Instant-setting adhesive composition

Claim 2

An instant-setting adhesive composition comprising a 2-cyanoacrylate and at least one 1,1-disubstituted diene represented by the following general formula (A), the amount of said 1,1-disubstituted diene being more than 50% by weight but not more than 90% by weight based on the total amount of both components: ##STR3## wherein R 1 is a hydrogen atom, an alkyl group having 1 to 5 carbon atoms, an aryl group, an aralkyl group or a halogen atom, R 2 is a hydrogen atom or an alkyl group having 1 to 5 carbon atoms, and X and Y, which may be the same or different, are selected from the group consisting of cyano group, carboxylate group, ethylsulfone group, phenylsulfone group, formyl group, acetyl group, benzoyl group, diethylphosphonyl group, amido group and phenyl group.

Claim 3

An instant-setting adhesive composition according to claim 1, wherein in the general formula (A), R 1 is a hydrogen atom or an alkyl group having 1 or 2 carbon atoms, R 2 is a hydrogen atom, X is a cyano group, and Y is a carboxylate group, an ethylsulfone group, a benzoyl group, a diethylphosphonyl group, an amide group, or a phenyl group.

Claim 4

An instant-setting adhesive composition according to claim 1, wherein the 1,1-disubstituted diene represented by the general formula (A) is one or more compound selected from the group consisting of 1-cyano-1-carbomethoxybutadiene-1,3, 1-cyano-1-carbethoxybutadiene-1,3, 1-cyano-1-carbo-n-propoxybutadiene-1,3, 1-cyano-1-carboisopropoxybutadiene-1,3, 1-cyano-1-carbo-n-butoxybutadiene-1,3, 1-cyano-1-carboisobutoxybutadiene-1,3, 1-cyano-1-carbo-tert-butoxybutadiene-1,3, 1,1-dicyanobutadiene-1,3, 1,1-dicarbomethoxybutadiene-1,3, 1,1-dicarbethoxybutadiene-1,3, 1-cyano-1-ethylsulfonylbutadiene-1,3, 1-acetyl-1-phenylbutadiene-1,3, 1-cyano-1-acetamidobutadiene-1,3, 1-formyl-1-phenylbutadiene-1,3, 1-cyano-1-phenylbutadiene-1,3, 1-cyano-1-benzenesulfonylbutadiene-1,3, 1-cyano-1-diethylphosphonobutadiene-1,3, 1-benzoyl-1-cyanobutadiene1,3, 1-cyano-1-carbethoxy-3-(n-amyl)butadiene-1,3, 1-cyano-1-carbethoxy-2-methylbutadiene-1,3, 1-cyano-1-carbethoxy-3-phenylbutadiene-1,3, 1,1-dicarbethoxy-3-methylbutadiene-1,3, and 1-cyano-1-carbethoxy-3-chlorobutadiene-1,3.

Claim 5

An instant-setting adhesive composition according to claim 2, wherein the 1,1-disubstituted diene represented by the general formula (A) in one or more compound selected from the group consisting of 1-cyano-1-carbomethoxybutadiene-1,3, 1-cyano-1-carbethoxybutadiene-1,3, 1-cyano-1-carbo-n-propoxybutadiene-1,3, 1-cyano-1-carboisopropoxybutadiene-1,3, 1-cyano-1-carbo-n-butoxybutadiene-1,3, 1-cyano-1-carboisobutoxybutadiene-1,3, 1-cyano-1-carbo-tert-butoxybutadiene-1,3, 1-cyano-1-ethylsulfonylbutadiene-1,3, 1-cyano-1-acetamidobutadiene-1,3, 1-cyano-1-phenylbutadiene-1,3, 1-cyano-1-diethylphosphonobutadiene-1,3, 1-benzoyl-1-cyanobutadiene-1,3, and 1-cyano-1-carbethoxy-2-methylbutadiene-1,3.

Claim 6

An instant-setting adhesive composition according to claims 1, 2, 3 or 4, wherein the 2-cyanoacrylate is one or more compound selected from the group consisting of methyl 2-cyanoacrylate, ethyl 2-cyanoacrylate, n-propyl 2-cyanoacrylate, isopropyl 2-cyanoacrylate, n-butyl 2-cyanoacrylate, isobutyl 2-cyanoacrylate, tert-butyl 2-cyanoacrylate, amyl 2-cyanoacrylate, n-hexyl 2-cyanoacrylate, cyclohexyl 2-cyanoacrylate, heptyl 2-cyanoacrylate, n-octyl 2-cyanoacrylate, 2-ethylhexyl 2-cyanoacrylate, dodecyl 2-cyanoacrylate, allyl 2-cyanoacrylate, propargyl 2-cyanoacrylate, benzyl 2-cyanoacrylate, phenyl 2-cyanoacrylate, 2-methoxyethyl 2-cyanoacrylate, 2-ethoxyethyl 2-cyanoacrylate, 2-chloroethyl 2-cyanoacrylate, hexafluoroisopropyl 2-cyanoacrylate, trifluoroethyl 2-cyanoacrylate, and 2-cyanoethyl 2-cyanoacrylate.

Claim 7

An instant-setting adhesive composition according to claims 1, 2, 3 or 4, wherein the amount of one or more 1,1-disubstituted dienes is 60 to 90% by weight per 40 to 10% by weight of the 2-cyanoacrylate.

Claim 8

An instant-setting adhesive composition according to claims 1, 2, 3 or 4, wherein the amount of one or more 1,1-disubstituted dienes is 65 to 85% by weight per 35 to 15% by weight of the 2-cyanoacrylate.

Claim 9

An instant-setting adhesive composition according to claims 1, 2, 3 or 4, which further contains one or more members selected from the group consisting of lactone compounds, alcohols, alcohol ethers, alcohol esters, and crown ether compounds.

Claim 10

An instant-setting adhesive composition according to claim 8, wherein the lactone compound is one or more members selected from the group consisting of β-propiolactone, β-pivalolactone, γ-butyrolactone, 3-carbethoxy-γ-butyrolactone, 5-ethyl-γ-butyrolactone, phthalide, δ-valerolactone, coumarin, dihydrocoumarin, ε-caprolactone, heptodilactone, and dimethylheptodilactone.

Claim 11

An instant-setting adhesive composition according to claim 8, wherein the alcohol is one or more members selected from the group consisting of methyl alcohol, ethyl alcohol, n-propyl alcohol, isopropyl alcohol, n-butyl alcohol, isobutyl alcohol, tert-butyl alcohol, n-amyl alcohol, ethylene glycol, propylene glycol, tetramethylene glycol, pentamethylene glycol, hexamethylene glycol, heptamethylene glycol, octamethylene glycol, decamethylene glycol, polybutadienediol, chloropropylene glycol, 3-methylpentanediol, 2,2-diethylpropanediol, 2-ethyl-1,4-butanediol, diethylene glycol, triethylane glycol, polyethylene glycol, dipropylene glycol, polypropylene glycol, glycerol, trimethylolmethane, trimethylolethane, trimethylolpropane, and 1,2,6-hexanetriol.

Claim 12

An instant-setting adhesive composition according to claim 8, wherein the alcohol ether is one or more members selected from the group consisting of propylene glycol methyl ether, dipropylene glycol methyl ether, tripropylene glycol methyl ether, ethylene glycol ethyl ether, ethylene glycol n-butyl ether, diethylene glycol methyl ether, diethylene glycol ethyl ether, diethylene glycol n-butyl ether, ethylene glycol phenyl ether, polyoxyethylene lauryl ether, and polyoxyethylene nonylphenyl ether.

Claim 13

An instant-setting adhesive composition according to claim 8, wherein the alcohol ester is one or more members selected from the group consisting of polyethylene glycol monolaurate, polyethylene glycol monostearate, glycerol monolaurate, glycerol monostearate, sorbitan monolaurate, and polyoxyethylene sorbitan monolaurate.

Claim 14

An instant-setting adhesive composition according to claim 8, wherein the crown ether compound is one or more members selected from the group consisting of 18-crown-6, dithia-15-crown, 15-crown-5, 18-crown-5, dibenzo-18-crown-6, dibenzo-24-crown-8, dicyclohexyl-18-crown-6, and 1,2-vinylbenzo-15-crown-5.

Claim 15

An instant-setting adhesive composition according to claim 8, wherein the amount of the lactone compound is 0.1 to 30 parts by weight per 100 parts by weight of the total amount of the 2-cyanoacrylate and the 1,1-disubstituted diene.

Claim 16

An instant-setting adhesive composition according to claim 8, wherein the amount of the lactone compound is 0.5 to 10 parts by weight per 100 parts by weight of the total amount of the 2-cyanoacrylate and the 1,1-disubstituted diene.

Claim 17

An instant-setting adhesive composition according to claim 8, wherein the amount of at least one compound selected from the group consisting of alcohols, alcohol ethers and alcohol esters is 0.001 to 5 parts by weight per 100 parts by weight of the total amount of the 2-cyanoacrylate and the 1,1-disubstituted diene.

Claim 18

An instant-setting adhesive composition according to claim 8, wherein the amount of at least one compound selected from the group consisting of alcohols, alcohol ethers and alcohol esters is 0.05 to 2 parts by weight per 100 parts by weight of the total amount of the 2-cyanoacrylate and the 1,1-disubstituted diene.

Claim 19

An instant-setting adhesive composition according to claim 8, wherein the amount of the crown ether compound is 0.001 to 5 parts by weight per 100 parts by weight of the total amount of the 2-cyanoacrylate ester and the 1,1-disubstituted diene.

Claim 20

An instant-setting adhesive composition according to claim 8 wherein the amount of the crown ether compound is 0.05 to 2 part by weight per 100 parts by weight of the total amount of the 2-cyanoacrylate and the 1,1-disubstituted diene.