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Novel light stabilizers for polymers

Assignee: Wyeth Holdings LLC
•
Filing: 1981-07-20
•
Granted: 1982-09-07
•
Expires: 2001-07-20
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Abstract

Abstract Ultraviolet light stabilizers for polymers are disclosed. The stabilizers have the formula ##STR1##

Inventors

  • 👤 Frank F. Loffelman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 05:49
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3467; C08K5/3477; C08K5/3492

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 321 words
A compound of the formula (I) ##STR16## wherein W represents C 1 -C 20 alkoxy, or ##STR17## wherein R and R 1 are the same or different and each represent hydrogen, C 1 -C 20 alkyl, or together form a piperidino, pyrrolidyl, or morpholino radical; n is an integer from 1 to 3; and m is an integer from 1 to 6; when m is 1, X and Y are the same or different and each represent chloro, bromo, ##STR18## wherein R and R 1 are as previously defined, C 1 -C 12 alkoxy, C 1 -C 12 alkylthio, ##STR19## wherein n and W are as previously defined, or the radicals (II) or (III) ##STR20## wherein R 2 represents hydrogen, C 1 -C 8 alkyl, or benzyl; R 3 and R 4 independently represent C 1 -C 8 alkyl, benzyl, or phenethyl, or together with the carbon to which they are attached form a C 5 -C 10 cycloalkyl; R 5 represents hydrogen, C 2 -C 3 hydroxyalkyl, C 1 -C 8 alkyl, hydroxyl, or oxyl; R 6 represents hydrogen, C 1 -C 20 alkyl, or the radical (IV) ##STR21## wherein R 2 , R 3 , R 4 , and R 5 are as previously defined; with the proviso that at least one X or Y, must contain a piperidinyl moiety (IV); and when m is an integer from 2 to 6, X is as previously defined; Y is an m-valent radical derived from a polyamine, polyalcohol, or polymercaptan containing a C 2 -C 20 alkylene chain, either straight-chained or branched, wherein the alkylene chain may be interrupted by oxy, thio, or ##STR22## wherein R 7 represents hydrogen, C 1 -C 20 alkyl, or the moiety (IV); C 5 -C 10 cycloalkylene, ##STR23## C 6 -C 12 arylene; or C 8 -C 14 arylenedialkylene; with the proviso that at least one piperidinyl moiety (IV) is present in X or Y.
Claim 2
Dependent Claim 321 words
A compound of the formula (I) ##STR16## wherein W represents C 1 -C 20 alkoxy, or ##STR17## wherein R and R 1 are the same or different and each represent hydrogen, C 1 -C 20 alkyl, or together form a piperidino, pyrrolidyl, or morpholino radical; n is an integer from 1 to 3; and m is an integer from 1 to 6; when m is 1, X and Y are the same or different and each represent chloro, bromo, ##STR18## wherein R and R 1 are as previously defined, C 1 -C 12 alkoxy, C 1 -C 12 alkylthio, ##STR19## wherein n and W are as previously defined, or the radicals (II) or (III) ##STR20## wherein R 2 represents hydrogen, C 1 -C 8 alkyl, or benzyl; R 3 and R 4 independently represent C 1 -C 8 alkyl, benzyl, or phenethyl, or together with the carbon to which they are attached form a C 5 -C 10 cycloalkyl; R 5 represents hydrogen, C 2 -C 3 hydroxyalkyl, C 1 -C 8 alkyl, hydroxyl, or oxyl; R 6 represents hydrogen, C 1 -C 20 alkyl, or the radical (IV) ##STR21## wherein R 2 , R 3 , R 4 , and R 5 are as previously defined; with the proviso that at least one X or Y, must contain a piperidinyl moiety (IV); and when m is an integer from 2 to 6, X is as previously defined; Y is an m-valent radical derived from a polyamine, polyalcohol, or polymercaptan containing a C 2 -C 20 alkylene chain, either straight-chained or branched, wherein the alkylene chain may be interrupted by oxy, thio, or ##STR22## wherein R 7 represents hydrogen, C 1 -C 20 alkyl, or the moiety (IV); C 5 -C 10 cycloalkylene, ##STR23## C 6 -C 12 arylene; or C 8 -C 14 arylenedialkylene; with the proviso that at least one piperidinyl moiety (IV) is present in X or Y.
Claim 3
Dependent Claim 20 words
The compound of claim 1 of the formula (V) ##STR24## wherein m' is an integer from about 2 to 4.
Claim 4
Dependent Claim 24 words
The compound of claim 2 wherein R 2 , R 5 and R 6 are hydrogen, and R 3 and R 4 are methyl.
Claim 5
Dependent Claim 20 words
The compound of claim 1 of the formula (VI) ##STR25## wherein m" is an integer from about 2 to 6.
Claim 6
Dependent Claim 24 words
The compound of claim 4 wherein R 2 , R 5 and R 6 are hydrogen, and R 3 and R 4 are methyl.
Claim 7
Dependent Claim 6 words
The compound of claim 1: 1,8-bis[4-ethoxycarbonylmethyleneamino-6-(2,2,6,6-tetramethyl-4-piperidinyl)amino-1,3,5-triazin-2-yl]-1,8-di-azaoctane.
Claim 8
Dependent Claim 6 words
The compound of claim 1: 1,4,7-tris[4-ethoxy-carbonylmethyleneamino-6-(2,2,6,6-tetramethyl-4-piperidinyl)amino-1,3,5-triazin-2-yl]-1,4,7-triazaheptane.
Claim 9
Dependent Claim 6 words
The compound of claim 1: 1,4,7,10,13-pentakis-[4-ethoxycarbonylmethyleneamino-6-(2,2,6,6-tetramethyl-4-piperidinyl)amino-1,3,5-triazin-2-yl]-1,4,7,10,13-pentaazatridecane.
Claim 10
Dependent Claim 32 words
A method for stabilizing a polymer which is normally subject to degradation by ultraviolet radiation which comprises incorporating into said polymer an ultraviolet stabilizingly effective amount of a compound of claim 1.
Claim 11
Dependent Claim 28 words
The method of claim 9 wherein the compound is incorporated in a concentration of from about 0.2 to 2% by weight based on the weight of the polymer.
Claim 12
Dependent Claim 11 words
The method of claim 9 wherein the polymer is a polyolefin.
Claim 13
Dependent Claim 10 words
The method of claim 11 wherein the polyolefin is polypropylene.
Claim 14
Dependent Claim 20 words
The method of claim 9 wherein the compound is that of claim 2, 3, 4, 5, 6, 7 or 8.
Claim 15
Dependent Claim 13 words
The composition produced by the method of claim 9, 10, 11 or 12.
Claim 16
Dependent Claim 9 words
The composition produced by the method of claim 13.

References Cited (Backward Citations)

US4028334A Cited
US4141883A Cited
US4191683A Cited
US4108829A Cited
US4161592A Cited
US4234728A Cited
US4294963A Cited
US4288593A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-09-06 1986-03-08 1986-09-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-09-06 1990-03-08 1990-09-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-09-06 1994-03-08 1994-09-07 $7700.00 Window Closed / Lapsed

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