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US3915642A Expired / Lapsed US ⏱️ 0.0 years remaining

Quantitative analysis of single ion species

Assignee: Dow Chemical Co
•
Filing: 1973-08-06
•
Granted: 1975-10-28
•
Expires: 1993-08-06
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Abstract

Abstract Method of quantitative analysis of a single ion species paired with at least one species of counter valent ion in an aqueous or highly polar sample solution, the solution containing substantially no other ions of the same valence as said single ion species, save for ions capable of forming a relatively undissociated ion pair with hydrogen ions or hydroxide ions, in which the sample solution is added to an ion exchange resin bed, the resin being an ion exchange resin capable of exchanging ions of the same valence as the at least one species of counter valent ion and the ion exchange resin being in an ion form easily eluted by other ions of the same valence, eluting the single ion species from the ion exchange resin bed and quantitatively detecting the single ion species with a conductivity cell and associated readout means. The apparatus is an ion exchange column charged with an ion exchange resin in an ion form easily elutable by the counter valent ions accompanying a single ion species to be determined, a conductivity cell and associated read-out means, means for bringing sample solution and eluant water to the ion exchange column and liquid conduit means for conducting effluent from the ion exchange column to the conductivity cell.

Inventors

  • 👤 Hamish Small
  • 👤 Timothy S Stevens

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 02:19
CPC Classifications
B; B01; B01J; B01J39/00; B01J39/26; B01J39/04; B01J39/05; B01J41/00; B01J41/04; B01J41/05; B01J41/20; G; G01; G01N; G01N27/00; G01N27/02; G01N27/04; G01N27/06; G01N30/00; G01N30/96; B01J2220/00; B01J2220/50; B01J2220/54; Y; Y10; Y10T; Y10T436/00; Y10T436/17; Y10T436/173845; Y10T436/175383

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 168 words
THE METHOD OF CHROMATOGRAPHIC QUANTITATIVE ANALYSIS OF A SINGLE ION SPECIES PAIRED WITH AT LEAST ONE SPECIES OF COUNTERVALENT ION IN A SAMPLE SOLUTION THE SOLUTION CONTAINING SUBSTANTIALLY NO OTHER IONS OF THE SAME VALENCE AS SAID SINGLE ION, SAVE FOR IONS CAPABLE OF FORMING RELATIVELY UNDISSOCIATED ION PAIRS WITH HYDROGEN IONS OR HYDROXIDE IONS WHICH COMPRISES: ADDING A PREDETERMINED AMOUNT OF SAID SAMPLE SOLUTIONS TO ION EXCHANGE RESIN BED MEANS SAID MEANS BEING CHARGED WITH AN ION EXCHANGE RESIN CAPABLE OF EXCHANGING IONS OF THE SAME VALENCE SIGNED AS THE COUNTERVALENT ION AND THE ION EXCHANGE RESIN BEING IN AN ION FORM EASILY ELUTED BY SAID AT LEAST ONE SPECIES OF COUNTERVALENT ION, AND ELUTING SAID SAMPLE FROM THE COLUMN WITH WATER AS ELUANT SAID SAMPLE BEING IN THE FORM OF A SINGLE ION PAIR CONSISTING OF THE SINGLE ION SPECIES TO BE DETERMINED AND A SINGLE SPECIES OF COUNTERVALENT ION THE COUNTERVALENT ION BEING THE ION FORM IN WHICH THE ION EXCHANGE RESIN HAS BEEN PREPARED,
Claim 2
Independent Claim 168 words
THE METHOD OF CHROMATOGRAPHIC QUANTITATIVE ANALYSIS OF A SINGLE ION SPECIES PAIRED WITH AT LEAST ONE SPECIES OF COUNTERVALENT ION IN A SAMPLE SOLUTION THE SOLUTION CONTAINING SUBSTANTIALLY NO OTHER IONS OF THE SAME VALENCE AS SAID SINGLE ION, SAVE FOR IONS CAPABLE OF FORMING RELATIVELY UNDISSOCIATED ION PAIRS WITH HYDROGEN IONS OR HYDROXIDE IONS WHICH COMPRISES: ADDING A PREDETERMINED AMOUNT OF SAID SAMPLE SOLUTIONS TO ION EXCHANGE RESIN BED MEANS SAID MEANS BEING CHARGED WITH AN ION EXCHANGE RESIN CAPABLE OF EXCHANGING IONS OF THE SAME VALENCE SIGNED AS THE COUNTERVALENT ION AND THE ION EXCHANGE RESIN BEING IN AN ION FORM EASILY ELUTED BY SAID AT LEAST ONE SPECIES OF COUNTERVALENT ION, AND ELUTING SAID SAMPLE FROM THE COLUMN WITH WATER AS ELUANT SAID SAMPLE BEING IN THE FORM OF A SINGLE ION PAIR CONSISTING OF THE SINGLE ION SPECIES TO BE DETERMINED AND A SINGLE SPECIES OF COUNTERVALENT ION THE COUNTERVALENT ION BEING THE ION FORM IN WHICH THE ION EXCHANGE RESIN HAS BEEN PREPARED,
Claim 3
Dependent Claim 25 words
The method as in claim 1 in which the single ion species is a cation and the ion exchange resin is an anion exchange resin.
Claim 4
Dependent Claim 43 words
The method as in claim 2 in which the anion exchange resin is in the hydroxide form and the cation is selected from the group consisting of alkali metal, ammonia, water-soluble protonated, organic amine, water-soluble quaternary ammonium compound, barium ion and strontium ion.
Claim 5
Dependent Claim 44 words
The method as in claim 2 in which the anion exchange resin is in the acetate form and the cation is selected from the group consisting of the ions of alkali metal, alkaline-earth metal, ammonia, water-soluble protonated organic amine and water-soluble quaternary ammonium compound.
Claim 6
Dependent Claim 25 words
The method as in claim 1 in which the single ion species is an anion and the ion exchange resin is a cation exchange resin.
Claim 7
Dependent Claim 18 words
The method as in claim 5 in which the cation exchange resin is in the hydrogen ion form.
Claim 8
Dependent Claim 18 words
The method as in claim 5 in which the cation exchange resin is in the lithium ion form.
Claim 9
Dependent Claim 51 words
The method as in claim 5 in which the anion is selected from the group consisting of chloride, bromide, iodide, nitrate, nitrite, sulfate, sulfite, bisulfate, bisulfite, carbonate, orthophosphate, hydrogenphosphate, dihydrogenphosphate, metaphosphate, phosphite, and carboxylate ion of water-soluble carboxylic acids having a dissociation constant at least equal to 1 X 10 6.

References Cited (Backward Citations)

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US2711995A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-10-27 1979-04-28 1979-10-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-10-27 1983-04-28 1983-10-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-10-27 1987-04-28 1987-10-28 $7700.00 Window Closed / Lapsed

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