Patent US4307254A successfully refreshed from Google Patents.
US4307254A
Expired / Lapsed
US
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Catalytic distillation process
Assignee: Catalytic Distillation Technologies
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Filing: 1980-02-25
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Granted: 1981-12-22
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Expires: 2000-02-25
Abstract
Abstract A method for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C4 feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.
Inventors
- 👤 Lawrence A. Smith, Jr.
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 22:20
CPC Classifications
C; C07; C07C; C07C41/00; C07C41/01; C07C41/05; C07C41/06; B; B01; B01D; B01D3/00; B01D3/009; B01J; B01J8/00; B01J8/02; C07C41/34; C07C41/40; C07C41/42; B01J2208/00; B01J2208/00008; B01J2208/00017; B01J2208/00026; B01J2208/00035; B01J2208/0007; B01J2208/00106; B01J2208/00168; B01J2208/00247; B01J2208/00539; B01J2208/00548; B01J2208/00557; Y; Y02; Y02P; Y02P20/00; Y02P20/10; Y10; Y10S; Y10S203/00; Y10S203/06
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
126 words
A method of preparing methyl tertiary butyl ether comprising: (a) feeding (1) a mixture containing isobutene and normal butene and (2) methanol to a distillation column reactor into a feed zone, (b) concurrently in said distillation column reactor: (1) contacting said mixture and said methanol with a fixed bed acid cation exchange resin packing in a distillation reaction zone thereby catalytically reacting the isobutene with methanol to form methyl tertiary butyl ether and (2) fractionating the resulting mixture of ether and normal butene in said fixed bed acid cation exchange resin packing, (c) withdrawing the ether from the distillation column reactor at a point below said feed zone and (d) withdrawing the normal butene from the distillation column reactor at a point above said feed zone.
Claim 2
Independent Claim
126 words
A method of preparing methyl tertiary butyl ether comprising: (a) feeding (1) a mixture containing isobutene and normal butene and (2) methanol to a distillation column reactor into a feed zone, (b) concurrently in said distillation column reactor: (1) contacting said mixture and said methanol with a fixed bed acid cation exchange resin packing in a distillation reaction zone thereby catalytically reacting the isobutene with methanol to form methyl tertiary butyl ether and (2) fractionating the resulting mixture of ether and normal butene in said fixed bed acid cation exchange resin packing, (c) withdrawing the ether from the distillation column reactor at a point below said feed zone and (d) withdrawing the normal butene from the distillation column reactor at a point above said feed zone.
Claim 3
Dependent Claim
28 words
The method according to claim 1 wherein the temperature of said column is the boiling point of the mixture and said methanol under the pressure in said column.
Claim 4
Dependent Claim
25 words
The method according to claim 2 wherein said reacting and fractionating are carried out at a pressure in the range of 10 to 300 psig.
Claim 5
Dependent Claim
28 words
The method according to claim 1 wherein isobutene is removed from the mixture in said process thereby producing an overhead having a substantially reduced amount of isobutene therein.
Claim 6
Dependent Claim
14 words
The process according to claim 1 wherein said methyl tertiary butyl ether is recovered.
Claim 7
Dependent Claim
21 words
The method according to claim 1 wherein the feed into the distillation column reactor contains less than 1 mole % water.
Claim 8
Dependent Claim
24 words
The method according to claim 1 wherein said feed zone is at the lower end of said fixed bed acid cation exchange resin packing.
Claim 9
Independent Claim
163 words
A method of preparing methyl tertiary butyl ether comprising: (a) feeding (1) a mixture containing isobutene and normal butene and (2) methanol to a distillation column reactor into a feed zone, (b) concurrently in said distillation column reactor: (1) contacting said mixture and said methanol with a fixed bed acid cation exchange resin packing in a distillation reaction zone thereby catalytically reacting the isobutene with methanol to form methyl tertiary butyl ether and (2) fractionating the resulting mixture of ether and normal butene in said fixed bed acid cation exchange resin packing, (c) withdrawing the ether from the distillation column reactor at a point below said feed zone and (d) withdrawing the normal butene from the distillation column reactor at a point above said feed zone, said fixed bed catalyst packing comprising acid cation exchange resin in a plurality of closed pockets in a cloth belt which is arranged and supported in the column by open mesh stainless steel wire intimately associated therewith.
Claim 10
Independent Claim
163 words
A method of preparing methyl tertiary butyl ether comprising: (a) feeding (1) a mixture containing isobutene and normal butene and (2) methanol to a distillation column reactor into a feed zone, (b) concurrently in said distillation column reactor: (1) contacting said mixture and said methanol with a fixed bed acid cation exchange resin packing in a distillation reaction zone thereby catalytically reacting the isobutene with methanol to form methyl tertiary butyl ether and (2) fractionating the resulting mixture of ether and normal butene in said fixed bed acid cation exchange resin packing, (c) withdrawing the ether from the distillation column reactor at a point below said feed zone and (d) withdrawing the normal butene from the distillation column reactor at a point above said feed zone, said fixed bed catalyst packing comprising acid cation exchange resin in a plurality of closed pockets in a cloth belt which is arranged and supported in the column by open mesh stainless steel wire intimately associated therewith.
Claim 11
Dependent Claim
18 words
The method according to claim 8 wherein said cloth belt and said stainless steel wire are twisted together.
Claim 12
Dependent Claim
22 words
The method according to claim 9 wherein said cloth belt and said stainless steel wire are twisted together into a helical form.
Claim 13
Dependent Claim
23 words
The method according to claim 10 wherein said fixed bed consists of a plurality of said cloth belts and wire in helical form.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-12-21 | 1985-06-22 | 1985-12-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-12-21 | 1989-06-22 | 1989-12-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-12-21 | 1993-06-22 | 1993-12-22 | $7700.00 | Window Closed / Lapsed |