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US4312682A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of heat treating nickel-base alloys for use as ceramic kiln hardware and product

Assignee: Haynes International Inc
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Filing: 1979-12-21
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Granted: 1982-01-26
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Expires: 1999-12-21
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Abstract

Abstract Disclosed is a NICRALY alloy containing nominally about 16% chromium, about 5.3% aluminum, about 0.02% yttrium and the balance essentially nickel, and heat treated in a manner to develop an essentially aluminum oxide surface. The NICRALY alloy is especially suited for use as components and support systems in kilns that are used in the firing steps in the manufacture of ceramic articles.

Inventors

  • 👤 Robert B. H. Herchenroeder

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 10:40
CPC Classifications
C; C22; C22C; C22C19/00; C22C19/03; C22C19/05

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 133 words
The method for producing a kiln hardware article for use in the manufacture of ceramic products including the steps of: a. providing an alloy consisting essentially of, in weight percent, 8 to 25 chromium, 2.5 to 8 aluminum, a small but effective yttrium content not exceeding over 0.04, and the balance nickel and impurities plus modifying elements optionally selected from the groups: up to 15 total Mo, Rh, Hf, W, Ta and Cb; up to 0.5 total C, B, Mg, Zr and Ca; up to 1Si, up to 2Mn, up to 20Co, up to 5Ti, and up to 30Fe b. fashioning said alloy into said article with a required shape for said use, and c. heat treating said fashioned article to provide a predominantly aluminum oxide film of the surface of said article.
Claim 2
Independent Claim 133 words
The method for producing a kiln hardware article for use in the manufacture of ceramic products including the steps of: a. providing an alloy consisting essentially of, in weight percent, 8 to 25 chromium, 2.5 to 8 aluminum, a small but effective yttrium content not exceeding over 0.04, and the balance nickel and impurities plus modifying elements optionally selected from the groups: up to 15 total Mo, Rh, Hf, W, Ta and Cb; up to 0.5 total C, B, Mg, Zr and Ca; up to 1Si, up to 2Mn, up to 20Co, up to 5Ti, and up to 30Fe b. fashioning said alloy into said article with a required shape for said use, and c. heat treating said fashioned article to provide a predominantly aluminum oxide film of the surface of said article.
Claim 3
Dependent Claim 25 words
The method of claim 1 wherein said alloy contains about 10 to 20 chromium, about 3 to 7 aluminum and about 0.005 to 0.035 yttrium.
Claim 4
Dependent Claim 23 words
The method of claim 1 wherein step "a" includes providing said alloy by ESR process and then hot and/or cold working said alloy.
Claim 5
Dependent Claim 28 words
The method of claim 1 wherein the heat treatment of step "c" comprises heat treating said article at a temperature over 2000° F. for at least one hour.
Claim 6
Dependent Claim 11 words
A kiln hardware article made by the process of claim 1.

References Cited (Backward Citations)

US3067473A Cited
GB1196714A Cited
GB1262757A Cited
US3754902A Cited
US3832167A Cited
GB1397066A Cited
GB1512811A Cited
GB1512984A Cited
GB1544720A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-01-25 1985-07-27 1986-01-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-01-25 1989-07-27 1990-01-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-01-25 1993-07-27 1994-01-26 $7700.00 Window Closed / Lapsed

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