Particulated polyetherimide and method for making

Claim 1

A method for making particulated substantially organic solvent-free polyetherimide which comprises heating particulated substantially organic solvent-free polyetheramide acid consisting essentially of chemically combined units of the formula, ##STR9## at a temperature in the range of from 135° C. to 175° C. until the resulting particulated product consists essentially of at least about 70 mole percent of chemically combined imide units of the formula, ##STR10## based on the total moles of chemically combined imide and amide acid units without a substantial degree of sintering occurring in the resulting particulated product, where the polyetheramide acid is the product of reaction of organic dianhydride and organic diamine utilized in a mole ratio of 1 mole of organic dianhydride, per 1 to 1.5 mole of organic diamine, where the organic dianhydride is selected from the group consisting of (A) aromatic bis(ether anhydride)s of the formula, ##STR11## (B) mixtures of 1 or more of said bis(ether anhydride)s with up to 30 mole percent of benzophenone dianhydride of the formula, ##STR12## with at least one organic diamine of the formula, H.sub.2 N--R--NH.sub.2, where said polyetheramide acid reaction product has a number average molecular weight of below about 5000, where Z is a member selected from ##STR13## and divalent organic radicals of the general formula, ##STR14## X is a member selected from the class consisting of divalent radicals of the formulas --C y H 2 y--, --C--, ##STR15## --O--, and --S--, y is an integer from 1 to 5, and R is a divalent organic radical selected from the class consisting of aromatic hydrocarbon radicals having from 6 to about 20 carbon atoms and halogenated derivatives thereof, alkylene radicals having from 2 to about 20 carbon atoms, from C 2 to about C 8 alkylene terminated polydiorganosiloxane and divalent radicals of the general formula, ##STR16## Q is a member selected from the class consisting of --O--, --S--, and --C 2 H 2x --, where x is an integer from 1 to 5.

Claim 2

A method for making particulated substantially organic solvent-free polyetherimide which comprises heating particulated substantially organic solvent-free polyetheramide acid consisting essentially of chemically combined units of the formula, ##STR9## at a temperature in the range of from 135° C. to 175° C. until the resulting particulated product consists essentially of at least about 70 mole percent of chemically combined imide units of the formula, ##STR10## based on the total moles of chemically combined imide and amide acid units without a substantial degree of sintering occurring in the resulting particulated product, where the polyetheramide acid is the product of reaction of organic dianhydride and organic diamine utilized in a mole ratio of 1 mole of organic dianhydride, per 1 to 1.5 mole of organic diamine, where the organic dianhydride is selected from the group consisting of (A) aromatic bis(ether anhydride)s of the formula, ##STR11## (B) mixtures of 1 or more of said bis(ether anhydride)s with up to 30 mole percent of benzophenone dianhydride of the formula, ##STR12## with at least one organic diamine of the formula, H.sub.2 N--R--NH.sub.2, where said polyetheramide acid reaction product has a number average molecular weight of below about 5000, where Z is a member selected from ##STR13## and divalent organic radicals of the general formula, ##STR14## X is a member selected from the class consisting of divalent radicals of the formulas --C y H 2 y--, --C--, ##STR15## --O--, and --S--, y is an integer from 1 to 5, and R is a divalent organic radical selected from the class consisting of aromatic hydrocarbon radicals having from 6 to about 20 carbon atoms and halogenated derivatives thereof, alkylene radicals having from 2 to about 20 carbon atoms, from C 2 to about C 8 alkylene terminated polydiorganosiloxane and divalent radicals of the general formula, ##STR16## Q is a member selected from the class consisting of --O--, --S--, and --C 2 H 2x --, where x is an integer from 1 to 5.