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US4310657A
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Polymeric monohydroxybenzenoid hydroquinoid antioxidants
Assignee: BP Corp North America Inc
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Filing: 1979-06-25
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Granted: 1982-01-12
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Expires: 1999-06-25
Abstract
Abstract Compositions of oxidizable organic materials having stabilizing amounts of polymeric monohydroxybenzenoid hydroquinoid antioxidants of from about 500 to about 10,000 molecular weight, and the said polymers which are the reaction products of an alpha, alpha' alkyl aromatic compound containing a benzenoid ring, a hydroquinone compound and a monohydroxy benzenoid compound.
Inventors
- 👤 Carl Serres, Jr.
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 19:19
CPC Classifications
C; C08; C08G; C08G61/00; C08G61/12; C08G61/02; C08L; C08L101/00; C08G2261/00; C08G2261/30; C08G2261/31; C08G2261/34; C08G2261/342; C08G2261/3424
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
115 words
A monohydroxybenzenoid hydroquinoid polymer of the formula ##STR6## wherein R is a benzenoid ring group selected from the group consisting of benzene, naphthalene, biphenyl, diphenylmethane, thiophene, benzothiophene and dibenzothiophene moieties, wherein Ar is a benzenoid ring group selected from the group consisting of phenyl, naphthyl, anthranyl and phenanthranyl groups, and wherein R' is an alkyl group of 9 to 18 carbon atoms, and R", R'", R"" and R""' are independently selected from a group consisting of hydrogen, alkyls of one to 26 carbon atoms and aralkyls of from 7 to 26 carbon atoms, x and y are of the ratio of from 1:1 to 1:3 and n is an integer of from one to 20.
Claim 2
Dependent Claim
115 words
A monohydroxybenzenoid hydroquinoid polymer of the formula ##STR6## wherein R is a benzenoid ring group selected from the group consisting of benzene, naphthalene, biphenyl, diphenylmethane, thiophene, benzothiophene and dibenzothiophene moieties, wherein Ar is a benzenoid ring group selected from the group consisting of phenyl, naphthyl, anthranyl and phenanthranyl groups, and wherein R' is an alkyl group of 9 to 18 carbon atoms, and R", R'", R"" and R""' are independently selected from a group consisting of hydrogen, alkyls of one to 26 carbon atoms and aralkyls of from 7 to 26 carbon atoms, x and y are of the ratio of from 1:1 to 1:3 and n is an integer of from one to 20.
Claim 3
Dependent Claim
141 words
The polymer of claim 1 wherein the said polymer is the reaction product of (A) an alpha, alpha' alkyl aromatic compound of the formula QCH 2 RCH 2 Q wherein Q is selected from the group consisting of halogen, hydroxy, ethers and esters, the alkyl and acyl groups of said ethers and esters of from one to 12 carbon atoms, and R is the said benzenoid ring group, (B) a monohydroxybenzenoid compound of the formula H 2 Ar(OH)R'R"R'" wherein Ar is the said benzenoid ring group and R'R"R'" are the said hydrogen, alkyls and aralkyls and (C) a hydroquinone compound ##STR7## wherein R"" and R""' are the said hydrogen, alkyls and aralkyls and wherein the mole ratio of said alpha, alpha' alkyl aromatic compound to the additive mole ratio of the said monohydroxybenzenoid compound plus the said hydroquinone compound is 1:1.
Claim 4
Dependent Claim
26 words
The polymer of claim 2 wherein the said alpha, alpha' alkyl aromatic compound is selected from the group consisting of alpha, alpha'-dihalo ortho, meta, and paraxylenes.
Claim 5
Dependent Claim
36 words
The polymer of claim 2 wherein the said alpha, alpha' alkyl aromatic compound is selected from the group consisting of alpha, alpha'-dichloroparaxylene, alpha, alpha'-difluoroparaxylene, alpha, alpha'-dibromoparaxylene, alpha, alpha'-diiodoparaxylene, bis-chloromethyl biphenyl, bis-chloromethyltoluene, bis-chloromethylnaphthalene, bis-chloromethylthiophene, bis-chlorodiphenylmethane and bis-chloromethyldibenzothiophene.
Claim 6
Dependent Claim
42 words
The polymer of claim 2 wherein the said alpha, alpha' alkyl aromatic compound is alpha, alpha' dichloroparaxylene, the said hydroquinone compound is 1,4-dihydroxybenzene and the said monohydroxybenzenoid compound is selected from the group consisting of, para-nonylphenol, para-dodecyclphenol, 3-n-pentadecyl phenol and octadecyl phenol.
Claim 7
Dependent Claim
13 words
The said polymer of claim 5 wherein the said monohydroxybenzenoid compound is para-nonylphenol.
Claim 8
Dependent Claim
13 words
The said polymer of claim 5 wherein the said monohydroxybenzenoid compound is para-dodecylphenol.
Claim 9
Dependent Claim
13 words
The said polymer of claim 5 wherein the said monohydroxybenzenoid compound is 3-n-pentadecylphenol.
Claim 10
Dependent Claim
13 words
The said polymer of claim 5 wherein the said monohydroxybenzenoid compound is octadecylphenol.
Claim 11
Dependent Claim
31 words
The said polymer of claim 2 wherein the said alpha, alpha' alkyl aromatic compound is alpha, alpha'dichloroparaxylene, the said hydroquinone compound is tertiary butylhydroquinone and the said monohydroxybenzenoid compound is 3-n-pentadecylphenol.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-01-11 | 1985-07-13 | 1986-01-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-01-11 | 1989-07-13 | 1990-01-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-01-11 | 1993-07-13 | 1994-01-12 | $7700.00 | Window Closed / Lapsed |