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US4329441A
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Process for the polymerization of allyl ammonium salts and the resulting products
Assignee: Agfa Gevaert AG
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Filing: 1980-11-12
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Granted: 1982-05-11
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Expires: 2000-11-12
Abstract
Abstract A process for the polymerization of allyl ammonium salts is disclosed wherein allyl ammonium salt is polymerized in the presence of a phosphorus compound.
Inventors
- 👤 Peter Bergthaller
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 12:42
CPC Classifications
C; C08; C08F; C08F26/00; C08F26/02
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
224 words
A process for the polymerisation of allyl ammonium salts, wherein a compound corresponding to the following formula ##STR7## in which R 1 and R 2 which may be the same or different and represent hydrogen; an aliphatic, araliphatic or cycloaliphatic radical which may be substituted or R 1 and R 2 may together represent the atoms required to complete a 5- to 7-membered heterocyclic group; R 3 to R 5 which may be the same or different, represent hydrogen or an alkyl radical which may be substituted, A is an anion and/or R 3 represents the radical (--CR.sup.5 R.sup.4 --NR.sup.1 R.sup.2 H).sup.+ A is polymerised in the presence of a phosphorus compound corresponding to the following formula ##STR8## in which R 20 and R 21 which may be the same or different, represent hydrogen; an alkyl group which may be substituted; an aryl group which may be substituted; hydroxyl; alkoxy; aralkyl; aralkoxy; dialkylamino; or R 20 and R 21 represent the group --O--R 23 --O-- where R 23 is an alkyl radical which may be substituted containing no more than 6 carbon atoms, R 22 represents hydrogen; an acyl group which may be substituted; alkyl; dialkylamino; X represents a single electron pair or an oxygen atom, X represents a single electron pair when none of the substituents R 20 to R 22 represents hydrogen.
Claim 2
Dependent Claim
224 words
A process for the polymerisation of allyl ammonium salts, wherein a compound corresponding to the following formula ##STR7## in which R 1 and R 2 which may be the same or different and represent hydrogen; an aliphatic, araliphatic or cycloaliphatic radical which may be substituted or R 1 and R 2 may together represent the atoms required to complete a 5- to 7-membered heterocyclic group; R 3 to R 5 which may be the same or different, represent hydrogen or an alkyl radical which may be substituted, A is an anion and/or R 3 represents the radical (--CR.sup.5 R.sup.4 --NR.sup.1 R.sup.2 H).sup.+ A is polymerised in the presence of a phosphorus compound corresponding to the following formula ##STR8## in which R 20 and R 21 which may be the same or different, represent hydrogen; an alkyl group which may be substituted; an aryl group which may be substituted; hydroxyl; alkoxy; aralkyl; aralkoxy; dialkylamino; or R 20 and R 21 represent the group --O--R 23 --O-- where R 23 is an alkyl radical which may be substituted containing no more than 6 carbon atoms, R 22 represents hydrogen; an acyl group which may be substituted; alkyl; dialkylamino; X represents a single electron pair or an oxygen atom, X represents a single electron pair when none of the substituents R 20 to R 22 represents hydrogen.
Claim 3
Dependent Claim
24 words
A process as claimed in claim 1, wherein the polymerisation is carried out at a temperature in the range from 60° to 90° C.
Claim 4
Dependent Claim
23 words
A process as claimed in claim 1, wherein the phosphorus atom in the compound (II) is present in the oxidation state of +3.
Claim 5
Dependent Claim
25 words
A process as claimed in claim 1, wherein the polymerisation reaction is carried out with copolymerisation of an ethylenically unsaturated comonomer of the acryl type.
Claim 6
Dependent Claim
18 words
A process as claimed in claim 4, wherein the polymerisation reaction is carried out with allyl ammonium salts.
Claim 7
Dependent Claim
91 words
A process as claimed in claim 1, wherein R 1 , R 2 , R 4 , R 5 represent hydrogen R 3 represents hydrogen; CH 2 NH 2 R 1 or methyl A represents chloride R 20 and R 21 represent hydrogen; alkyl containing from 1 to 12 carbon atoms which may be substituted; phenyl; hydroxy; alkoxy containing from 1 to 12 carbon atoms; benzyl or aralkoxy; R 22 represents hydrogen; acetyl, pivaloyl, butyryl, benzoyl or alkyl containing from 1 to 12 carbon atoms and X represents an oxygen atom.
Claim 8
Dependent Claim
24 words
A process as claimed in claim 6, wherein the comound of formula (II) is phosphorus acid or a monoester or diester of phosphorous acid.
Claim 9
Dependent Claim
50 words
A process as claimed in claim 1, wherein the compound of formula (I) is a salt of allyl amine and in that the compound of formula (II) is at least one of the following substances: dibutyl phosphite; diethyl phosphite; phenyl phosphinic acid; phenyl phosphinic acid butyl ester or hypophosphorous acid.
Claim 10
Dependent Claim
17 words
A process as claimed in claim 8, wherein acrylamide and/or acrylic acid is used as additional comonomer.
Claim 11
Dependent Claim
80 words
Polymers containing recurring units of the following formula: ##STR9## in which R 1 and R 2 which may be the same or different, represent hydrogen; an aliphatic, araliphatic or cycloaliphatic radical which may be substituted or R 1 and R 2 may together represent the atoms required to complete a 5-membered to 7-membered heterocylic group, and R 3 to R 5 which may be the same or different represent hydrogen or alkyl which may be substituted, or a salt thereof.
Claim 12
Dependent Claim
80 words
Polymers containing recurring units of the following formula: ##STR9## in which R 1 and R 2 which may be the same or different, represent hydrogen; an aliphatic, araliphatic or cycloaliphatic radical which may be substituted or R 1 and R 2 may together represent the atoms required to complete a 5-membered to 7-membered heterocylic group, and R 3 to R 5 which may be the same or different represent hydrogen or alkyl which may be substituted, or a salt thereof.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-05-10 | 1985-11-09 | 1986-05-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-05-10 | 1989-11-09 | 1990-05-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-05-10 | 1993-11-09 | 1994-05-11 | $7700.00 | Window Closed / Lapsed |