated to form said charge-generating layer.
Claim 13
Dependent Claim
35 words
Process according to claim 7 in which said dye mixture and volatile vehicle are ground to form a coating composition comprising a dispersion of dye particles having a maximum particle size of about 0.25 mil.
Claim 14
Dependent Claim
31 words
Process according to claim 7 which comprises coating said electroconductive support with a continuous bonding layer of adhesive resin and applying said charge-generating layer to the surface of said bonding layer.
References Cited (Backward Citations)
GB2032637A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-10-11 | 1986-04-12 | 1986-10-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-10-11 | 1990-04-12 | 1990-10-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-10-11 | 1994-04-12 | 1994-10-12 | $7700.00 | Window Closed / Lapsed |