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US4323599A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for achieving particle-to-particle contact in an antifouling coating

Assignee: Standard Oil Co
•
Filing: 1979-11-28
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Granted: 1982-04-06
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Expires: 1999-11-28
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Abstract

Abstract Copper flake is treated to remove oxides and other contaminants from its surface and incorporated into an uncured water-insoluble polymer. When applied to a marine structure such as a boat hull, the coating exhibits outstanding anti-fouling properties. The cleaned copper flake is preferably incorporated into an uncured epoxy resin modified by reaction with a polyol. In one embodiment of the invention, the coating is applied and cured underwater using a strippable carrier.

Inventors

  • 👤 David W. Marshall

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 00:14
CPC Classifications
C; C09; C09D; C09D5/00; C09D5/16; C09D5/1656; C09D5/1662; B; B05; B05D; B05D1/00; B05D1/28; B05D1/286; B05D7/00; B05D7/22; B05D7/222; C08; C08G; C08G59/00; C08G59/18; C08G59/20; C08G59/22; C08G59/226; C09D163/00; C09D5/1606; C09D5/1612; C09D5/1618; Y; Y10; Y10S; Y10S428/00; Y10S428/907; Y10T; Y10T428/00; Y10T428/15; Y10T428/25; Y10T428/256; Y10T428/31504; Y10T428/31511; Y10T428/31529

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 85 words
A method for controlling fouling of the surface of a water pipe interior or a submergible or submerged marine structure by applying a copper-containing polymeric coating, said method comprising: (a) providing the copper in flake form; (b) cleaning the copper flake to remove substantially all contaminating surface deposits; (c) mixing the cleaned copper flake with an uncured water-insoluble polymer; (d) applying the mixture as a coating onto the surface of the water pipe interior or submergible or submerged marine structure; and (e) curing the coating.
Claim 2
Independent Claim 85 words
A method for controlling fouling of the surface of a water pipe interior or a submergible or submerged marine structure by applying a copper-containing polymeric coating, said method comprising: (a) providing the copper in flake form; (b) cleaning the copper flake to remove substantially all contaminating surface deposits; (c) mixing the cleaned copper flake with an uncured water-insoluble polymer; (d) applying the mixture as a coating onto the surface of the water pipe interior or submergible or submerged marine structure; and (e) curing the coating.
Claim 3
Dependent Claim 15 words
The method of claim 1 wherein said water-insoluble polymer is an epoxy or polyester resin.
Claim 4
Dependent Claim 18 words
The method of claim 1 wherein said water-insoluble polymer is an epoxy resin modified with an epoxidized polyol.
Claim 5
Dependent Claim 28 words
The method of claim 3 wherein the copper flake is incorporated into the resin in a quantity sufficient to render the entire thickness of the coating electrically conductive.
Claim 6
Dependent Claim 19 words
The method of claim 4 wherein the copper flake constitutes 25% to 60% by weight of the uncured mixture.
Claim 7
Dependent Claim 25 words
The method of claim 1, 3 or 4 wherein the cleaning is accomplished by contacting the coper flake with an organic solvent and an acid.
Claim 8
Dependent Claim 41 words
The method of claim 6 wherein said solvent is selected from the group consisting of haloalkylenes of 1-3 carbon atoms, ethers, ketones and aromatic solvents and said acid is selected from the group consisting of dilute mineral acids and polycarboxylic acids.
Claim 9
Dependent Claim 17 words
The method of claim 1, 3 or 4 wherein the coating is applied to a boat hull.
Claim 10
Dependent Claim 41 words
The method of claim 1, 3 or 4 wherein the mixture is first applied as a coating to a strippable carrier, then the coating is contacted against an underwater surface and the carrier is stripped off after the coating is cured.

References Cited (Backward Citations)

US3983075A Cited
US4115130A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-04-05 1985-10-05 1986-04-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-04-05 1989-10-05 1990-04-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-04-05 1993-10-05 1994-04-06 $7700.00 Window Closed / Lapsed

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