Process for decaffeinating tea

Claim 2

Process for decaffeinating a tea extract which contains caffeine and tannins capable of complexing with caffeine comprising: (a) cooling said extract sufficiently to form (i) an aqueous solubles phase containing cold-water soluble components of the cooled extract, including a portion of the caffeine, and (ii) an insolubles phase containing a cold-water-insoluble complex of tannins with another portion of the caffeine; (b) separating the solubles phase from the insolubles phase; (c) treating the insolubles phase to remove caffeine therefrom; (d) adding decaffeinated tannins to the solubles phase; and (e) repeating steps (a) through (d) until the desired degree of decaffeination has been achieved.

Claim 3

Process according to claim 1, wherein volatiles are stripped from the tea extract prior to step (a), and are recombined with the extract when the process has been completed.

Claim 4

Process according to claim 2, wherein following addition of volatiles to the decaffeinated tea extract, said extract is dried.

Claim 5

Process according to claim 1, wherein the extract is cooled in step (a) to a temperature between about 0° C. and about 15° C.

Claim 6

Process according to claim 1, wherein the extract is concentrated, prior to step (a), to contain from about 5% to about 25% by weight solids.

Claim 7

Process according to claim 1, where in step (c), the caffeine is removed from the insolubles phase by contact with a water-immiscible fatty material.

Claim 8

Process according to claim 1, where in step (c), the caffeine is removed from the insolubles phase by contact with a chlorinated hydrocarbon.

Claim 9

Process according to claim 1, wherein the decaffeinated tannins are oxidized prior to their addition to the solubles phase in step (d).

Claim 10

Process according to claim 1, wherein the last-added tannins are added in an amount such that the solids content of the decaffeinated extract is substantially the same as that of the concentrated extract prior to decaffeination.

Claim 11

Process for decaffeinating a tea extract which contains caffeine and tannins capable of complexing with caffeine and from which volatiles have been removed, comprising: (a) cooling said extract sufficiently to form (i) an aqueous solubles phase containing cold-water soluble components of the cooled extract, including a portion of the caffeine, and (ii) an insolubles phase containing a cold-water-insoluble complex of tannins with another portion of the caffeine; (b) separating the solubles phase from the insolubles phase; (c) treating the insolubles phase to remove caffeine therefrom; (d) cooling the decaffeinated insolubles phase to form a cold-water-insoluble decaffeinated tannin precipitate and a solution of cold-water-soluble tannins; (e) separating said decaffeinated tannin precipitate from the solution of cold-water-soluble tannins; (f) mixing an aliquot of decaffeinated tannin precipitate from step (e) with aqueous tea extract, cooling said mixture to precipitate tannins-caffeine complex therefrom and separating the precipitate from the supernatant; (g) mixing a further aliquot of decaffeinated tannin precipitate from step (e) with the supernatant from step (f), cooling said mixture to precipitate tannins-caffeine complex therefrom and separating the precipitate from the supernatant; (h) adding cold-water-soluble tannins from step (e) to the supernatant from step (g) and restoring volatiles thereto; (i) drying the volatile-containing, decaffeinated extract.

Claim 12

Process for decaffeinating a tea extract which contains caffeine and tannins capable of complexing with caffeine and from which volatiles have been removed, comprising: (a) cooling said extract sufficiently to form (i) an aqueous solubles phase containing cold-water soluble components of the cooled extract, including a portion of the caffeine, and (ii) an insolubles phase containing a cold-water-insoluble complex of tannins with another portion of the caffeine; (b) separating the solubles phase from the insolubles phase; (c) treating the insolubles phase to remove caffeine therefrom; (d) cooling the decaffeinated insolubles phase to form a cold-water-insoluble decaffeinated tannin precipitate and a solution of cold-water-soluble tannins; (e) separating said decaffeinated tannin precipitate from the solution of cold-water-soluble tannins; (f) mixing an aliquot of decaffeinated tannin precipitate from step (e) with aqueous tea extract, cooling said mixture to precipitate tannins-caffeine complex therefrom and separating the precipitate from the supernatant; (g) mixing a further aliquot of decaffeinated tannin precipitate from step (e) with the supernatant from step (f), cooling said mixture to precipitate tannins-caffeine complex therefrom and separating the precipitate from the supernatant; (h) adding cold-water-soluble tannins from step (e) to the supernatant from step (g) and restoring volatiles thereto; (i) drying the volatile-containing, decaffeinated extract.

Claim 13

Process according to claim 10, wherein following step (g), a further aliquot of decaffeinated tanning precipitate from step (e) is mixed with the supernatant from step (g), the mixture is cooled to precipitate tannins-caffeine complex therefrom and the precipitate is separated from the resultant supernatant; and in step (h) cold-water-soluble tannins from step (e) and volatiles are added to said resultant supernatant.

Claim 14

Process according to claim 10, wherein following step (g), one or more additional stages of decaffeination of the supernatant from step (g) is carried out by addition of decaffeinated tannins precipitate and separation of the resultant tannins-caffeine complex; and in step (h) cold-water-soluble tannins from step (e) and volatiles are added to the last decaffeinated supernatant.

Claim 15

Process for decaffeinating a tea extract which contains caffeine and tannins capable of complexing with caffeine comprising: (a) cooling said extract sufficiently to form (i) an aqueous solubles phase containing cold-water soluble components of the cooled extract, including a portion of the caffeine, and (ii) an insolubles phase containing a cold-water-insoluble complex of tannins with another portion of the caffeine; (b) separating the solubles phase from the insolubles phase; (c) treating the insolubles phase to remove caffeine therefrom and form a decaffeinated insolubles phase; (d) cooling the decaffeinated insolubles phase to form a cold-water-insoluble decaffeinated tannin precipitate and a solution of cold-water-soluble tannins; (e) separating the decaffeinated tannin precipitate from the solution of cold-water-soluble tannins; (f) mixing the separated decaffeinated tannin precipitate with the partially decaffeinated solubles phase of step (b); (g) cooling the mixture to precipitate a further tannins-caffeine complex; (h) separating the precipitate from the supernatant; (i) decaffeinating the tannins-caffeine complex precipitate and returning the decaffeinated tannins to the supernatant; and (j) adding the solution of cold-water soluble tannins from step (d) of the supernatant.

Claim 16

Process for decaffeinating a tea extract which contains caffeine and tannins capable of complexing with caffeine comprising: (a) cooling said extract sufficiently to form (i) an aqueous solubles phase containing cold-water soluble components of the cooled extract, including a portion of the caffeine, and (ii) an insolubles phase containing a cold-water-insoluble complex of tannins with another portion of the caffeine; (b) separating the solubles phase from the insolubles phase; (c) treating the insolubles phase to remove caffeine therefrom and form a decaffeinated insolubles phase; (d) cooling the decaffeinated insolubles phase to form a cold-water-insoluble decaffeinated tannin precipitate and a solution of cold-water-soluble tannins; (e) separating the decaffeinated tannin precipitate from the solution of cold-water-soluble tannins; (f) mixing the separated decaffeinated tannin precipitate with the partially decaffeinated solubles phase of step (b); (g) cooling the mixture to precipitate a further tannins-caffeine complex; (h) separating the precipitate from the supernatant; (i) decaffeinating the tannins-caffeine complex precipitate and returning the decaffeinated tannins to the supernatant; and (j) adding the solution of cold-water soluble tannins from step (d) of the supernatant.