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US4315046A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for securing primerless adhesion of silicone resin coating composition to cast acrylics

Assignee: General Electric Co
•
Filing: 1980-07-17
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Granted: 1982-02-09
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Expires: 2000-07-17
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Abstract

Abstract Neutral to basic silicone resin abrasion resistant coating compositions can be adherently secured to cast acrylic plastic substrates without a primer if the substrate is provided with a wash coat of glacial acetic acid shortly before being coated with said silicone resin composition.

Inventors

  • 👤 Robert B. Frye

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 05:23
CPC Classifications
B; B05; B05D; B05D7/00; B05D7/02; B05D3/00; B05D3/10; B05D3/101; C; C08; C08J; C08J7/00; C08J7/04; C08J7/0427; C08J7/043; C08J7/046; C08J2333/00; C08J2483/00

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 144 words
In process for forming an adherent, abrasion-resistant coating on unprimed cast acrylic substrate, the steps comprising: (i) applying to said substrate a wash coating of glacial acetic acid and draining said wash coating for from 2 to 5 minutes. (ii) thereafter applying a coating composition comprising a dispersion of colloidal silica in an aliphatic alcohol-water solution of the partial condensate of a silanol of the formula RSi(OH) 3 , wherein R is selected from the group consisting of alkyl having from 1 to 3 carbon atoms and aryl, at least 70 weight percent of the silanol being CH 3 Si(OH) 3 , said composition containing 10 to 40% solids, said solids consisting essentially of 10 to 70 weight % colloidal silica and 30 to 90 weight % of the partial condensate and wherein said composition has a pH of from 7.1 to about 7.8.
Claim 2
Dependent Claim 144 words
In process for forming an adherent, abrasion-resistant coating on unprimed cast acrylic substrate, the steps comprising: (i) applying to said substrate a wash coating of glacial acetic acid and draining said wash coating for from 2 to 5 minutes. (ii) thereafter applying a coating composition comprising a dispersion of colloidal silica in an aliphatic alcohol-water solution of the partial condensate of a silanol of the formula RSi(OH) 3 , wherein R is selected from the group consisting of alkyl having from 1 to 3 carbon atoms and aryl, at least 70 weight percent of the silanol being CH 3 Si(OH) 3 , said composition containing 10 to 40% solids, said solids consisting essentially of 10 to 70 weight % colloidal silica and 30 to 90 weight % of the partial condensate and wherein said composition has a pH of from 7.1 to about 7.8.
Claim 3
Dependent Claim 20 words
A process is defined in claim 1 wherein said composition also includes a small amount of a polysiloxane polyether copolymer.
Claim 4
Dependent Claim 14 words
A process defined in claim 1 wherein said coating is cured on the substrate.
Claim 5
Dependent Claim 31 words
A process as defined in claim 1 wherein said aqueous coating composition contains about 20% solids, the partial condensate is of CH 3 Si(OH) 3 and the aliphatic alcohol is methanol.
Claim 6
Dependent Claim 17 words
A process as defined in claim 1 wherein the pH is from about 7.2 to about 7.8.
Claim 7
Dependent Claim 33 words
A process as defined in claim 2 wherein said polysiloxane polyether copolymer is present in an amount of from about 2.5 to about 15% by weight of the total solids of the composition.
Claim 8
Dependent Claim 14 words
A process as defined in claim 1 wherein said cast acrylic substrate is transparent.

References Cited (Backward Citations)

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US3561995A Cited
US3629165A Cited
US3686018A Cited
US3708225A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-02-08 1985-08-10 1986-02-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-02-08 1989-08-10 1990-02-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-02-08 1993-08-10 1994-02-09 $7700.00 Window Closed / Lapsed

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