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US4316952A Expired / Lapsed US ⏱️ 0.0 years remaining

Energy sensitive element having crosslinkable polyester

Assignee: 3M Co
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Filing: 1981-01-05
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Granted: 1982-02-23
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Expires: 2001-01-05
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Abstract

Abstract Water-dispersible radiation curable polyesters having backbone hydantoin groups and alpha-methylene groups are disclosed. These polyesters are useful in the field of graphic arts.

Inventors

  • 👤 Larry A. Wendling

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 06:52
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/032; C; C08; C08G; C08G18/00; C08G18/06; C08G18/70; C08G18/71; C08G18/81; C08G18/8108; C08G59/00; C08G59/14; C08G59/1433; C08G59/1438; C08G59/1455; C08G59/1461; C08G59/1466; C08G59/18; C08G59/20; C08G59/22; C08G59/26; C08G59/40; C08G59/42; C08G59/4207; C08G63/00; C08G63/68; C08G63/685; C08G63/6854; C08G63/6858; G03F7/038; G03F7/0388

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 219 words
An energy-sensitive element having a substrate with a coating on at least one side thereon, said coating comprising an energy-curable polyester, said polyester being crosslinkable and having heterocyclic moieties and backbone alpha-methylene groups and repeating units of the general formula: ##STR10## wherein R is a single bond or an alkylene group having 1 to 6 carbon atoms and optionally one catenary oxygen; R 1 is hydrogen, ##STR11## wherein R 3 is alkenyl or alkyl having 2 to 5 carbon atoms and can be substituted by phenyl or carboxyl and R 4 is aliphatic or aromatic hydrocarbyl having up to 8 carbon atoms; R 2 is hydrogen or methyl; W is a divalent group that is required to complete a 5- or 6-membered heterocyclic ring, wherein W is ##STR12## and wherein R 5 , R 6 , R 7 , and R 8 are independently hydrogen or lower alkyl of 1 to 4 carbon atoms; Q is the divalent or trivalent residue of hydrocarbyl di- or tri-carboxylic acids, said residue formed by the removal of active hydrogens from the caroboxylic acid groups and containing up to 40 carbon atoms and optionally containing catenary oxygen atoms; and a is zero or one, but can be one for no more than 20 mole percent of the carboxylic acids, and Z is ##STR13##
Claim 2
Dependent Claim 219 words
An energy-sensitive element having a substrate with a coating on at least one side thereon, said coating comprising an energy-curable polyester, said polyester being crosslinkable and having heterocyclic moieties and backbone alpha-methylene groups and repeating units of the general formula: ##STR10## wherein R is a single bond or an alkylene group having 1 to 6 carbon atoms and optionally one catenary oxygen; R 1 is hydrogen, ##STR11## wherein R 3 is alkenyl or alkyl having 2 to 5 carbon atoms and can be substituted by phenyl or carboxyl and R 4 is aliphatic or aromatic hydrocarbyl having up to 8 carbon atoms; R 2 is hydrogen or methyl; W is a divalent group that is required to complete a 5- or 6-membered heterocyclic ring, wherein W is ##STR12## and wherein R 5 , R 6 , R 7 , and R 8 are independently hydrogen or lower alkyl of 1 to 4 carbon atoms; Q is the divalent or trivalent residue of hydrocarbyl di- or tri-carboxylic acids, said residue formed by the removal of active hydrogens from the caroboxylic acid groups and containing up to 40 carbon atoms and optionally containing catenary oxygen atoms; and a is zero or one, but can be one for no more than 20 mole percent of the carboxylic acids, and Z is ##STR13##
Claim 3
Dependent Claim 24 words
The element of claim 1 wherein said coating further comprises 0.01 to 5.0 percent by weight of the total polymerizable polyester of a photoinitiator.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-02-22 1985-08-24 1986-02-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-02-22 1989-08-24 1990-02-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-02-22 1993-08-24 1994-02-23 $7700.00 Window Closed / Lapsed

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