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US4348305A Expired / Lapsed US ⏱️ 0.0 years remaining

Liquid detergent compositions comprising mixtures of alkyl polyglycol ethers and quaternary ammonium fabric softening agents

Assignee: Henkel AG and Co KGaA
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Filing: 1981-03-13
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Granted: 1982-09-07
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Expires: 2001-03-13
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Abstract

Abstract An improved liquid detergent composition is comprised of: (a) from about 5 to 18% by weight of a mixture of alkyl polyglycol ethers; (b) from about 5 to 18% by weight of a second mixture of alkyl polyglycol ethers, the quantitative ratio of (a) to (b) being from about 2:1 to 1:2; and (c) from about 2.5 to 10% by weight of a fabric-softening quaternary ammonium salt.

Inventors

  • 👤 Manfred Hennemann
  • 👤 Albrecht Lohr

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 14:21
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/0005; C11D3/001; C11D3/0015; C11D1/00; C11D1/66; C11D1/835; C11D1/8355; C11D1/38; C11D1/62; C11D1/72

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 313 words
A liquid detergent having an optimum combination of washing ability, fabric softening action, and sudsing behavior, said liquid detergent comprising: (a) from about 5 to 18% by weight of a mixture of alkyl polyglycol ethers of the formula ##STR3## wherein R 1 represents a linear alkyl radical; R 2 , in from about 20 to 75% of said alkyl polyglycol ethers, represents a C 1 to C 4 alkyl group and, in from 25 to 80% of said alkyl polyglycol ethers, represents a hydrogen atom, the total number of carbon atoms in R 1 and R 2 together being from about 11 to 15; and wherein n represents an average value of from about 5 to 9, n being a value such that the ethylene oxide portion of the alkyl polyglycol ether represents from about 50 to 65% by weight, based on the total weight of the alkyl polyglycol ether; (b) from about 5 to 18% by weight of a mixture of alkyl polyglycol ethers of Formula I, wherein R 1 represents a linear alkyl group; R 2 is a hydrogen atom or, in from about 20 to 75% of said alkyl polyglycol ethers, represents a C 1 to C 4 alkyl group and, in from about 25 to 80% of said alkyl polyglycol ethers, represents a hydrogen atom, the total number of carbon atoms in R 1 and R 2 together being from about 6 to 10; and wherein n represents an average value of from about 3 to 8, n being of such a value that the ethylene oxide portion of the alkyl polyglycol ether represents from about 55 to 70% by weight, based on the total weight of the alkyl polyglycol ether, the quantitative ratio of (a) to (b) being from about 2:1 to 1:2; and (c) from about 2.5 to 10% by weight of a fabric-softening quaternary ammonium salt.
Claim 2
Dependent Claim 313 words
A liquid detergent having an optimum combination of washing ability, fabric softening action, and sudsing behavior, said liquid detergent comprising: (a) from about 5 to 18% by weight of a mixture of alkyl polyglycol ethers of the formula ##STR3## wherein R 1 represents a linear alkyl radical; R 2 , in from about 20 to 75% of said alkyl polyglycol ethers, represents a C 1 to C 4 alkyl group and, in from 25 to 80% of said alkyl polyglycol ethers, represents a hydrogen atom, the total number of carbon atoms in R 1 and R 2 together being from about 11 to 15; and wherein n represents an average value of from about 5 to 9, n being a value such that the ethylene oxide portion of the alkyl polyglycol ether represents from about 50 to 65% by weight, based on the total weight of the alkyl polyglycol ether; (b) from about 5 to 18% by weight of a mixture of alkyl polyglycol ethers of Formula I, wherein R 1 represents a linear alkyl group; R 2 is a hydrogen atom or, in from about 20 to 75% of said alkyl polyglycol ethers, represents a C 1 to C 4 alkyl group and, in from about 25 to 80% of said alkyl polyglycol ethers, represents a hydrogen atom, the total number of carbon atoms in R 1 and R 2 together being from about 6 to 10; and wherein n represents an average value of from about 3 to 8, n being of such a value that the ethylene oxide portion of the alkyl polyglycol ether represents from about 55 to 70% by weight, based on the total weight of the alkyl polyglycol ether, the quantitative ratio of (a) to (b) being from about 2:1 to 1:2; and (c) from about 2.5 to 10% by weight of a fabric-softening quaternary ammonium salt.
Claim 3
Dependent Claim 29 words
The liquid detergent composition of claim 1 wherein component (a) plus component (b) represent from about 10 to 30% by weight, based on the total weight of the composition.
Claim 4
Dependent Claim 29 words
The liquid detergent composition of claim 2 wherein component (a) plus component (b) represent from about 15 to 30% by weight, based on the total weight of the composition.
Claim 5
Dependent Claim 25 words
The liquid detergent composition of claim 1 wherein R 1 and R 2 of component (a) together contain from about 11 to 13 carbon atoms.
Claim 6
Dependent Claim 31 words
The liquid detergent composition of claim 1 wherein the ethylene oxide portion of component (a) represents from about 55 to 60% by weight, based on the total weight of component (a).
Claim 7
Dependent Claim 25 words
The liquid detergent composition of claim 1 wherein R 1 and R 2 of component (b) together contain from about 8 to 10 carbon atoms.
Claim 8
Dependent Claim 31 words
The liquid detergent composition of claim 1 wherein the ethylene oxide portion of component (b) represents from about 55 to 65% by weight, based on the total weight of component (b).
Claim 9
Dependent Claim 17 words
The liquid detergent composition of claim 1 wherein component (c) is a derivative of ammonia or imidazoline.
Claim 10
Dependent Claim 17 words
The liquid detergent composition of claim 1 or 8 wherein component (c) contains two long-chain aliphatic radicals.
Claim 11
Dependent Claim 37 words
The liquid detergent composition of claim 1 wherein component (c) is a quaternary ammonium salt whose atom is selected from the group of chloro, bromo, methyl sulfato, ethyl sulfato, methane sulfonato, ethane sulfonato, or toluene sulfonato groups.
Claim 12
Dependent Claim 18 words
The liquid detergent composition of claim 1 or 10 wherein component (c) is a ditallow-alkyl-dimethylammonium or distearyl-dimethylammonium salt.
Claim 13
Dependent Claim 16 words
The liquid detergent composition of claim 11 wherein component (c) is distallow-alkyl-dimethyl-ammonium chloride or distearyl-dimethylammonium chloride.
Claim 14
Dependent Claim 13 words
The liquid detergent composition of claim 1 which also is comprised of water.
Claim 15
Dependent Claim 188 words
The liquid detergent composition of claim 1 comprised of: (a) from about 10 to 12.5% by weight of an alkyl polyglycol ether of Formula I wherein R 1 and R 2 together contain from about 11 to 13 carbon atoms and wherein the average ethylene oxide content of the alkyl polyglycol ether is from about 55 to 65% by weight, based on the total weight of the alkyl polyglycol ether; (b) from about 10 to 12.5% by weight of an alkyl polyglycol ether of Formula I wherein R 1 contains from about 7 to 10 carbon atoms, R 2 is a hydrogen atom, and the average ethylene oxide portion of the alkyl polyglycol ether is from about 60 to 70% by weight, based on the weight of the alkyl polyglycol ether; (c) from about 2.5 to 5% by weight of a ditallow-alkyl-dimethylammonium salt, based on the total weight of the composition; and (d) balance to 100% of water, water-miscible organic solvents, hydrotropic agents, dyes, perfumes, heavy metal sequestrants, preservatives, opacifiers, or viscosity standardizing agents, or a mixture thereof, wherein water comprises from about 35 to 85% by weight.
Claim 16
Dependent Claim 17 words
The liquid detergent composition of claim 14 wherein component (c) is the chloride or methyl sulfate salt.
Claim 17
Dependent Claim 41 words
The liquid detergent composition of claim 1, wherein component (c) is a derivative of ammonia or imidazoline having at least one quaternary nitrogen and having two long-chain aliphatic radicals, each of said radicals having from about 14 to 26 carbon atoms.
Claim 18
Dependent Claim 55 words
The liquid detergent composition of claim 1, wherein component (c) is obtained (i) by alkylation of a long-chained secondary amine or (ii) by reacting 1 mole of an aminoalkyl-ethylene diamine or hydroxyalkyl ethylene diamine with 2 moles of a long-chained C 14 /C 26 fatty acid or ester thereof and then alkylating the reaction product.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-09-06 1986-03-08 1986-09-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-09-06 1990-03-08 1990-09-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-09-06 1994-03-08 1994-09-07 $7700.00 Window Closed / Lapsed

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