Urethane rheology modifiers substantially free of terminal hydrophobic groups and compositions containing same

Claim 2

A urethane rheology modifier characterized in having a branched structure, substantially no terminal hydrophobic groups and capable of modifying the rheology properties of water-based and organic solvent-based compositions, derived from the reaction of (a) for each 8 moles of a polyalkylene oxide having a molecular weight of from about 2,000 to about 20,000; (b) from about 0.1 mole to about 3 moles of a polyfunctional material, said material having at least 3 active hydrogens capable of reacting with isocyanate or being a polyisocyanate having at least three isocyanate groups; (c) from about 4 moles to about 15 moles of a diisocyanate; (d) less than about 3 moles water; and (e) an amount of additional diisocyanate to compensate for any water which is present and capable of consuming isocyanate functionality.

Claim 3

The rheology modifier of claim 1 wherein the polyfunctional material is selected from the group consisting of polyols, amines, amine alcohols, thiols, polyisocyanates, and mixtures thereof.

Claim 4

The rheology modifier of claim 2 wherein the polyfunctional material is the polyisocyanate.

Claim 5

The rheology modifier of claim 2 wherein the polyfunctional material is the polyol.

Claim 6

The rheology modifier of claim 4 wherein the polyol is a trifunctional alcohol.

Claim 7

The rheology modifier of claim 5 wherein the trifunctional alcohol is trimethylolpropane.

Claim 8

The rheology modifier of claim 1 or 6 wherein the polyalkylene oxide is a polyethylene oxide.

Claim 9

The rheology modifier of claim 7 wherein the polyethylne oxide has a molecular weight of from about 4000 to about 12,000.

Claim 10

The rheology modifier of claim 8 wherein the diisocyanate is selected from the group consisting of toluene diisocyanate, isophorone diisocyanate, bis para-isocyanato cyclohexylmethane and mixtures thereof.

Claim 11

The rheology modifier of claim 1 wherein the rheology modifier is derived from the reaction of (a) for each 8 moles of the polyalkylene oxide; (b) from about 1 mole to about 3 moles of the polyfunctional material; (c) from about 6 moles to about 12 moles of the diisocyanate; (d) less than about 2.8 moles water; and (e) an amount of additional diisocyanate to compensate for any water present.

Claim 12

The rheology modifier of claim 10 wherein polyethylene oxide, trimethylolpropane, bis para-isocyanato cyclohexylmethane and water are reacted.

Claim 13

A process for making a urethane rheology modifier characterized in having a branched structure, substantially no terminal hydrophobic groups and capable of modifying the rheology properties of water-based and organic solvent-based compositions, comprising (1) blending in an inert organic solvent (a) for each 8 moles of a polyalkylene oxide having a molecular weight of from about 2,000 to about 20,000, (b) from about 0.1 mole to about 3 moles of a polyfunctional material, said material having at least 3 active hydrogens capable of reacting with isocyanate or being a polyisocyanate having at least 3 isocyanate groups, (c) from about 4 moles to about 15 moles of a diisocyanate, (d) less than about 3 moles water, and (e) an amount of additional diisocyanate to compensate for any water which is present and capable of consuming isocyanate functionality; and (2) reacting the mixture of step (1) until substantially no free isocyanate groups are present, so as to form the rheology modifier.

Claim 14

A process for making a urethane rheology modifier characterized in having a branched structure, substantially no terminal hydrophobic groups and capable of modifying the rheology properties of water-based and organic solvent-based compositions, comprising (1) blending in an inert organic solvent (a) for each 8 moles of a polyalkylene oxide having a molecular weight of from about 2,000 to about 20,000, (b) from about 0.1 mole to about 3 moles of a polyfunctional material, said material having at least 3 active hydrogens capable of reacting with isocyanate or being a polyisocyanate having at least 3 isocyanate groups, (c) from about 4 moles to about 15 moles of a diisocyanate, (d) less than about 3 moles water, and (e) an amount of additional diisocyanate to compensate for any water which is present and capable of consuming isocyanate functionality; and (2) reacting the mixture of step (1) until substantially no free isocyanate groups are present, so as to form the rheology modifier.

Claim 15

The process of claim 12 wherein the organic solvent is compatible with a water-based coating composition.

Claim 16

The process of claim 12 wherein the organic solvent is compatible with an organic solvent-based coating composition.

Claim 17

The process of claim 13 wherein the organic solvent is selected from the group consisting of 1-methyl-2-pyrrolidinone, dimethylformamide, dimethyl acetamide, gamma butyrolactone, dioxane, acetonitrile, dimethyl and diethyl ethers of ethylene glycol and diethylene glycol, and mixtures thereof.

Claim 18

The process of claim 15 wherein the organic solvent is 1-methyl-2-pyrrolidinone.

Claim 19

The process of claim 13 wherein a polyhydric material is added after substantially no free isocyanate groups are present.

Claim 20

The process of claim 17 wherein the polyhydric material is selected from the group consisting of ethylene glycol, propylene glycol, glycerine, and mixtures thereof.

Claim 21

The process of claim 18 wherein the polyhydric material is propylene glycol.

Claim 22

The process of claim 17 wherein the temperature of the mixture is maintained at from about 100° C. to about 130° C. while the polyhydric material is added.

Claim 23

The process of claim 12 wherein the mixture of step (1) is reacted at a temperature ranging from about 100° C. to about 130° C.

Claim 24

The process of claim 12 wherein the polyfunctional material is selected from the group consisting of polyols, amines, amine alcohols, thiols, polyisocyanates and mixtures thereof.

Claim 25

The process of claim 22 wherein the polyfunctional material is the polyisocyanate.

Claim 26

The process of claim 22 wherein the polyfunctional material is a trifunctional alcohol.

Claim 27

The process of claim 24 wherein the polyalkylene oxide is a polyethylene oxide having a molecular weight of from about 4,000 to about 12,000.

Claim 28

The process of claim 25 wherein the diisocyanate is selected from the group consisting of toluene diisocyanate, isophorone diisocyanate, bis para-isocyanato cyclohexylmethane and mixtures thereof.

Claim 29

The process of claim 26 wherein the mixture of step (1) comprises (a) for each 8 moles of the polyalkylene oxide, (b) from about 1 mole to about 3 moles of the polyfunctional material, (c) from about 6 moles to about 12 moles of the diisocyanate; (d) less than about 2.8 moles water; and (e) an amount of additional diisocyanate to compensate for any water present.

Claim 30

The process of claim 27 wherein polyethylene oxide, trimethylolpropane, bis para-isocyanato cyclohexylmethane and water are reacted.

Claim 31

A coating composition consisting essentially of a film forming polymeric resin and about 0.1% to about 10%, based on the film forming polymeric resin solids, of a rheology modifier, said modifier characterized in having a branched structure, substantially no terminal hydrophobic groups and derived from the reaction of (a) for each 8 moles of a polyalkylene oxide having a molecular weight of from about 2,000 to about 20,000, (b) from about 0.1 mole to about 3 moles of a polyfunctional material, said material having at least 3 active hydrogens capable of reacting with isocyanates or being a polyisocyanate having at least 3 isocyanate groups; (c) from about 4 moles to about 15 moles of a diisocyanate; (d) less than about 3 moles water; and (e) an amount of diisocyanate to compensate for any water which is present and capable of consuming isocyanate functionality.

Claim 32

A coating composition consisting essentially of a film forming polymeric resin and about 0.1% to about 10%, based on the film forming polymeric resin solids, of a rheology modifier, said modifier characterized in having a branched structure, substantially no terminal hydrophobic groups and derived from the reaction of (a) for each 8 moles of a polyalkylene oxide having a molecular weight of from about 2,000 to about 20,000, (b) from about 0.1 mole to about 3 moles of a polyfunctional material, said material having at least 3 active hydrogens capable of reacting with isocyanates or being a polyisocyanate having at least 3 isocyanate groups; (c) from about 4 moles to about 15 moles of a diisocyanate; (d) less than about 3 moles water; and (e) an amount of diisocyanate to compensate for any water which is present and capable of consuming isocyanate functionality.

Claim 33

The composition of claim 29 wherein the polyfunctional material is selected from the group consisting of polyols, amines, amine alcohols, thiols, polyisocyanates, and mixtures thereof.

Claim 34

The composition of claim 30 wherein the polyfunctional material is the polyisocyanate.

Claim 35

The composition of claim 30 wherein the polyfunctional material is the polyol.

Claim 36

The composition of claim 32 wherein the polyol is a trifunctional alcohol.

Claim 37

The composition of claim 33 wherein the trifunctional alcohol is trimethylolpropane.

Claim 38

The composition of claim 31 or 32 wherein the polyalkylene oxide is polyethylene oxide having a molecular weight of from about 4000 to about 12,000.

Claim 39

The composition of claim 35 wherein the diisocyanate is selected from the group consisting of toluene diisocyanate, isophorone diisocyanate, bis para-isocyanato cyclohexylmethane and mixtures thereof.

Claim 40

The composition of claim 29 wherein the rheology modifier is derived from (a) for each 8 moles of the polyalkylene oxide; (b) about 1 mole to about 3 moles of the polyfunctional material; (c) about 6 moles to about 12 moles of the diisocyanate; (d) less than about 2.8 moles water; and (e) an amount of additional diisocyanate to compensate for any water present.

Claim 41

The composition of claim 29 wherein the film-forming resin is an epoxy, vinyl, alkyd, polyester, acrylic, aminoplast, phenolplast, cellulose derivative, amide or urethane resin or mixture thereof.

Claim 42

The composition of claim 29 wherein the film-forming resin is a latex resin.

Claim 43

The composition of claim 39 wherein the composition contains from about 5% to about 70% of the polymeric film-forming resin.