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US4331737A Expired / Lapsed US ⏱️ 0.0 years remaining

Oxynitride film and its manufacturing method

Assignee: Zaidan Hojin Handotai Kenkyu Shinkokai
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Filing: 1980-12-11
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Granted: 1982-05-25
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Expires: 2000-12-11
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Abstract

Abstract The oxynitride film according to the present invention contains Ga and/or Al and has O/N ratio of at least 0.15. This film is obtained by relying on, for example, chemical vapor deposition technique. The O/N ratio in the film may be varied by, for example, varying the distance between the substrate and the substance-supply source, or by varying the proportion of an oxidizing gas contained in a carrier gas. This film is used either as a surface passivation film of III-V compound semiconductors such as GaAs, or as an insulating film for active surface portions of IG-FET, or as an optical anti-reflective film.

Inventors

  • 👤 Jun-ichi Nishizawa
  • 👤 Ikuo Shiota

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 15:41
CPC Classifications
H; H10; H10P; H10P14/00; H10P14/60; H10P14/69; H10P14/692; H10P14/6938; H10P14/6939; C; C23; C23C; C23C14/00; C23C14/06; C23C14/0676; C23C16/00; C23C16/22; C23C16/30; C23C16/308; H10D; H10D1/00; H10D1/60; H10D1/62; H10D1/66; H10D64/00; H10D64/01; H10D64/013; H10D64/01358; H10D64/60; H10D64/66; H10D64/68; H10D64/681; H10D64/685; H10D64/691; H10D64/693; H10P14/69391; H10P14/69397; H10P14/63; H10P14/6326; H10P14/6328; H10P14/6332; H10P14/6334; H10P14/6336; Y; Y10; Y10S; Y10S438/00; Y10S438/958; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31678

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 80 words
A Group III-V semiconductor substrate wherein the semiconductor is formed with at least one element of the Group III elements and at least one element of the Group V elements in the periodic table, said substrate having a main surface; a film formed on said substate and substantially formed of oxynitride of at least one substance selected from the group consisting of gallium, aluminum and their mixture, said oxynitride having a finite O/N ratio by atomic fraction greater than 0.15.
Claim 2
Dependent Claim 80 words
A Group III-V semiconductor substrate wherein the semiconductor is formed with at least one element of the Group III elements and at least one element of the Group V elements in the periodic table, said substrate having a main surface; a film formed on said substate and substantially formed of oxynitride of at least one substance selected from the group consisting of gallium, aluminum and their mixture, said oxynitride having a finite O/N ratio by atomic fraction greater than 0.15.
Claim 3
Dependent Claim 62 words
A combination according to claim 1, further comprising: a conductive layer provided at least locally on said film, that side of said film located opposite to the side contacting said main surface, said substrate comprising a pair of heavily doped regions exposed at said main surface and partially contacting said film, said regions having conductivity type opposite to that of said substrate.
Claim 4
Dependent Claim 25 words
A combination according to claim 1, in which: said substrate comprises at least one pn junction terminating at said main surface covered with said film.
Claim 5
Dependent Claim 33 words
A combination according to claim 1, in which: said substrate comprises at least one boundary between space charge region and neutral region, said boundary terminating at said main surface covered with said film.
Claim 6
Dependent Claim 26 words
A combination according to claim 1, further comprising at least one layer of insulating film other than said oxynitride film of gallium, aluminum, or their mixture.
Claim 7
Dependent Claim 73 words
A combination according to claim 1, in which: said film is formed at least locally on the main surface of said group III-V semiconductor substrate and has a non-uniform composition distribution that the O/N ratio by atomic fraction in that side of the film contacting the main surface of said substrate is small and that this ratio increases at the region located within thickness of said film and being apart from said side.
Claim 8
Dependent Claim 18 words
A combination according to claim 6, in which: said O/N ratio by atomic fraction is at least 0.2.
Claim 9
Dependent Claim 18 words
A combination according to claim 6, in which: said O/N ratio by atomic fraction is at least 0.3.
Claim 10
Dependent Claim 21 words
A combination according to claim 6 in which: the O/N ratio by atomic fraction of said region is at least 0.3.
Claim 11
Dependent Claim 32 words
A combination according to claim 6 further comprising a conductive layer at least locally on that side of said film located opposite to the side contacting the main surface of said substrate.
Claim 12
Dependent Claim 79 words
A combination according to claim 1, in which: said film is formed at least locally on the main surface of said Group III-V semiconductor substrate and has a non-uniform composition distribution that the O/N ratio by atomic fraction in that side of the film contacting the main surface of the substrate is small and that this ratio increases continuously in such a manner through the thickness of said film that said ratio takes a minimal value at said side.
Claim 13
Dependent Claim 18 words
A combination according to claim 11, in which: said O/N ratio by atomic fraction is at least 0.2.
Claim 14
Dependent Claim 18 words
A combination according to claim 11, in which: said O/N ratio by atomic fraction is at least 0.3.
Claim 15
Dependent Claim 33 words
A combination according to claim 1, further comprising a conductive layer formed at least locally on that side of said film located opposite to the side contacting the main surface of said substrate.
Claim 16
Dependent Claim 38 words
A combination according to claim 14, further comprising at least one layer of insulating film other than said oxynitride film of gallium, aluminum, or their mixture, at a site located between the conductive layer and said oxynitride film.
Claim 17
Dependent Claim 32 words
A combination according to claim 1 wherein the semiconductor is formed with at least one of the elements gallium, aluminum, and indium and at least one of the elements arsenic and phosphorus.
Claim 18
Dependent Claim 11 words
A combination according to claim 16 wherein the semiconductor is GaAs.
Claim 19
Dependent Claim 15 words
A combination according to claim 16 wherein the semiconductor is Ga x Al 1-x As.
Claim 20
Dependent Claim 15 words
A combination according to claim 16 wherein the semiconductor is GaAs x P 1-x .
Claim 21
Dependent Claim 19 words
A combination according to claim 16 wherein the semiconductor is In x GA 1-x As y P 1-y .

References Cited (Backward Citations)

US4018631A Cited
US4172906A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-05-24 1985-11-23 1986-05-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-05-24 1989-11-23 1990-05-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-05-24 1993-11-23 1994-05-25 $7700.00 Window Closed / Lapsed

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