US4315088A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for producing α-olefin polymer
Assignee: Mitsubishi Chemical Corp
•
Filing: 1979-12-11
•
Granted: 1982-02-09
•
Expires: 1999-12-11
Abstract
Abstract This invention relates to a process for producing an alpha -olefin polymer having a high stereoregularity in a high yield by polymerizing alpha -olefin in the presence of a catalyst composed of solid catalyst component (I) prepared by contacting (A) magnesium halide, (B) aromatic carboxylic acid ester, (C) halogen compound of titanium, and (D) siloxyaluminum compound with each other, and (II) an organometallic compound of a metal of Group I to III in the Periodic Table.
Inventors
- 👤 Sadao Kitagawa
- 👤 Isao Okada
- 👤 Teruo Saito
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 15:55
CPC Classifications
C; C08; C08F; C08F4/00; C08F4/02; C08F4/022; C08F10/00; Y; Y10; Y10S; Y10S526/00; Y10S526/906
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
216 words
A process for producing an α-olefin polymer which comprises homopolymerizing an α-olefin selected from the group consisting of propylene, butene-1, and 4-methylpentene-1, or copolymerizing two or more of said α-olefins or one or more of said α-olefins and ethylene or an α-olefin containing 4 to 8 carbon atoms in the presence of a catalyst consisting essentially of: (I) a solid catalyst component prepared by contacting with each other, (A) a magnesium dihalide of the formula MgX 2 where x is a halogen atom, (B) an aromatic carboxylic acid ester, (C) titanium tetrachloride, and (D) a siloxyaluminum compound selected from the group consisting of trimethylsiloxyaluminum dichloride, triethylsiloxyaluminum dichloride, triphenyl-siloxyaluminum dichloride, trichlorosiloxyaluminum dichloride, a reaction product of dimethylpolysiloxane and aluminum chloride, a reaction product of methylphenylpolysiloxane and aluminum chloride, or a reaction product of methylhydrogenpolysiloxane and aluminum chloride; and (II) organometallic compound of a metal of Groups I, II or III in the Periodic Table, wherein ingredient B is used in an amount of about 0.01 to 10 mols, ingredient C in an amount of about 0.001 to 1,000 mols, and ingredient D in an amount of about 0.001 to 1 mol, per mol of ingredient A; and wherein said ingredients A, B and D are pulverized together, contacted with ingredient C in a slurry state, and washed.
Claim 2
Dependent Claim
216 words
A process for producing an α-olefin polymer which comprises homopolymerizing an α-olefin selected from the group consisting of propylene, butene-1, and 4-methylpentene-1, or copolymerizing two or more of said α-olefins or one or more of said α-olefins and ethylene or an α-olefin containing 4 to 8 carbon atoms in the presence of a catalyst consisting essentially of: (I) a solid catalyst component prepared by contacting with each other, (A) a magnesium dihalide of the formula MgX 2 where x is a halogen atom, (B) an aromatic carboxylic acid ester, (C) titanium tetrachloride, and (D) a siloxyaluminum compound selected from the group consisting of trimethylsiloxyaluminum dichloride, triethylsiloxyaluminum dichloride, triphenyl-siloxyaluminum dichloride, trichlorosiloxyaluminum dichloride, a reaction product of dimethylpolysiloxane and aluminum chloride, a reaction product of methylphenylpolysiloxane and aluminum chloride, or a reaction product of methylhydrogenpolysiloxane and aluminum chloride; and (II) organometallic compound of a metal of Groups I, II or III in the Periodic Table, wherein ingredient B is used in an amount of about 0.01 to 10 mols, ingredient C in an amount of about 0.001 to 1,000 mols, and ingredient D in an amount of about 0.001 to 1 mol, per mol of ingredient A; and wherein said ingredients A, B and D are pulverized together, contacted with ingredient C in a slurry state, and washed.
Claim 3
Dependent Claim
32 words
The process of claim 1, wherein a pulverized mixture of said ingredients A, B, C and D is treated with a halogen or an interhalogen compound in a halogenated hydrocarbon and washed.
Claim 4
Dependent Claim
12 words
The process of claim 1, wherein ingredient A is MgCl 2 .
Claim 5
Dependent Claim
70 words
The process of claim 1, wherein ingredient B is represented by the formulae (A) or (B): ##STR3## wherein R 7 and R 9 each represents a hydrogen atom, a hydrocarbon residue containing about 1 to 20 carbon atoms, or an alkoxy or aryloxy group containing about 1 to 20 carbon atoms and R 8 represents a hydrocarbon residue or a halogenated hydrocarbon residue containing about 1 to 20 carbon atoms.
Claim 6
Dependent Claim
13 words
The process of claim 4, wherein ingredient B is represented by formula (A).
Claim 7
Dependent Claim
30 words
The process of claim 5, wherein ingredient B is selected from the group consisting of methyl benzoate, ethyl benzoate, isopropyl benzoate, methyl toluylate, ethyl toluylate, methyl anisate, and ethyl anisate.
Claim 8
Dependent Claim
46 words
The process of claim 1, wherein ingredient C is represented by the formula: Ti(OR.sup.10).sub.m X.sub.4-m wherein R 10 represents a hydrocarbon residue containing about 1 to 15 carbon atoms. X represents a chlorine or a bromine atom and m is a number of 0 to 3.
Claim 9
Dependent Claim
37 words
The process of claim 1, wherein said solid catalyst component is prepared by contacting said ingredients A, B, C and D with a halide of an element of Groups IVb, Vb and VIb of the Periodic Table.
Claim 10
Dependent Claim
24 words
The process of claim 8, wherein said halide is used in an amount of about 0.001 to 1 mol per mol of ingredient A.
Claim 11
Dependent Claim
23 words
The process of claim 1, wherein said organometallic compound is an organo compound of a metal of Group IIIb of the Periodic Table.
Claim 12
Dependent Claim
13 words
The process of claim 10, wherein said organometallic compound is an organoaluminum compound.
Claim 13
Dependent Claim
47 words
The process of claim 11, wherein said organoaluminum compound is represented by the formula: R.sub.a AlX.sub.3-a wherein R represents a hydrocarbon residue containing about 1 to 20 carbon atoms, X represents a halogen atom or a hydrogen atom, and a is a number satisfying the relationship 2≦a≦3.
Claim 14
Dependent Claim
14 words
The process of claim 1, wherein said catalyst additionally comprises an electron donor compound.
Claim 15
Dependent Claim
36 words
The process of claim 1, wherein said contact is carried out in a solvent and said solvent is a halogenated hydrocarbon having a dielectric constant of not less than about 6 at 10° to 50° C.
Claim 16
Dependent Claim
28 words
The process of claim 14, wherein said halogenated hydrocarbon is selected from the group consisting of 1,2-dichloroethane, 1,1-dichloroethane, 2,2-dichloroethane, o-dichlorobenzene, ethyl bromide, isopropyl bromide, t-butyl bromide and 1,2-dichloropropane.
References Cited (Backward Citations)
US3787323A
Cited
US4107414A
Cited
US4071672A
Cited
JPS5044273A
Cited
US4157435A
Cited
DE2701647A1
Cited
US4146502A
Cited
DE2757725A1
Cited
US4168361A
Cited
DE2818642A1
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-02-08 | 1985-08-10 | 1986-02-09 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-02-08 | 1989-08-10 | 1990-02-09 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-02-08 | 1993-08-10 | 1994-02-09 | $7700.00 | Window Closed / Lapsed |