Curable resin composition

Claim 2

In a curable resin composition comprising a mixture and/or a preliminary reaction product of: (A) at least one component selected from the group consisting of: (i) a polyfunctional cyanate ester monomer having the formula: R--O--C.tbd.N)m wherein m is an integer of 2 to 5 and R is an aromatic organic group, the cyanate groups being directly bonded to the aromatic nucleus of said aromatic organic group, (ii) a prepolymer of (i), and (iii) a coprepolymer of (i) and an amine; and (B) another compound, the improvement wherein said another compound is a polyamideimide obtainable by the reaction of trimellitic anhydride with aromatic diamine or aromatic diisocyanate, or the reaction of pyromellitic anhydride, aromatic diamine and aromatic dicarboxylic acid or aromatic aminocarboxylic acid.

Claim 3

The composition as defined in claim 1 wherein the cyanate ester is selected from the group consisting of 1,3-, 1,4-dicyanatobenzene; 1,3,5-tricyanatobenzene; 1,3-, 1,4-, 1,6-, 1,8- 2,6- or 2,7-dicyanatonaphthalene; 1,3,6-tri-cyanatonaphthalene; 4,4'-dicyanatobiphenyl; bis(4-cyanatophenyl)methane; 2,2-bis(4-cyanatophenyl)propane, 2,2-bis(3,5-dichloro-4-cyanatophenyl)propane, 2,2-bis(3,5-dibromo-4-dicyanatophenyl)propane; bis(4-cyanatophenyl)ester; bis(4-cyanatophenyl)thioether; bis(4-cyanatophenyl)sulfone; tris(4-cyanatophenyl)phosphite; tris(4-cyanatophenyl)phosphate; bis(3-chloro-4-cyanatophenyl)methane; cyanated novolak derived from novolak cyanated bisphenol type polycarbonate oligomer derived from bisphenol type polycarbonate oligomer and mixture thereof.

Claim 4

The composition as defined in claim 1 wherein the ratio by weight of component (a) to component (b) is in the range of from 99:1 to 1:99.

Claim 5

In a curable resin composition comprising a mixture and/or a preliminary reaction product of: (A) at least one component selected from the group consisting of: (i) a polyfunctional cyanate ester monomer having the formula: R--O--C.tbd.N)m wherein m is an integer of 2 to 5 and R is an aromatic organic group, the cyanate groups being directly bonded to the aromatic nucleus of said aromatic organic group, (ii) a prepolymer of (i), and (iii) a coprepolymer of (i) and an amine; (B) another compound; and (C) at least one compound selected from the group consisting of: (i) a polyfunctional maleimide, (ii) a prepolymer of (C) (i), and (iii) a coprepolymer of (C) (i) and an amine, the improvement wherein said another compound is a polyamideimide obtainable by the reaction of trimellitic anhydride with aromatic diamine or aromatic diisocyanate, or the reaction of pyromellitic anhydride, aromatic diamine and aromatic dicarboxylic acid or aromatic aminocarboxylic acid.

Claim 6

In a curable resin composition comprising a mixture and/or a preliminary reaction product of: (A) at least one component selected from the group consisting of: (i) a polyfunctional cyanate ester monomer having the formula: R--O--C.tbd.N)m wherein m is an integer of 2 to 5 and R is an aromatic organic group, the cyanate groups being directly bonded to the aromatic nucleus of said aromatic organic group, (ii) a prepolymer of (i), and (iii) a coprepolymer of (i) and an amine; (B) another compound; and (C) at least one compound selected from the group consisting of: (i) a polyfunctional maleimide, (ii) a prepolymer of (C) (i), and (iii) a coprepolymer of (C) (i) and an amine, the improvement wherein said another compound is a polyamideimide obtainable by the reaction of trimellitic anhydride with aromatic diamine or aromatic diisocyanate, or the reaction of pyromellitic anhydride, aromatic diamine and aromatic dicarboxylic acid or aromatic aminocarboxylic acid.

Claim 7

The composition as defined in claim 4 wherein the cyanate ester is selected from the group consisting of 1,3-, 1,4-dicyanatobenzene; 1,3,5-tricyanatobenzene; 1,3-, 1,4-, 1,6-, 1,8-, 2,6- or 2,7-dicyanatonaphthalene; 1,3,6-tricyanatonaphthalene; 4,4'-dicyanatobiphenyl; bis(4-cyanatophenyl)methane; 2,2-bis(4-cyanatophenyl)propane, 2,2-bis(3,5-dichloro-4-cyanatophenyl)propane, 2,2-bis(3,5-dibromo-4-dicyanatophenyl)propane; bis(4-cyanatophenyl)ether; bis(4-cyanatophenyl)thioether; bis(4-cyanatophenyl)sulfone; tris(4-cyanatophenyl)phosphite; tris(4-cyanatophenyl)phosphate; bis(3-chloro-4-cyanatophenyl)methane; cyanated novolak derived from novolak cyanated bisphenol type polycarbonate oligomer derived from bisphenol type polycarbonate oligomer and mixture thereof.

Claim 8

The composition as defined in claim 4 wherein the ratio by weight of component (a) to component (b) is in the range of from 99:1 to 1:99.

Claim 9

A curable resin composition in accordance with claim 1 wherein said component (A) comprises a cyanate ester component comprising at least one component selected from the group consisting of: (1) said polyfunctional aromatic cyanate ester monomer, (2) prepolymers of (1), and (3) coprepolymers of (1) and an amine, said amine being selected from the group consisting of meta- or para-phenylenediamine, meta- or para-xylylenediamine, 1,4- or 1,3-cyclohexanediamine, hexahydroxylylenediamine, 4,4'-diaminobiphenyl, bis(4-aminophenyl)methane, bis(4-aminophenyl)ether, bis(4-aminophenyl)sulfone, bis(4-amino-3-methylphenyl)methane, bis(3-chloro-4-aminophenyl)methane, bis(4-amino-3,5-dimethylphenyl)methane, bis(4-aminophenyl)cyclohexane, 2,2-(4-aminophenyl)propane, 2,2bis(4-amino-3-methylphenyl)propane, 2,2-bis(3,5-dibromo-4-aminophenyl)propane, bis(4-aminophenyl)phenylmethane, 3,4-diaminophenyl-4'-aminophenylmethane and 1,1-bis(4-aminophenyl)-1-phenylethane.

Claim 10

A curable resin composition in accordance with claim 4 wherein said component (A) comprises a cyanate ester component comprising at least one component selected from the group consisting of: (1) said polyfunctional aromatic cyanate ester monomer, (2) prepolymers of (1), and (3) coprepolymers of (1) and an amine, said amine being selected from the group consisting of meta- or para-phenylenediamine, meta- or para-xylylenediamine, 1,4- or 1,3-cyclohexanediamine, hexahydroxylylenediamine, 4,4'-diaminobiphenyl, bis(4-aminophenyl)methane, bis(4-aminophenyl)ether, bis(4-aminophenyl)sulfone, bis(4-amino-3-methylphenyl)methane, bis(3-chloro-4-aminophenyl)methane, bis(4-amino-3,5-dimethylphenyl)methane, bis(4-aminophenyl)cyclohexane, 2,2-(4-aminophenyl)propane, 2,2-bis(4-amino-3-methylphenyl)propane, 2,2-bis(3,5-dibromo-4-aminophenyl)propane, bis(4-aminophenyl)phenylmethane, 3,4-diaminophenyl-4'-aminophenylmethane and 1,1-bis(4-aminophenyl)-1-phenylethane.

Claim 11

A curable resin composition in accordance with claim 4 or claim 8, wherein said component (C) comprises: at least one maleimide compound selected from the group consisting of (a) a polyfunctional maleimide having the formula: ##STR4## wherein R' is a divalent to pentavalent aromatic or alicyclic organic group, each of X 1 and X 2 represents a hydrogen atom, halogen atom or alkyl group, and n is an integer of 2 to 5, (b) a prepolymer of (a), and (c) a coprepolymer of (a) and an amine, said amine being selected from the group consisting of meta- or para-phenylenediamine, meta- or para-xylylenediamine, 1,4- or 1,3-cyclohexanediamine, hexahydroxylylenediamine, 4,4'-diaminobiphenyl, bis(4-aminophenyl)methane, bis(4-aminophenyl)ether, bis(4-aminophenyl)sulfone, bis(4-amino-3-methylphenyl)methane, bis(3-chloro-4-aminophenyl)methane, bis(4-amino-3,5-dimethylphenyl)methane, bis(4-aminophenyl)cyclohexane, 2,2-(4-aminophenyl)propane, 2,2-bis(4-amino-3-methylphenyl)propane, 2,2-bis(3,5-dibromo-4-aminophenyl)propane, bis(4-aminophenyl)phenylmethane, 3,4-diaminophenyl-4'-aminophenylmethane, 1,1-bis(4-aminophenyl)-1-phenylethane, melamine having s-triazine ring, and a polyamine obtainable by reaction of aniline with formaldehyde, in which two or more benzene rings are bonded through a methylene bond.