Process for the production of highly water-absorbing but less water-soluble hydrogels

Claim 2

A process for producing a highly water-absorbing but less water-soluble hydrogel comprising polymerizing at least one hydrophilic ethylenically unsaturated monomer selected from the group consisting of a carboxylic acid containing an ethylenically unsaturated group, a sulfonic acid containing an ethylenically unsaturated group, and derivatives thereof to form a homopolymer or copolymer of said hydrophilic ethylenically unsaturated monomer, or a mixture of at least 50% of said hydrophilic ethylenically unsaturated monomer and less than 50% of an ethylenically unsaturated monomer copolymerizable therewith other than said hydrophilic ethylenically unsaturated monomer, in the presence of 0.005% to 20% by weight based on the total weight of the ethylenically unsaturated monomers of at least one difunctional compound selected from the group consisting of compounds represented by the formula (1): ##STR13## wherein l is an integer of from 5 to 100.

Claim 3

A process for producing a highly water-absorbing but less water-soluble hydrogel comprising polymerizing at least one hydrophilic ethylenically unsaturated monomer selected from the group consisting of a carboxylic acid containing an ethylenically unsaturated group, a sulfonic acid containing an ethylenically unsaturated group, and their derivatives selected from a carboxylic acid base-containing monomer, an amido-group containing monomer or sodium styrenesulfonate to form a honopolymer or copolymer of said hydrophilic ethylenically unsaturated monomers, or a mixture of at least 50% of said hydrophilic ethylenically unsaturated monomer and less than 50% of ethylenically unsaturated monomer copolymerizable therewith other than said hydrophilic ethylenically unsaturated monomer, in the presence of 0.005% to 20% by weight based on the total weight of the ethylenically unsaturated monomers of at least one difunctional compound represented by formula (4): ##STR14## wherein R 3 is hydrogen or a methyl group, p is an integer of from 10 to 150, and q is 0 or an integer of from 1 to 150.

Claim 4

A process for producing a highly water-absorbing but less water-soluble hydrogel comprising polymerizing at least one hydrophilic ethylenically unsaturated monomer selected from the group consisting of a carboxylic acid containing an ethylenically unsaturated group, a sulfonic acid containing an ethylenically unsaturated group, and their derivatives selected from a carboxylic acid base-containing monomer, an amido-group containing monomer or sodium styrenesulfonate to form a honopolymer or copolymer of said hydrophilic ethylenically unsaturated monomers, or a mixture of at least 50% of said hydrophilic ethylenically unsaturated monomer and less than 50% of ethylenically unsaturated monomer copolymerizable therewith other than said hydrophilic ethylenically unsaturated monomer, in the presence of 0.005% to 20% by weight based on the total weight of the ethylenically unsaturated monomers of at least one difunctional compound represented by formula (4): ##STR14## wherein R 3 is hydrogen or a methyl group, p is an integer of from 10 to 150, and q is 0 or an integer of from 1 to 150.

Claim 5

A process as in claim 2, wherein said carboxylic acid base-containing monomer is an alkali metal salt of acrylic or methacrylic acid, sodium maleate, an acrylic or methacrylic acid trimethylamine salt or an acrylic or methacrylic acid triethanolamine salt, and said amido group containing monomer is N-hexylacrylamide, acryl or methacrylamide, N-methylolated acrylamide or N,N-dimethylacrylamide.

Claim 6

A process as in claim 2, wherein said hydrophilic ethylenically unsaturated monomer is selected from the group consisting of a sulfonic acid containing an ethylenically unsaturated group and sodium styrenesulfonate.

Claim 7

A process as in claim 4, wherein said sulfonic acid containing an ethylenically unsaturated group is selected from the group consisting of vinylsulfonic acid, vinyltoluenesulfonic acid, styrenesulfonic acid and sulfopropyl acrylate or methacrylate.

Claim 8

A water-absorbing but less water-soluble hydrogel produced by a process as in claim 1, 2, 3, 4 or 5.

Claim 9

A process as in claim 1, wherein the materials polymerized consist essentially of said at least one hydrophilic ethylenically unsaturated monomer and said at least one difunctional compound.

Claim 10

A process as in claim 2, wherein the materials polymerized consist essentially of said at least one hydrophilic ethylenically unsaturated monomer and said at least one difunctional compound.

Claim 11

A process as in claim 1 or 2 wherein the carboxylic acid containing an ethylenically unsaturated group is selected from the group consisting of acrylic or methacrylic acid, crotonic acid, itaconic acid, maleic acid and fumaric acid.

Claim 12

A process as in claim 1 or 2 wherein the sulfonic acid containing an ethylenically unsaturated group is selected from the group consisting of vinylsulfonic acid, vinyltoluenesulfonic acid, styrenesulfonic acid and sulfopropyl acrylate or methacrylate.

Claim 13

A process as in claim 1 or 2 wherein the derivative of the carboxylic acid containing an ethylenically unsaturated group is a carboxylic acid base-containing monomer, or an amido group-containing monomer and the derivative of the sulfonic acid containing an ethylenically unsaturated group is sodium styrenesulfonate.

Claim 14

A process as in claim 1 or 2 wherein said difunctional said hydrophilic ethylenically unsaturated monomer is an alkali metal salt of acrylic or methacrylic acid. said hydrophilic ethylenically unsaturated monomer is an alkali metal salt of acrylic or methacrylic acid.

Claim 15

A process as in claim 1 or 2 wherein the ethylenically unsaturated monomer copolymerizable with the hydrophilic ethylenically unsaturated monomer is selected from the group consisting of ester bond-containing monomers, nitrile group-containing monomers, styrene-based monomers, and vinyl pyridine-based monomers.

Claim 16

A process as in claim 1 or 2 wherein the amount of the difunctional compound added is from 0.01% to 5% by weight, based upon the total weight of the ethylenically unsaturated monomers.

Claim 17

A process as in claim 1 or 2 wherein the amount of the difunctional compound added is from 0.01% to 1% by weight, based upon the total weight of the ethylenically unsaturated monomers.

Claim 18

A process as in claim 1 or 2 wherein the polymerization is carried out at a temperature of from about 10° C. to 150° C. for a period of from about 1 to 9 hours.

Claim 19

A process as in claim 1 or 2 wherein l is an integer of from 5 to 50.

Claim 20

A process as in claim 16, wherein said temperature is from 20° C. to 100° C.

Claim 21

A process as in claim 1 or 2, wherein said difunctional compound is a compound represented by the formula (4).

Claim 22

A process as in claim 1 or 2, wherein the materials polymerized consist essentially of said at least one hydrophilic ethylenically unsaturated monomer and said at least one difunctional compound.