Process for toning tacky image surfaces with dry nonelectroscopic toners

Claim 2

A process for color development of a surface having imagewise tacky and nontacky areas which comprises (a) applying to the image-bearing surface dry nonelectroscopic toner comprising pigmented organic resin particles having a size distribution within the range of 0.2 to 30 micrometers and not more than 50 percent of the particles being less than 1 micrometer particle size, the improvement whereby the pigmented particles are surface coated with at least 1% by weight of an antistatic agent in combination with at least 0.5% by weight of slip agent selected from the class consisting of silicone oil having a weight average molecular weight of about 230 to 50,000; saturated hydrocarbons having a weight average molecular weight of about 200 to 10,000; and fluorocarbon compounds having a weight average molecular weight of 500 to 500,000 and (b) distributing the toner particles over the image surface whereby the distributed toner particles become embedded solely in the tacky image areas, and (c) physically removing toner particles from the nontacky areas which are left substantially free of the toner particles.

Claim 3

A process according to claim 1 wherein the tacky surface is present in a photopolymerizable layer.

Claim 4

A process according to claim 1 wherein the tacky surface is present in an imagewise exposed photosensitive layer comprising at least one thermoplastic binder and a photosensitive system, consisting essentially of I. at least one dihydropyridine compound of the formula ##STR6## wherein R is alkyl, alkenyl of 3 to 11 carbon atoms, phenylalkyl, phenylalkenyl, unsubstituted aryl of 6 to 10 carbon atoms, and heteroaryl, R 1 and R 2 , which can be the same or different, are alkyl, and R 3 and R 4 , which can be the same or different, are COOR', COR', CN, R' is alkyl; and II. at least one hexaarylbiimidazole compound.

Claim 5

A process according to claim 1 wherein the tacky surface is present in an imagewise exposed element consisting nontonable image areas and tacky nonphotosensitive image areas.

Claim 6

A process according to claim 1 wherein a surprint multicolor proof is formed by laminating at least one other tonable photoimagable layer over the previously imagewise toned layer, each tonable photoimagable layer being exposed through a different color separation transparency and the respective layer having been colored with toners in a spectral region corresponding to the color separation transparency used for exposure.

Claim 7

A process according to claim 5 wherein four photoimaged toned elements are present in the surprint multicolor proof and the toned element and separation transparencies correspond, respectively, to yellow, magenta, cyan and black.

Claim 8

A process according to claim 1 wherein the slip agent on the toner surface is polydimethylsiloxane or polymethyl(X)siloxane where X is an alkyl chain with 2 to 12 carbon atoms.

Claim 9

A process according to claim 1 wherein the antistatic agent on the toner surface is an anionic antistatic agent.

Claim 10

A process according to claim 8 wherein the anionic antistatic agent is a member taken from the group consisting of: (a) sodium alkyl benzene sulfonate wherein alkyl is an alkyl chain with 8 to 18 carbon atoms; (b) sodium alkyl sulfonate wherein alkyl is an alkyl chain with 10 to 20 carbon atoms; (c) secondary alkyl sulfate wherein one or both alkyl groups are substituted with functional groups taken from the group consisting of ester, ether, and alcohol, the alkyl being an alkyl chain of 1 to 18 carbon atoms; (d) phosphorous-containing compound of the formula (RO) m P(O(OX) n wherein R is an alkyl chain with 4 to 18 carbon atoms, X is an cation taken from the group consisting of H, K, Na, NH 4 , m is 1 or 2 and n is 2 or 1; and (e) amine salt of alkyl sulfate wherein alkyl is an alkyl chain of 8 to 18 carbon atoms and amine is taken from the group consisting of ammonia, diethyanolamine, triethanolamine and diethylcyclohexyl amine.

Claim 11

A process according to claim 1 wherein the antistatic agent on the toner surface is a cationic antistatic agent.

Claim 12

A process according to claim 10 wherein the cationic antistatic agent is a member taken from the group consisting of (a) alkyl trimethyl ammonium bromide wherein alkyl is an alkyl chain with 1 to 18 carbon atoms; and (b) Quaternary ammonium compounds of the formula: ##STR7## wherein R and R 1 may be a saturated or unsaturated alkyl chain with 1 to 24 carbon atoms or mixtures thereof, R 2 may be an alkyl chain of 1 to 24 carbon atoms or R 3 wherein R 3 is a polyether substituent of the formula --(CH 2 CH 2 O) m --[CH 2 CH(CH 3 )O] n --H wherein m and n may be 0 to 20, the total of m and n being at least 1, and X is an anion taken from the group consisting of CH 3 SO 4 , C 2 H 5 SO 4 , (CH 3 ) 2 PO 4 , (C 2 H 5 ) 2 PO 4 ; the total number of carbon atoms in R,R 1 and R 2 should not exceed 38.

Claim 13

A process according to claim 1 wherein the antistatic agent on the toner surface is an amphoteric antistatic agent.

Claim 14

A process according to claim 12 wherein the amphoteric antistatic agent is taken from the class consisting of alkyl bis(polyethanoxy)-gamma-sulfopropyl betaine and alkyl bis(hydroxyethyl)-gamma-sulfopropyl betaine wherein alkyl is an alkyl chain with 12 to 14 carbon atoms and in the former the number of polyether units is 1 to 4.

Claim 15

A process according to claim 1 wherein the antistatic agent is a nonionic antistatic agent.

Claim 16

A process according to claim 14 wherein the nonionic antistatic agent is a member taken from the group consisting of a compound of the formula: (a) R(OCH 2 CH 2 ) n --OH wherein R is a saturated and unsaturated alkyl chain with 12 to 18 carbon atoms or CH 3 (CH 2 ) 7 --CH═CH(CH 2 ) 8 --, and n is 2 to 10; (b) R(OCH 2 CH 2 ) m [OCH 2 CH(CH 3 )] n --OH wherein R is an alkyl chain with 12 to 18 carbon atoms, m is 0 to 10 and n is 1 to 10; and (c) mono and diglycerides of carboxylic acids having an alkyl chain of 12 to 18 carbon atoms.

Claim 17

A process according to claim 1 wherein the pigmented resin particles are comprised of cellulose acetate particles having pigment particles embedded in their surfaces.

Claim 18

A process for automatic color development of a surface having imagewise tacky and nontacky areas by dispensing and embedding dry particulate toners on the surface by means of an automatic toning apparatus having a dispenser for dispensing said toner above said surface, and an applicator for embedding said particulate toners in said surface, and means for moving the tacky surface past the dispenser and said applicator, the dispenser includes a hopper having an independently movable side wall, and means to oscillate the side wall laterally of the tacky surface, thereby to supply the particulate material to the surface at a uniform, controlled rate, the improvement wherein dry, nonelectroscopic toners comprising pigmented organic resin particles having a size distribution within the range of 0.2 to 30 micrometers and not more than 50 percent of the particles being less than 1 micrometer particle size are surface coated with at least 1% by weight of an antistatic agent in combination with at least 0.5% by weight of slip agent selected from the class consisting of silicone oil having a weight average molecular weight of about 230 to 50,000; saturated hydrocarbons having a weight average molecular weight of about 200 to 10,000; and fluorocarbon compounds having a weight average molecular weight of 500 to 500,000 are automatically dispensed, embedded, and the excess removed.

Claim 19

A process for automatic color development of a surface having imagewise tacky and nontacky areas by dispensing and embedding dry particulate toners on the surface by means of an automatic toning apparatus having a dispenser for dispensing said toner above said surface, and an applicator for embedding said particulate toners in said surface, and means for moving the tacky surface past the dispenser and said applicator, the dispenser includes a hopper having an independently movable side wall, and means to oscillate the side wall laterally of the tacky surface, thereby to supply the particulate material to the surface at a uniform, controlled rate, the improvement wherein dry, nonelectroscopic toners comprising pigmented organic resin particles having a size distribution within the range of 0.2 to 30 micrometers and not more than 50 percent of the particles being less than 1 micrometer particle size are surface coated with at least 1% by weight of an antistatic agent in combination with at least 0.5% by weight of slip agent selected from the class consisting of silicone oil having a weight average molecular weight of about 230 to 50,000; saturated hydrocarbons having a weight average molecular weight of about 200 to 10,000; and fluorocarbon compounds having a weight average molecular weight of 500 to 500,000 are automatically dispensed, embedded, and the excess removed.

Claim 20

A process according to claim 17 wherein the tacky surface is present in a photopolymerizable layer.

Claim 21

A process according to claim 17 wherein the tacky surface is present in an imagewise exposed photosensitive layer comprising at least one thermoplastic binder and a photosensitive system, consisting essentially of I. at least one dihydropyridine compound of the formula ##STR8## wherein R is alkyl, alkenyl of 3 to 11 carbon atoms, phenylalkyl, phenylalkenyl, unsubstituted aryl of 6 to 10 carbon atoms, and heteroaryl, R 1 and R 2 , which can be the same or different, are alkyl, and R 3 and R 4 , which can be the same or different, are COOR', COR', CN, R' is alkyl; and II. at least one hexaarylbiimidazole compound.

Claim 22

A process according to claim 17 wherein the tacky surface is present in an imagewise exposed element containing nontonable image areas and tacky nonphotosensitive image areas.