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US4324822A Expired / Lapsed US ⏱️ 0.0 years remaining

Metal can paint providing coating retaining high adhesion even with lapse of time

Assignee: Toyo Seikan Group Holdings Ltd
•
Filing: 1980-07-03
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Granted: 1982-04-13
•
Expires: 2000-07-03
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Abstract

Abstract Disclosed is a paint for a can which comprises an epoxy resin component formed by condensation of a dihydroxyl compound with an epihalohydrin and a curing agent component, said epoxy resin component containing terminal α-glycol groups at a concentration of 0.05 to 0.60 equivalent per Kg of the resin. This paint provides a coating capable of retaining a high adhesion even with the lapse of time and resisting a severe treatment such as retort sterilization. When this paint is applied to a bonded can, leakage of the content from the side seam with the lapse of time can be effectively prevented. When this paint is applied to a can provided with an easy-open can lid, occurrence of the enamel feather can be prevented at the time of opening the lid.

Inventors

  • 👤 Seishichi Kobayashi
  • 👤 Tatsuo Mori
  • 👤 Akihiko Morofuji

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 22:22
CPC Classifications
C; C09; C09D; C09D163/00; C08; C08G; C08G12/00; C08G12/02; C08G12/04; C08G12/10; C08G12/12; C08G59/00; C08G59/14; C08G59/1405; C08G59/1427; C08G59/18; C08G59/40; C08G59/4007; C08G59/4014; C08G59/4021; C08G59/42; C08G8/00; C08G8/04; C08G8/08; C08G8/24; Y; Y10; Y10T; Y10T428/00; Y10T428/13; Y10T428/1352; Y10T428/1355; Y10T428/31504; Y10T428/31511; Y10T428/31529

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 65 words
A paint for cans which comprises (1) an epoxy resin component formed by condensation of a dihydroxyl compound with an epihalohydrin and (2) a curing agent component, said epoxy resin component containing terminal α-glycol groups at a concentration of 0.05 to 0.60 equivalents per Kg of the resin, and terminal epoxy groups at a concentration of 0.20 to 1.80 equivalents per Kg of the resin.
Claim 2
Dependent Claim 65 words
A paint for cans which comprises (1) an epoxy resin component formed by condensation of a dihydroxyl compound with an epihalohydrin and (2) a curing agent component, said epoxy resin component containing terminal α-glycol groups at a concentration of 0.05 to 0.60 equivalents per Kg of the resin, and terminal epoxy groups at a concentration of 0.20 to 1.80 equivalents per Kg of the resin.
Claim 3
Dependent Claim 42 words
A paint as set forth in claim 1 wherein the epoxy resin component is an epoxy resin in which the terminal α-glycol groups and the terminal epoxy groups are present at a molar ratio in the range of from 5/95 to 75/25.
Claim 4
Dependent Claim 172 words
A paint as set forth in claim 1 or 2 wherein the epoxy resin component is an epoxy resin represented by the following general formula: ##STR9## wherein R stands for a divalent residue formed by removing two hydroxyl groups from a dihydroxyl compound, espccially an alkylene or arylene group having 2 to 20 carbon atoms or a combination thereof, Y stands for ##STR10## or a hydrogen atom, with the proviso that the following conditions (a) to (d) are satisfied: (a) the concentration of ##STR11## is 0.05 to 0.60 equivalent per Kg of the resin, (b) the concentration of ##STR12## is 0.20 to 1.80 equivalents per Kg of the resin, (c) the molar ratio of ##STR13## is in the range of from 5/95 to 75/25 and (d) terminal hydroxyl groups derived from a dihydroxyl compound may be present in an amount of up to 50 mol % based on the total terminal groups, and n is a number selected so that the number average molecular weight of the resin is 900 to 5500.
Claim 5
Dependent Claim 29 words
A paint as set forth in claim 1 wherein the epoxy resin component is an epoxy resin formed by condensation of an epihalohydrin with bisphenol A or bisphenol B.
Claim 6
Dependent Claim 61 words
A solution-type can paint as set forth in claim 1 wherein the curing agent component is a resinous curing agent selected from the group consisting of phenol-formaldehyde resins, urea-formaldehyde resins, malamine-formaldehyde resins, acrylic resins, alkyd resins and polyamide resins and the resinous curing agent is present in an amount of 5 to 60% by weight based on the epoxy resin component.
Claim 7
Dependent Claim 40 words
A powdery can paint as set forth in claim 1 wherein the curing agent component is an acid anhydride or dicyandiamide and is present in an amount of 3 to 40% by weight based on the solid epoxy resin component.
Claim 8
Dependent Claim 31 words
A coated metal can which is coated and baked at least on the inner face of a can lid or can body with the paint as set forth in claim 1.

References Cited (Backward Citations)

US2558949A Cited
US3405093A Cited
US3477990A Cited
US3921847A Cited
US3932144A Cited
US4215210A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-04-12 1985-10-12 1986-04-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-04-12 1989-10-12 1990-04-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-04-12 1993-10-12 1994-04-13 $7700.00 Window Closed / Lapsed

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