Polyacrylate thickening agents

Claim 2

An interpolymer of monomers comprising (1) at least 60 weight percent of acrylic acid or methacrylic acid; (2) between about 0.2-20 weight percent of a glyceryl ether derivative in which one hydroxyl group is in the free form, one hydroxyl group is in the form of an allyl ether substituent, and the other hydroxyl group is in the form of an ether or ester substituent, wherein said glyceryl ether derivative is prepared by reacting allyl glycidyl ether with a monohydric alcohol or a monocarboxylic acid in the mole ratio of allyl glycidyl ether to alcohol or acid of 1:1 to 1:0.5 and wherein the monohydric alcohol is an alkyl alcohol which contains from one to 20 carbon atoms, an arylalkyl alcohol which contains from 7 to 20 carbon atoms, or an alkenyl alcohol which contains from 12 to 20 carbon atoms, or glycol or polyglycol monoethers having the formula RO(C.sub.2 H.sub.4 O).sub.n H wherein R is an alkyl group which contains from 1 to 10 carbon atoms or an aryl group which is phenyl or alkyl substituted phenyl wherein the alkyl group contains from 1 to 12 carbon atoms and wherein n has a value of 1 to about 40, and wherein the monocarboxylic acid is an alkyl monocarboxylic acid which contains from 2 to 20 carbon atoms, an aryl monocarboxylic acid which contains 7 to 20 carbon atoms, or an alkenyl monocarboxylic acid which contains from 5 to 20 carbon atoms; and (3) between about 0-20 weight percent of another olefinically unsaturated monomer copolymerizable therewith.

Claim 3

An interpolymer in accordance with claim 1 wherein the mole ratios are 1:0.95 to 1:0.8.

Claim 4

An interpolymer in accordance with claim 1 wherein the carboxylic acid groups are at least partially neutralized.

Claim 5

An interpolymer in accordance with claim 1 wherein a 0.5 weight percent solution of the said interpolymer in water has a viscosity between about 20,000-60,000 cps at a pH between about 5-9.

Claim 6

An interpolymer in accordance with claim 1 wherein the glyceryl ether monomer before polymerization substantially corresponds to the formula: ##STR4## and is the reaction product of allyl glycidyl ether and benzyl alcohol.

Claim 7

An interpolymer in accordance with claim 1 wherein the glyceryl ether monomer before polymerization substantially corresponds to the formula: ##STR5## and in the reaction product of allyl glycidyl ether and ethylene glycol monobutyl ether.

Claim 8

An interpolymer in accordance with claim 1 wherein the glyceryl ether monomer before polymerization substantially corresponds to the formula: ##STR6## and is the reaction product of allyl glycidyl ether and diethylene glycol monobutyl ether.

Claim 9

An interpolymer in accordance with claim 1 wherein the glyceryl ether monomer before polymerization substantially corresponds to the formula: ##STR7## and is the reaction product of allyl glycidyl ether and undecylenic acid.

Claim 10

An interpolymer in accordance with claim 1 wherein the said interpolymer contains acrylamide as a third monomer component.

Claim 11

An interpolymer in accordance with claim 1 wherein the said interpolymer contains N,N-dialkylacrylamide as a third monomer component.

Claim 12

An interpolymer in accordance with claim 1 wherein the said interpolymer contains alkyl (meth)acrylate as a third monomer component.

Claim 13

An interpolymer in accordance with claim 1 wherein the said interpolymer contains maleic anhydride as a third monomer component.

Claim 14

A thickened liquid composition which contains an effective quantity of a thickening agent which is an interpolymer of monomers comprising (1) at least 60 weight percent of acrylic acid or methacrylic acid; (2) between about 0.2-20 weight percent of a glyceryl ether derivative in which one hydroxyl group is in the free form, one hydroxyl group is in the form of an allyl ether substituent, and the other hydroxyl group is in the form of an ether or ester substituent wherein said glyceryl ether derivative is prepared by reacting allyl glycidyl ether with a monohydric alcohol or a monocarboxylic acid in the mole ratio of allyl glycidyl ether to alcohol or acid of 1:1 to 1:0.5 and wherein the monohydric alcohol is an alkyl alcohol which contains from one to 20 carbon atoms, an arylalkyl alcohol which contains from 7 to 20 carbon atoms, or an alkenyl alcohol which contains from 12 to 20 carbon atoms, or glycol or polyglycol monoethers having the formula RO(C.sub.2 H.sub.4 O).sub.n H wherein R is an alkyl group which contains from 1 to 10 carbon atoms or an aryl group which is phenyl or alkyl substituted phenyl wherein the alkyl group contains from 1 to 12 carbon atoms and wherein n has a value of 1 to about 40, and wherein the monocarboxylic acid is an alkyl monocarboxylic acid which contains from 2 to 20 carbon atoms, an aryl monocarboxylic acid which contains 7 to 20 carbon atoms, or an alkenyl monocarboxylic acid which contains from 5 to 20 carbon atoms; and (3) between about 0-20 weight percent of another olefinically unsaturated monomer.

Claim 15

A thickened liquid composition which contains an effective quantity of a thickening agent which is an interpolymer of monomers comprising (1) at least 60 weight percent of acrylic acid or methacrylic acid; (2) between about 0.2-20 weight percent of a glyceryl ether derivative in which one hydroxyl group is in the free form, one hydroxyl group is in the form of an allyl ether substituent, and the other hydroxyl group is in the form of an ether or ester substituent wherein said glyceryl ether derivative is prepared by reacting allyl glycidyl ether with a monohydric alcohol or a monocarboxylic acid in the mole ratio of allyl glycidyl ether to alcohol or acid of 1:1 to 1:0.5 and wherein the monohydric alcohol is an alkyl alcohol which contains from one to 20 carbon atoms, an arylalkyl alcohol which contains from 7 to 20 carbon atoms, or an alkenyl alcohol which contains from 12 to 20 carbon atoms, or glycol or polyglycol monoethers having the formula RO(C.sub.2 H.sub.4 O).sub.n H wherein R is an alkyl group which contains from 1 to 10 carbon atoms or an aryl group which is phenyl or alkyl substituted phenyl wherein the alkyl group contains from 1 to 12 carbon atoms and wherein n has a value of 1 to about 40, and wherein the monocarboxylic acid is an alkyl monocarboxylic acid which contains from 2 to 20 carbon atoms, an aryl monocarboxylic acid which contains 7 to 20 carbon atoms, or an alkenyl monocarboxylic acid which contains from 5 to 20 carbon atoms; and (3) between about 0-20 weight percent of another olefinically unsaturated monomer.

Claim 16

A thickened liquid composition in accordance with claim 13 wherein the quantity of thickening agent is in the range between about 0.1-5 weight percent, based on the weight of liquid medium.

Claim 17

A thickened liquid composition in accordance with claim 13 wherein the liquid medium is a polar solvent.

Claim 18

A thickened liquid composition in accordance with claim 13 wherein the composition is an aqueous medium having a pH between about 5-9, and having a viscosity between about 20,000-60,000 cps.

Claim 19

A print paste formulation having incorporated therein a thickening agent which comprises an interpolymer in accordance with claim 1.