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Ophthalmic glasses with high indices of refraction

Assignee: Corning Glass Works
•
Filing: 1981-12-07
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Granted: 1982-09-28
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Expires: 2001-12-07
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Abstract

Abstract The present invention is drawn to glasses suitable for the fabrication of segments or buttons for multifocal ophthalmic lenses. The inventive glasses have refractive indices ranging between about 1.745-1.771, an Abbe number greater than 29 for a refractive index of 1.771 and greater than 31 for a refractive index of 1.745, a softening point between about 640°-700° C., a coefficient of thermal expansion (25°-300° C.) between about 90-98×10 -7 /°C., and satisfactory chemical durability. The glasses consist essentially, expressed in terms of weight percent on the oxide basis, of ______________________________________ SiO 2 28-32.5 Na 2 O 2-9 K 2 O 0-4 Li 2 O 0-1 K 2 O + Na 2 O + Li 2 O 4-10.5 BaO 0-22 La 2 O 3 0-20 BaO + La 2 O 3 14-22 PbO 28.5-34 ZnO 0-4 TiO 2 0-9 ZrO 2 2-6.5 Nb 2 O 5 0-10 TiO 2 + Nb 2 O 5 4.5-12 ZrO 2 + TiO 2 + Nb 2 O 5 6-17 ______________________________________

Inventors

  • 👤 Jean E. Boudot
  • 👤 Jean P. Mazeau
  • 👤 Andre C. Michaud

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 09:02
CPC Classifications
C; C03; C03C; C03C3/00; C03C3/04; C03C3/062; C03C3/07; Y; Y10; Y10S; Y10S501/00; Y10S501/90; Y10S501/903

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 134 words
A glass suitable for the fabrication of segments or buttons for multifocal ophthalmic lenses having a refractive index between 1.745-1.771, an Abbe number greater than 29 for a refractive index of 1.771 and greater than 31 for a refractive index of 1.745, a softening temperature between approximately 640°-700° C., a coefficient of thermal expansion (25°-300° C.) of approximately 90-98×10 -7 /°C. and satisfactory chemical durability, which consists essentially, espressed in terms of weight percent on the oxide basis, of ______________________________________ SiO.sub.2 28-32.5 Na.sub.2 O 2-9 K.sub.2 O 0-4 Li.sub.2 O 0-1 K.sub.2 O + Na.sub.2 O + Li.sub.2 O 4-10.5 BaO 0-22 La.sub.2 O.sub.3 0-20 BaO + La.sub.2 O.sub.3 14-22 PbO 28.5-34 ZnO 0-4 TiO.sub.2 0-9 ZrO.sub.2 2-6.5 Nb.sub.2 O.sub.5 0-10 TiO.sub.2 + Nb.sub.2 O.sub.5 4.5-12 ZrO.sub.2 + TiO.sub.2 + Nb.sub.2 O.sub.5 6-17 ______________________________________
Claim 2
Dependent Claim 134 words
A glass suitable for the fabrication of segments or buttons for multifocal ophthalmic lenses having a refractive index between 1.745-1.771, an Abbe number greater than 29 for a refractive index of 1.771 and greater than 31 for a refractive index of 1.745, a softening temperature between approximately 640°-700° C., a coefficient of thermal expansion (25°-300° C.) of approximately 90-98×10 -7 /°C. and satisfactory chemical durability, which consists essentially, espressed in terms of weight percent on the oxide basis, of ______________________________________ SiO.sub.2 28-32.5 Na.sub.2 O 2-9 K.sub.2 O 0-4 Li.sub.2 O 0-1 K.sub.2 O + Na.sub.2 O + Li.sub.2 O 4-10.5 BaO 0-22 La.sub.2 O.sub.3 0-20 BaO + La.sub.2 O.sub.3 14-22 PbO 28.5-34 ZnO 0-4 TiO.sub.2 0-9 ZrO.sub.2 2-6.5 Nb.sub.2 O.sub.5 0-10 TiO.sub.2 + Nb.sub.2 O.sub.5 4.5-12 ZrO.sub.2 + TiO.sub.2 + Nb.sub.2 O.sub.5 6-17 ______________________________________
Claim 3
Dependent Claim 59 words
A glass according to claim 1 consisting essentially, expressed in terms of weight percent on the oxide basis, of ______________________________________ SiO.sub.2 29-32 Na.sub.2 O 5-8 BaO 0-22 La.sub.2 O.sub.3 0-14 BaO + La.sub.2 O.sub.3 18-22 PbO 30-33 ZnO 0-3 TiO.sub.2 5-9 ZrO.sub.2 2-4 Nb.sub.2 O.sub.5 0-6 TiO.sub.2 + Nb.sub.2 O.sub.5 5-11 ZrO.sub.2 + TiO.sub.2 + Nb.sub.2 O.sub.5 8-14 ______________________________________
Claim 4
Dependent Claim 39 words
A glass according to claim 1 consisting essentially, expressed in terms of weight percent on the oxide basis, of ______________________________________ SiO.sub.2 30.9 Na.sub.2 O 6.7 BaO 8.0 ZnO 2.7 La.sub.2 O.sub.3 11.5 ZrO.sub.2 3.3 PbO 31.6 TiO.sub.2 5.3 ______________________________________

References Cited (Backward Citations)

US3902910A Cited
US3973976A Cited
US4213787A Cited
US4211569A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-09-27 1986-03-29 1986-09-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-09-27 1990-03-29 1990-09-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-09-27 1994-03-29 1994-09-28 $7700.00 Window Closed / Lapsed

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