Photochemically or thermally polymerizable mixtures

Claim 2

A photochemically or thermally polymerisable mixture containing (A) one or more cationically polymerisable compounds, (B) an aromatic iodonium salt as the polymerisation catalyst, (C) one or more photoinitiators which is an aromatic carbonyl compound, as the co-catalyst, and (D) an agent which forms free radicals on heating, as the second co-catalyst.

Claim 3

A mixture according to claim 1, wherein component (A) is an epoxide compound or a mixture thereof with other cationically polymerisable compounds, or a mixture of two or more epoxide compounds.

Claim 4

A mixture according to claim 1, wherein component (B) is an aromatic iodonium salt of the formula I ##STR8## in which Ar 1 and Ar 2 independently of one another are phenyl, naphthyl or phenyl which is substituted by one or more of the radicals C 1 -C 8 -alkyl, phenyl, phenoxy, halogen, nitro or C 1 -C 4 -alkoxy, or Ar 1 and Ar 2 together are a divalent radical of the formula II ##STR9## in which Y is a direct bond, --O--, --CH 2 -- or --CO-- and R is C 1 -C 4 -alkyl, halogen, nitro or C 1 -C 4 -alkoxy, M is a metal atom or metalloid atom from the series comprising B, P, As, Sb, Sn, Bi and Fe, Q is fluorine or chlorine and n is 4, 5 or 6 and 1 larger than the valency of M.

Claim 5

A mixture according to claim 3, wherein component B is a salt of the formula I in which Ar 1 and Ar 2 are phenyl or tolyl and [MQ n ] - is one of the anions BF 4 - , PF 6 - , AsF 6 - or SbF 6 - .

Claim 6

A mixture according to claim 1, wherein component (C) is a photoinitiator selected from the group consisting of benzoin, α-alkyl- and α-hydroxymethylbenzoins, benzoin ethers, dialkoxyacetophenones, benzil monoketals, thioxanthone and thioxanthone derivatives.

Claim 7

A mixture according to claim 1, wherein component (C) is an arylcarbonyl compound of the formula III ##STR10## in which n is 1 or 2, Ar, if n is 1, is aryl having 6-14 C atoms, tetrahydronaphthyl, thienyl, pyridyl, furyl or phenyl which is substituted by one or more of the radicals F, Cl, Br, CN, OH, C 1 -C 12 -alkyl, --OAlk, --O-phenyl, --SAlk, --S-phenyl, --SO 2 -phenyl, COOAlk, and Alk is a lower alkyl radical having 1-4 C atoms, and, if n is 2, is C 6 -C 12 arylene or a -phenylene-T-phenylene-group, X is one of the groups --OR 4 or --OSiR 5 (R 6 ) 2 , or together with R 1 is a --O--CH(R 7 )-- group, T is --O--, --S--, --SO 2 -- or --CH 2 --, R 1 is C 1 -C 8 alkyl, which is unsubstituted or substituted by --OH, --OAlk, C 2 -C 8 acyloxy, --COOAlk or --CN, or C 3 -C 4 alkenyl, C 5 -C 6 -cycloalkyl or C 7 -C 9 phenylalkyl, R 2 has one of the meanings defined for R 1 or is a --CH 2 CH 2 R 8 group, or together with R 1 is C 2 -C 8 alkylene or C 3 -C 9 oxa- or -aza-alkylene, R 4 is hydrogen, C 1 -C 12 alkyl, C 2 -C 6 alkyl which is substituted by OH, OAlk or CN, or C 3 -C 5 alkenyl, cyclohexyl, benzyl, unsubstituted phenyl or phenyl substituted by Cl or Alk, or 2-tetrahydropyranyl, R 5 and R 6 are identical or different and are C 1 -C 4 alkyl or phenyl, R 7 is hydrogen, C 1 -C 8 alkyl or phenyl and R 8 is --CONH 2 , --CONHAlk, --CON(Alk) 2 , --P(O)(OAlk) 2 or 2-pyridyl.

Claim 8

A mixture according to claim 6, wherein component (C) is a compound of the formula III in which n is 1, Ar is phenyl, chlorophenyl or C 7 -C 10 -alkylphenyl, R 1 and R 2 either are both methyl or together are pentamethylene and X is --OH, --OCH 3 , --O-allyl or --OSi(CH 3 ) 3 .

Claim 9

A mixture according to claim 1, wherein component (D) is a dibenzyl derivative of the formula IV ##STR11## in which R 9 is C 1 -C 4 -alkoxy or --OSi(R 11 )(R 12 )(R 13 ) and R 11 , R 12 and R 13 independently of one another are C 1 -C 4 -alkyl or phenyl and R 10 is phenyl, cyclohexyl or methyl, or component (D) is an oligomer of the formula V ##STR12## in which m is 2 to 20.

Claim 10

A mixture according to claim 1, wherein component (D) is benzpinacol.

Claim 11

A mixture according to claim 1, which contains catalytic amounts of a photosensitiser.

Claim 12

A process for the polymerisation of cationically polymerisable compounds by irradiation with short-wave light or by heating in the presence of an aromatic iodonium salt as the polymerisation catalyst, wherein a photoinitiator which is an aromatic carbonyl compound and an agent which forms free radicals on heating are additionally used as co-catalysts.

Claim 13

A process for the polymerisation of cationically polymerisable compounds by irradiation with short-wave light or by heating in the presence of an aromatic iodonium salt as the polymerisation catalyst, wherein a photoinitiator which is an aromatic carbonyl compound and an agent which forms free radicals on heating are additionally used as co-catalysts.

Claim 14

A process according to claim 11, wherein the polymerisation is carried out in two stages, the first stage being carried out by irradiation and the second stage by heating, or vice versa.

Claim 15

A process according to claim 11, wherein an epoxide compound or a mixture of epoxide compounds is polymerised.

Claim 16

A process according to claim 11, wherein a phenolformaldehyde resin or an aminoplast is polymerised.