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US4312744A Expired / Lapsed US ⏱️ 0.0 years remaining

FCC Process using low coke-make FCC catalyst

Assignee: Honeywell UOP LLC
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Filing: 1981-02-09
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Granted: 1982-01-26
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Expires: 2001-02-09
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Abstract

Abstract A process for cracking a hydrocarbon charge stock which uses a catalytic composite prepared by mixing a zeolitic crystalline aluminosilicate dispersed in a porous carrier material with a solution of rare earth salt, separating a filter cake from the slurry by a means not involving the washing of the filter cake and calcining the filter cake.

Inventors

  • 👤 Hosheng Tu
  • 👤 David C. DeCoster

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 09:45
CPC Classifications
B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/08; B01J29/084; C; C10; C10G; C10G11/00; C10G11/02; C10G11/04; C10G11/05

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 151 words
A process for cracking a hydrocarbon charge stock which comprises contacting said charge stock at cracking conditions with a catalytic composite prepared by the method which comprises: (a) preparing a catalyst powder comprising a zeolite crystalline aluminosilicate dispersed in a porous carrier material consisting essentially of silica, zirconia and alumina; (b) mixing said powder with a sufficient amount of an aqueous solution of a water soluble rare earth salt to form a slurry of said catalyst powder, the stoichiometric excess concentration of said rare earth salt in the solution being sufficient to impart to the final catalyst a weight ratio on a volatile free basis of rare earth ions to said carrier material greater than 1.0:100.0; (c) filtering or centrifuging said slurry to separate therefrom a filter cake containing said catalyst powder; and (d) calcining said filter cake without washing or drying said filter cake and recovering the resultant catalytic composite.
Claim 2
Dependent Claim 151 words
A process for cracking a hydrocarbon charge stock which comprises contacting said charge stock at cracking conditions with a catalytic composite prepared by the method which comprises: (a) preparing a catalyst powder comprising a zeolite crystalline aluminosilicate dispersed in a porous carrier material consisting essentially of silica, zirconia and alumina; (b) mixing said powder with a sufficient amount of an aqueous solution of a water soluble rare earth salt to form a slurry of said catalyst powder, the stoichiometric excess concentration of said rare earth salt in the solution being sufficient to impart to the final catalyst a weight ratio on a volatile free basis of rare earth ions to said carrier material greater than 1.0:100.0; (c) filtering or centrifuging said slurry to separate therefrom a filter cake containing said catalyst powder; and (d) calcining said filter cake without washing or drying said filter cake and recovering the resultant catalytic composite.
Claim 3
Dependent Claim 17 words
The process of claim 1 wherein said zeolitic crystalline aluminosilicate comprises a rare earth ion exchanged Y-zeolite.
Claim 4
Dependent Claim 11 words
The process of claim 1 wherein said rare earth comprises lanthanum.
Claim 5
Dependent Claim 14 words
The process of claim 1 wherein said rare earth salt comprises rare earth chloride.
Claim 6
Dependent Claim 42 words
The process of claim 1 wherein said calcining without washing or drying said filter cake is effected at a temperature of from about 200° C. to about 750° C. and a calcining time of from about 30 minutes to about 5 hours.
Claim 7
Dependent Claim 36 words
The process of claim 1 wherein said catalyst powder is obtained as a filter cake from an ion exchange procedure whereby sodium ions contained in the catalyst are exchanged with ammonium ions in an aqueous medium.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-01-25 1985-07-27 1986-01-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-01-25 1989-07-27 1990-01-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-01-25 1993-07-27 1994-01-26 $7700.00 Window Closed / Lapsed

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