Energy storage system for electric utility plant

Claim 3

A method as defined in claim 1, wherein the low pressure of the primary fluid is less than approximately 150 atm.

Claim 4

A method as defined in claim 1, wherein the high pressure of the primary fluid is at least approximately 20 atm.

Claim 5

A method as defined in claim 1, wherein the low pressure cavern has a volume of at least approximately 10 million cubic feet.

Claim 6

A method as defined in claim 1, wherein the high pressure cavern has a volume of at least approximately one million cubic feet.

Claim 7

A method as defined in claim 1, wherein the volume ratio of the respective high and low pressure caverns is at least 1:6.

Claim 8

A method as defined in claim 1, wherein the respective high and low pressure caverns comprise cavities in underground salt deposits.

Claim 9

A method as defined in claim 1, wherein the respective high and low pressure caverns comprise abandoned mines capable of being sealed to develop a substantially closed system.

Claim 10

A method as defined in claim 1, wherein said primary fluid includes an inert gas suitable for compression and expansion through the system.

Claim 11

A method as defined in claim 9, wherein the inert gas is selected from the group of N 2 , CO 2 , H 2 O and rare gases including He and Ar.

Claim 12

A method as defined in claim 1, wherein said fuel constituent is selected from the group consisting of combustible hydrocarbons, hydrogen and CO.

Claim 13

A method as defined in claim 1, wherein said stored, compressed primary fluid includes a liquid phase constituent capable of vaporization and cycling through the closed system.

Claim 14

A method as defined in claim 12, wherein the liquid phase constituent is selected from the group consisting of a. benzene, toluene or similar aromatic hydrocarbons, and b. cyclohexane or similar cyclic aliphatic hydrocarbons.

Claim 15

A method as defined in claim 1, wherein said expansion step employs a turbine/generator combination which is driven by the primary fluid.

Claim 16

A method as defined in claim 1, further comprising the step of generating said exothermic fuel constituent utilizing excess electrical output of said utility.

Claim 17

A method as defined in claim 15, wherein said generating step includes applying electrical output of said utility to an electrolysis device to produce hydrogen and oxygen as said exothermic fuel constituent.

Claim 18

A method as defined in claim 16, wherein said H 2 is introduced from the electrolysis device directly into said low pressure storage cavern during said low energy demand periods, said O 2 being separately stored for subsequent introduction as an exothermic fuel constituent in said reacting step.

Claim 19

A method as defined in claim 1, further comprising the step of separating exothermic fuel reaction product from the closed system.

Claim 20

A method as defined in claim 15, wherein the exothermic fuel constituent is generated by applying energy from the electrical output of the utility to drive reactants of a reversible chemical reaction to reaction product operable as an exothermic fuel in the reacting step of claim 1, said method including the additional steps of: a. introducing the reactants for reversible chemical reaction into the primary fluid prior to said reacting step of claim 1, b. applying energy from the electrical output of the utility to cause reaction of the reversible reactants to yield product operable as exothermic fuel constituent in combination with the primary fluid, c. compressing said primary fluid and fuel constituent combination to high pressures utilizing energy output produced by said utility during low consumer demand periods, d. storing said compressed primary fluid and fuel constituent combination in a high pressure underground storage cavern, e. transferring said compressed primary fluid and fuel constituent combination during peak power demand from said high pressure storage cavern to a reaction zone, f. reacting the exothermic fuel constituent (including the reversible reaction product of step b above) to form the reactants of the reversible chemical reaction within the compressed primary fluid to thereby generate a heated working fluid comprised of said primary fluid and any fuel reactants and products present, g. expanding said working fluid to produce an electrical output for supplementation of utility capacity, and h. returning at least the resulting expanded primary fluid and reversible reactants to said low pressure cavern.

Claim 21

A method as defined in claim 19, wherein said reversible chemical reaction comprises a reformation/methanation reaction ##EQU2## wherein the reactants comprise CH 4 +H 2 O and the reaction product includes CO+H 2 .

Claim 22

A method as defined in claim 20, including the following steps: a. introducing methane into the primary fluid within the low pressure cavern, b. transferring the primary fluid and methane to a heating zone, c. adding H 2 O to the methane/primary fluid combination, d. applying energy from the utility electrical output to develop heat in sufficient quantity to raise the temperature of the methane and H 2 O sufficient to support the following reaction: ##EQU3## e. compressing the reaction products of the previous step (CO and H 2 ) and transferring such products and primary fluid to the high pressure cavern for storage until use is required during peak energy demand, f. transferring said compressed primary fluid and reaction product during peak power demand from said high pressure storage cavern to a reaction zone, g. catalitically initiating reaction of the reaction product: CO+3H.sub.2 →CH.sub.4 +H.sub.2 O to generate a heated working fluid comprised of said primary fluid and any remaining reactants and reaction products from the previous step, h. expanding said working fluid to produce an electrical output for supplementation of utility capacity, and i. returning at least the resulting expanded primary fluid and methane to the low pressure cavern.

Claim 23

A method as defined in claim 19 wherein at least one of the reactants of the reversible chemical reaction is the primary fluid.