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US4323463A Expired / Lapsed US ⏱️ 0.0 years remaining

Secondary recovery process

Assignee: Texaco Inc
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Filing: 1980-06-11
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Granted: 1982-04-06
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Expires: 2000-06-11
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Abstract

Abstract Hydrocarbons are recovered from a subterranean hydrocarbon-bearing formation penetrated by an injection well and a production well by displacing hydrocarbons toward the production well using a drive fluid such as water thickened with a terpolymer of acrylamide, acrylonitrile and acrylic acid or a terpolymer of acrylamide, acrylonitrile and acrylic acid alkoxylated with ethylene oxide. If desired, the drive fluid may be saturated with carbon dioxide and/or natural gas at the injection pressure.

Inventors

  • 👤 Abraham Morduchowitz

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 20:59
CPC Classifications
E; E21; E21B; E21B43/00; E21B43/16; E21B43/164; C; C09; C09K; C09K8/00; C09K8/58; C09K8/588; C09K8/594; Y; Y10; Y10S; Y10S507/00; Y10S507/935; Y10S507/936

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 156 words
A process for recovering hydrocarbons from a subterranean, hydrocarbon-bearing formation penetrated by an injection well and a production well which comprises: (a) injecting into the formation via an injection well a drive fluid comprising brine having dissolved therein about 0.01 to about 5.0 weight percent of a terpolymer water insoluble, brine soluble, having a number average molecular weight from about 10,000 to about 2,000,000 and comprising recurring units of: ##STR4## wherein x, y and z represent the weight percent of the respective units in the said terpolymer and x ranges from about 50 to about 60 weight percent, y ranges from about 20 to about 30 weight percent and z ranges from about 10 to about 20 weight percent and wherein M is the radical --(CH.sub.2 CH.sub.2 O).sub.n H wherein n is an integer of from 1 to 3 inclusive (b) forcing the said fluid through the formation and (c) recovering hydrocarbons through the production well.
Claim 2
Dependent Claim 156 words
A process for recovering hydrocarbons from a subterranean, hydrocarbon-bearing formation penetrated by an injection well and a production well which comprises: (a) injecting into the formation via an injection well a drive fluid comprising brine having dissolved therein about 0.01 to about 5.0 weight percent of a terpolymer water insoluble, brine soluble, having a number average molecular weight from about 10,000 to about 2,000,000 and comprising recurring units of: ##STR4## wherein x, y and z represent the weight percent of the respective units in the said terpolymer and x ranges from about 50 to about 60 weight percent, y ranges from about 20 to about 30 weight percent and z ranges from about 10 to about 20 weight percent and wherein M is the radical --(CH.sub.2 CH.sub.2 O).sub.n H wherein n is an integer of from 1 to 3 inclusive (b) forcing the said fluid through the formation and (c) recovering hydrocarbons through the production well.
Claim 3
Dependent Claim 25 words
The process of claim 1 wherein the said drive fluid is saturated with carbon dioxide at a pressure of about 300 to about 3000 psig.
Claim 4
Dependent Claim 25 words
The process of claim 1 wherein the said drive fluid is saturated with natural gas at a pressure of about 300 to about 3000 psig.
Claim 5
Dependent Claim 34 words
The process of claim 1 wherein the said drive fluid includes about 0.005 to 0.3 weight percent of an alkaline agent selected from the group consisting of sodium hdyroxide, potassium hydroxide and sodium hypochlorite.
Claim 6
Dependent Claim 20 words
The process of claim 1 wherein said drive fluid contains about 0.001 to about 1.0 weight percent of a surfactant.
Claim 7
Dependent Claim 32 words
The process of claim 1 wherein said drive fluid contains about 0.001 to about 1.0 weight percent of a surfactant selected from the group consisting of alkylaryl sulfonates and alkyl polyethoxylated sulfates.
Claim 8
Dependent Claim 25 words
The process of claim 1 wherein the total salt concentration of said brine containing drive fluid is from about 2,000 ppm to about 20,000 ppm.
Claim 9
Dependent Claim 109 words
A fluid comprising brine having dissolved therein about 0.01 to about 5.0 weight percent of a terpolymer water insoluble, brine soluble, having a number average molecular weight from about 10,000 to about 2,000,000, and comprising recurring units of: ##STR5## wherein x, y and z represent the weight percent of the respective units in the said terpolymer and x ranges from about 50 to about 60 weight percent, y ranges from about 20 to about 30 weight percent and z ranges from about 10 to about 20 weight percent and wherein M is the radical --(CH.sub.2 CH.sub.2 O).sub.n H, wherein n is an integer of from 1 to 3 inclusive.
Claim 10
Dependent Claim 109 words
A fluid comprising brine having dissolved therein about 0.01 to about 5.0 weight percent of a terpolymer water insoluble, brine soluble, having a number average molecular weight from about 10,000 to about 2,000,000, and comprising recurring units of: ##STR5## wherein x, y and z represent the weight percent of the respective units in the said terpolymer and x ranges from about 50 to about 60 weight percent, y ranges from about 20 to about 30 weight percent and z ranges from about 10 to about 20 weight percent and wherein M is the radical --(CH.sub.2 CH.sub.2 O).sub.n H, wherein n is an integer of from 1 to 3 inclusive.
Claim 11
Dependent Claim 32 words
The fluid of claim 8 wherein about 0.005 to about 0.3 weight percent of an alkaline agent selected from the group consisting of sodium hydroxide, potassium hydroxide and sodium hypochlorite is included.
Claim 12
Dependent Claim 30 words
The fluid of claim 8 wherein about 0.001 to about 1.0 weight percent of a surfactant selected from the group consisting of alkylaryl sulfonates and alkyl polyethoxylated sulfates is included.
Claim 13
Dependent Claim 18 words
The fluid of claim 8 wherein the total salt concentration is about 2,000 ppm to about 20,000 ppm.

References Cited (Backward Citations)

US2808397A Cited
US3039529A Cited
US3684014A Cited
US3804173A Cited
US3880765A Cited
US4110224A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-04-05 1985-10-05 1986-04-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-04-05 1989-10-05 1990-04-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-04-05 1993-10-05 1994-04-06 $7700.00 Window Closed / Lapsed

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