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US4320189A
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Photopolymerizable composition containing s-triazine compound
Assignee: Asahi Kasei Corp
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Filing: 1980-09-29
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Granted: 1982-03-16
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Expires: 2000-09-29
Abstract
Abstract A novel photopolymerizable composition comprising (a) a non-gaseous ethylenically unsaturated compound, (b) a thermoplastic organic polymer binder, (c) a photopolymerization initiator and (d) a specific s-triazine compound provides improved adhesion of a photopolymer prepared therefrom to a substrate even in aqueous plating or etching solutions.
Inventors
- 👤 Tadashi Taguchi
- 👤 Toshihide Takemoto
- 👤 Noboru Fujikawa
- 👤 Mitsuo Kohno
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 10:17
CPC Classifications
H; H05; H05K; H05K3/00; H05K3/0073; H05K3/0076; C; C08; C08F; C08F2/00; C08F2/46; C08F2/48; C08F2/50; G; G03; G03F; G03F7/00; G03F7/004; G03F7/085; H05K2203/00; H05K2203/12; H05K2203/122; H05K2203/124; H05K3/10; H05K3/18; H05K3/181; H05K3/182; H05K3/184; H05K3/38; H05K3/389; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/114; Y10S430/12; Y10S430/121
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
113 words
A photopolymerizable composition which comprises: (a) at least one non-gaseous ethylenically unsaturated compound having at least two terminal ethylenic groups and capable of forming a high polymer with the aid of a photopolymerization initiator activated by actinic radiation, (b) at least one thermoplastic organic polymer binder, (c) at least one photopolymerization initiator activatable by actinic radiation, and (d) at least one s-triazine compound represented by the formula: ##STR2## wherein R 1 and R 2 each independently stands for a hydrogen atom, an amino group, an aryl group, a straight chain or branched (C 1 -C 4 )alkyl group, a straight chain or branched (C 1 -C 4 )alkylamino group, or a halogen atom.
Claim 2
Dependent Claim
113 words
A photopolymerizable composition which comprises: (a) at least one non-gaseous ethylenically unsaturated compound having at least two terminal ethylenic groups and capable of forming a high polymer with the aid of a photopolymerization initiator activated by actinic radiation, (b) at least one thermoplastic organic polymer binder, (c) at least one photopolymerization initiator activatable by actinic radiation, and (d) at least one s-triazine compound represented by the formula: ##STR2## wherein R 1 and R 2 each independently stands for a hydrogen atom, an amino group, an aryl group, a straight chain or branched (C 1 -C 4 )alkyl group, a straight chain or branched (C 1 -C 4 )alkylamino group, or a halogen atom.
Claim 3
Dependent Claim
38 words
A photopolymerizable composition as claimed in claim 1, wherein said aryl group is a phenyl or naphthyl group unsubstituted or substituted with one or two members selected from straight chain or branched (C 1 -C 4 )alkyl groups.
Claim 4
Dependent Claim
33 words
A photopolymerizable composition as claimed in claim 1 or 2, wherein said at least one s-triazine compound (d) is present in an amount of 0.1 to 5% by weight based on the composition.
Claim 5
Dependent Claim
31 words
A photopolymerizable composition as claimed in claim 3, wherein said at least one s-triazine compound (d) is present in an amount of 0.5 to 2% by weight based on the composition.
Claim 6
Dependent Claim
32 words
A photopolymerizable composition as claimed in any one of claims 1 or 2, wherein said at least one ethylenically unsaturated compound (a) is a polyacrylic or polymethacrylic ester of a polyhydric alcohol.
Claim 7
Dependent Claim
57 words
A photopolymerizable composition as claimed in any one of claims 1 or 2, wherein said at least one thermoplastic organic polymer binder is a member selected from the group consisting of methyl methacrylate homopolymer and copolymers, styrene homopolymer and copolymers, vinyl chloride homopolymer and copolymers, vinyl acetate homopolymer and copolymers, chlorinated polyethylene, polyvinyl alcohol, and polyvinyl butyral.
Claim 8
Dependent Claim
63 words
A photopolymerizable composition as claimed in any one of claims 1 or 2, wherein 20 to 60% by weight of said at least one ethylenically unsaturated compound (a), 30 to 77% by weight of said at least one thermoplastic organic polymer binder (b) and 1 to 10% by weight of said at least one photopolymerization initiator (c) are present based on the composition.
Claim 9
Dependent Claim
37 words
A photopolymerizable composition as claimed in claim 1, wherein the photopolymerization initiator (c) is a member selected from the group consisting of anthraquinone and its derivatives, benzoin and its derivatives, benzophenone and its derivatives, and quinone compounds.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-03-15 | 1985-09-14 | 1986-03-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-03-15 | 1989-09-14 | 1990-03-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-03-15 | 1993-09-14 | 1994-03-16 | $7700.00 | Window Closed / Lapsed |