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US4351980A Expired / Lapsed US ⏱️ 0.0 years remaining

Removal of olefin from aliphatic hydrocarbon by treatment with active solid

Assignee: Phillips Petroleum Co
•
Filing: 1979-05-22
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Granted: 1982-09-28
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Expires: 1999-05-22
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Abstract

Abstract Hydrocarbon, suitable for use as propellant, is contacted with a solid effective to remove odor-forming impurity therefrom. Hydrocarbons include isobutene-containing stream also containing minor proportions of unsaturated hydrocarbon, e.g. ethylene, propylene, isobutylene, and 2-butenes. Solids include an acid montmorillonite clay, aluminum chloride, AlCl 3 ·HCl, AlCl 3 ·RCl, at least one metal of Groups I, II, and III of the periodic table, and supported H 3 PO 4 .

Inventors

  • 👤 Robert E. Reusser
  • 👤 Elizabeth A. Claytor
  • 👤 Brenton E. Jones

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 16:11
CPC Classifications
C; C09; C09K; C09K3/00; C09K3/30; C07; C07C; C07C7/00; C07C7/12; Y; Y02; Y02P; Y02P30/00; Y02P30/20; Y02P30/40

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 51 words
A process for the removal of a small amount of an odor-forming impurity of the order of a few parts per million from a low boiling isoparaffin hydrocarbon aerosol propellant for spray-type application which comprises contacting said hydrocarbon with a solid-acid treated montmorillonite clay catalyst effective to remove said odor-forming impurity.
Claim 2
Dependent Claim 51 words
A process for the removal of a small amount of an odor-forming impurity of the order of a few parts per million from a low boiling isoparaffin hydrocarbon aerosol propellant for spray-type application which comprises contacting said hydrocarbon with a solid-acid treated montmorillonite clay catalyst effective to remove said odor-forming impurity.
Claim 3
Dependent Claim 14 words
A process according to claim 1 wherein the low boiling isoparaffin hydrocarbon is isobutane.
Claim 4
Dependent Claim 47 words
A process according to claim 1 wherein said catalyst is a magnesium-substituted hydrogen montmorillonite having the approximate analysis ______________________________________ SiO.sub.2 71.2% Al.sub.2 O.sub.3 16.5% MgO 3.2% Fe.sub.2 O.sub.3 3.6% CaO 2.6% SO.sub.3 1.3% K.sub.2 O + Na.sub.2 O 1.0% TiO.sub.2 0.6% Acidity 5.0-8.0 mg KOH/gm sample ______________________________________
Claim 5
Dependent Claim 26 words
A process according to claim 3 wherein the acidity of the clay is in the approximate range of from about 5 to about 8 milligrams KOH/gm.
Claim 6
Dependent Claim 30 words
A process according to claim 1 wherein the hydrocarbon is a low-boiling hydrocarbon containing a minor amount of at least one of the following: olefin, sulfide, mercaptan and oxygenated compounds.
Claim 7
Dependent Claim 23 words
A process according to claim 1 wherein the odor-forming impurity is at least one of the following: ethylene, propylene, isobutylene, n-butenes, and pentenes.

References Cited (Backward Citations)

US2899377A Cited
US2564488A Cited
US2626967A Cited
US2842605A Cited
US2856392A Cited
US3409691A Cited
US3394200A Cited
US4028430A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-09-27 1986-03-29 1986-09-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-09-27 1990-03-29 1990-09-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-09-27 1994-03-29 1994-09-28 $7700.00 Window Closed / Lapsed

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