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US4342591A
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Process for the recovery of gold and/or silver and possibly bismuth contained in sulfuretted ores and/or sulfoarsenides
Assignee: Mines et Produits Chimiques de Salsingne
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Filing: 1981-04-28
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Granted: 1982-08-03
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Expires: 2001-04-28
Abstract
Abstract The present invention relates to a process for the recovery of gold and/or silver and possibly bismuth contained in sulfuretted ores and/or sulfoarsenides, wherein said ores, after having been subjected to a reducing roasting, then to an oxidizing roasting then a possible crushing, are treated by a first lixiviation with sulfuric acid followed by a lixiviation with thiourea under precise conditions of operation.
Inventors
- 👤 Marcel Lesoille
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 22:50
CPC Classifications
C; C22; C22B; C22B11/00; C22B11/04; C01; C01G; C01G5/00; C01G5/003; C01G7/00; C01G7/003; C22B3/00; C22B3/04; C22B3/06; C22B3/08; C22B3/16; C22B3/1608; C22B3/1616; C22B30/00; C22B30/06; Y; Y02; Y02P; Y02P10/00; Y02P10/20
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
183 words
In a process for recovering gold and/or silver and possibly bismuth contained in a sulfuretted ore and/or sulfoarsenide, said ore, from which is gangue has been removed according to known processes, is treated according to the following successive operations: a reducing roasting; an oxidising roasting; a possible crushing; a first lixiviation by a sulfuric acid solution containing about 20 to 120 g of acid per liter, at a temperature of about 20° to 85° C. and for a duration of 0.5 to 3 hrs.; after separation of the solid, a lixiviation of said solid effected with the aid of a sulfuric acid thiourea solution containing from 10 to 50 g/l of thiourea, at a pH of 0.7 to 1.5, at a temperature of 20° to 70° C., for a duration of 15 mins. to 15 hrs., this lixiviation being conducted so that the potential of oxidoreduction of the medium is maintained at a value of between about 100 and about 180 mV; and, after filtration of the solution, a cementation of said solution to recover the gold, silver and bismuth that it contains.
Claim 2
Dependent Claim
183 words
In a process for recovering gold and/or silver and possibly bismuth contained in a sulfuretted ore and/or sulfoarsenide, said ore, from which is gangue has been removed according to known processes, is treated according to the following successive operations: a reducing roasting; an oxidising roasting; a possible crushing; a first lixiviation by a sulfuric acid solution containing about 20 to 120 g of acid per liter, at a temperature of about 20° to 85° C. and for a duration of 0.5 to 3 hrs.; after separation of the solid, a lixiviation of said solid effected with the aid of a sulfuric acid thiourea solution containing from 10 to 50 g/l of thiourea, at a pH of 0.7 to 1.5, at a temperature of 20° to 70° C., for a duration of 15 mins. to 15 hrs., this lixiviation being conducted so that the potential of oxidoreduction of the medium is maintained at a value of between about 100 and about 180 mV; and, after filtration of the solution, a cementation of said solution to recover the gold, silver and bismuth that it contains.
Claim 3
Dependent Claim
35 words
The process of claim 1, wherein the reducing roasting is effected at a temperature of about 680° to 720° C. and the oxidising roasting is effected at a temperature of about 550° to 630° C.
Claim 4
Dependent Claim
26 words
The process of one of claims 1 or 2, wherein the lixiviation by the acid thiourea solution is effected in the presence of a reducing agent.
Claim 5
Dependent Claim
13 words
The process of claim 3, wherein said reducing agent is SO 2 .
Claim 6
Dependent Claim
19 words
The process of claim 3, wherein said reducing agent is a sulfuretted solid taken after the reducing roasting step.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-08-02 | 1986-02-01 | 1986-08-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-08-02 | 1990-02-01 | 1990-08-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-08-02 | 1994-02-01 | 1994-08-03 | $7700.00 | Window Closed / Lapsed |