US4351643A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method for concentrating a low-concentration element in a solution
Assignee: Horiba Jobin Yvon Inc
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Filing: 1980-06-17
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Granted: 1982-09-28
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Expires: 2000-06-17
Abstract
Abstract Method of concentrating a low-concentration element in a solution and removing other, high-concentration elements, using an ion exchange resin specific to the element to be concentrated. The resin is disposed in a mini-column less than 3 mm in diameter into which the solution is made to pass, the elution of the element from the resin is carried out by using a very small volume of elution liquid. The invention applies to quantitative analysis by emission spectrum in an inductive plasma, and in this case the whole of the small volume of elution liquid, previously nebulized, is simultaneously supplied to the plasma.
Inventors
- 👤 Kuppusami Govindaraju
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 00:30
CPC Classifications
B; B01; B01J; B01J47/00; G; G01; G01N; G01N21/00; G01N21/62; G01N21/71; G01N21/73; Y; Y10; Y10T; Y10T436/00; Y10T436/25
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
208 words
A method for the quantitative analysis of a first element present in low concentration in a first solution wherein said first solution also contains a second element or group of second elements in a concentration higher than the concentration of said first element which comprises: passing said solution through a column of ion exchange resin for fixing specifically said first element, wherein the diameter of said column is 1 to 3 mm, and the height of said column is 1 to 10 cm, thereby removing said second element or a group of second elements from said first element; passing a small volume of elution liquid through said column to elute said first element from the ion exchange resin and thereby obtaining a second solution of said first element wherein said first element is present in higher concentration than in said first solution; supplying all of said second solution to a nebulizer, thereby transforming said second solution into an aerosol; introducing all of said aerosol and thereby introducing all of said first element initially present in said first solution into an inductive plasma; and analyzing the spectrum emitted whereby all of the said first element intially present in said first solution takes part in the emission of the spectrum.
Claim 2
Independent Claim
208 words
A method for the quantitative analysis of a first element present in low concentration in a first solution wherein said first solution also contains a second element or group of second elements in a concentration higher than the concentration of said first element which comprises: passing said solution through a column of ion exchange resin for fixing specifically said first element, wherein the diameter of said column is 1 to 3 mm, and the height of said column is 1 to 10 cm, thereby removing said second element or a group of second elements from said first element; passing a small volume of elution liquid through said column to elute said first element from the ion exchange resin and thereby obtaining a second solution of said first element wherein said first element is present in higher concentration than in said first solution; supplying all of said second solution to a nebulizer, thereby transforming said second solution into an aerosol; introducing all of said aerosol and thereby introducing all of said first element initially present in said first solution into an inductive plasma; and analyzing the spectrum emitted whereby all of the said first element intially present in said first solution takes part in the emission of the spectrum.
Claim 3
Dependent Claim
32 words
The method of claim 1 wherein several of said columns are arranged in parallel and wherein a solution is passed to each of the columns and wherein the solutions are analyzed sequentially.
Claim 4
Dependent Claim
29 words
The method of claim 2 wherein the columns contain the same ion exchange resin and whereby the concentration of the same element is analyzed for each of the solutions.
Claim 5
Dependent Claim
31 words
The method of claim 2 wherein different columns contain different ion exchange resins being specific to different elements present in low concentration, and whereby the concentrations of different elements are analyzed.
Claim 6
Dependent Claim
17 words
The method of claim 1 wherein said first element is copper and said first solution is seawater.
Claim 7
Dependent Claim
15 words
The method of claim 1 wherein the concentration of uranium in silicated rock is analyzed.
Claim 8
Dependent Claim
15 words
The method of claim 5 wherein about 1 ml of an elution liquid is employed.
Claim 9
Dependent Claim
15 words
The method of claim 6 wherein about 10 ml of an elution liquid is employed.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-09-27 | 1986-03-29 | 1986-09-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-09-27 | 1990-03-29 | 1990-09-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-09-27 | 1994-03-29 | 1994-09-28 | $7700.00 | Window Closed / Lapsed |