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US4337325A Expired / Lapsed US ⏱️ 0.0 years remaining

Pressure-sensitive adhesive

Assignee: Kendall Co
•
Filing: 1980-04-04
•
Granted: 1982-06-29
•
Expires: 2000-04-04
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Abstract

Abstract An optically clear blend of (1) a water-soluble polymer of a vinyl lactam having the structure ##STR1## in which X represents an alkylene bridge having three to five carbon atoms or a copolymer thereof with 1 to 80 mole percent of a copolymerizable monomer containing a polymerizable ethylenic unsaturation; and (2) a tacky water-insoluble copolymer of (A) an ester or a mixture of esters having the structure ##STR2## in which R' represents hydrogen or methyl and R 1 represents alkyl having from 1 to 14 carbon atoms and (B) from 1 to 12% by weight, based on the copolymer, of an ethylenic monomer containing an acid group, the vinyl lactam polymer or copolymer being present in an amount from 1 to 30% by weight of the blend and having a glass transition temperature from 20° to 150° C., and the tacky copolymer having a glass transition temperature below 0° C. and being present in an amount from 70 to 99% by weight of the blend and having a viscosity less than 50,000 cp at 350° F. The blend is useful as a pressure-sensitive adhesive composition.

Inventors

  • 👤 Kishore R. Shah

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 21:04
CPC Classifications
C; C09; C09J; C09J133/00; C09J133/04; C09J133/06; C09J133/062; C09J133/064; A; A61; A61L; A61L15/00; A61L15/16; A61L15/42; A61L15/58; A61L15/585; A61L17/00; A61L17/14; A61L17/145; A61L29/00; A61L29/08; A61L29/085; A61L29/14; A61L29/145; C01; C01B; C01B21/00; C01B21/20; C01B21/24; C01B21/26; C08; C08L; C08L39/00; C08L39/04; C08L39/06; C09J139/00; C09J139/04; C09J139/06; C09J7/00; C09J7/30; C09J7/38; C08L2666/00; C08L2666/02; C08L2666/04; C09J2301/00; C09J2301/30; C09J2301/302; Y; Y10; Y10T; Y10T428/00; Y10T428/28; Y10T428/2852; Y10T428/2878; Y10T428/2887; Y10T428/2891

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 215 words
A composition consisting essentially of an optically clear blend of (1) a water-soluble polymer of a vinyl lactam having the structure ##STR5## in which X represents an alkylene bridge having three to five carbon atoms, or a copolymer thereof with 1 to 80 mole percent of copolymerizable monomer containing a polymerizable ethylenic unsaturation, and (2) a tacky water-insoluble copolymer comprising (A) an ester or a mixture of esters having the structure ##STR6## in which R' represents hydrogen or methyl and R 1 represents alkyl having from 1 to 14 carbon atoms and (B) from 1 to 12% by weight, based on the tacky copolymer of an ethylenic monomer containing an acid group, said vinyl lactam polymer or copolymer being present in an amount from 1 to 30% by weight of the blend and having a glass transition temperature from 20° to 150° C., and the tacky copolymer having a glass transition temperature below 0° C. and being present in an amount from 70 to 99% by weight of the blend and being substantially free from cross-linking and having a viscosity less than 50,000 cps at 350° F. so that it possesses by itself insufficient cohesive strength to be useful as a pressure-sensitive adhesive, said blend having a viscosity less than 100,000 cps at 350° F.
Claim 2
Dependent Claim 215 words
A composition consisting essentially of an optically clear blend of (1) a water-soluble polymer of a vinyl lactam having the structure ##STR5## in which X represents an alkylene bridge having three to five carbon atoms, or a copolymer thereof with 1 to 80 mole percent of copolymerizable monomer containing a polymerizable ethylenic unsaturation, and (2) a tacky water-insoluble copolymer comprising (A) an ester or a mixture of esters having the structure ##STR6## in which R' represents hydrogen or methyl and R 1 represents alkyl having from 1 to 14 carbon atoms and (B) from 1 to 12% by weight, based on the tacky copolymer of an ethylenic monomer containing an acid group, said vinyl lactam polymer or copolymer being present in an amount from 1 to 30% by weight of the blend and having a glass transition temperature from 20° to 150° C., and the tacky copolymer having a glass transition temperature below 0° C. and being present in an amount from 70 to 99% by weight of the blend and being substantially free from cross-linking and having a viscosity less than 50,000 cps at 350° F. so that it possesses by itself insufficient cohesive strength to be useful as a pressure-sensitive adhesive, said blend having a viscosity less than 100,000 cps at 350° F.
Claim 3
Dependent Claim 18 words
A composition as claimed in claim 1 in which X represents --CH 2 --CH 2 --CH 2 --.
Claim 4
Dependent Claim 17 words
A composition as claimed in claim 2 in which R' represents hydrogen and (B) is acrylic acid.
Claim 5
Dependent Claim 27 words
A composition as claimed in claim 2 in which said vinyl lactam is present as a copolymer with vinyl acetate, an alkyl acrylate or an alkyl methacrylate.
Claim 6
Dependent Claim 20 words
A composition as claimed in claim 3 in which R 1 represents alkyl having from 4 to 8 carbon atoms.
Claim 7
Dependent Claim 13 words
A composition as claimed in claim 4 in which R 1 represents n-butyl.
Claim 8
Dependent Claim 13 words
A composition as claimed in claim 4 in which R 1 represents 2-ethylhexyl.
Claim 9
Dependent Claim 51 words
A composition as claimed in either of claims 2 or 3 in which the viscosity of the tacky copolymer is less than 50,000 cp at 350° F. and the vinyl lactam is present in the form of poly(vinyl pyrrolidone) in an amount from 1 to 8% by weight of the blend.

References Cited (Backward Citations)

US3027347A Cited
US3928262A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-06-28 1985-12-28 1986-06-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-06-28 1989-12-28 1990-06-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-06-28 1993-12-28 1994-06-29 $7700.00 Window Closed / Lapsed

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