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US4307240A
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Alkoxysilanes and method for making
Assignee: General Electric Co
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Filing: 1980-05-30
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Granted: 1981-12-22
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Expires: 2000-05-30
Abstract
Abstract Alkoxysilylacrylamides, alkoxysilylacrylates and alkoxysilylbenzylidene malonates are provided and a method for making such materials. These alkoxysilanes have been found useful as UV stabilizers and as adhesion promoters when incorporated into silicone compositions useful as top coats for thermoplastic organic polymers.
Inventors
- 👤 Ta-Yen Ching
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 12:22
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/54; C07; C07F; C07F7/00; C07F7/02; C07F7/08; C07C; C07C255/00; C07F7/18; C07F7/1804; C09; C09D; C09D183/00; C09D183/04
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
123 words
Alkoxysilylacrylamides or alkoxysilylacrylates having the formula, ##STR9## and alkoxysilylmalonates having the formula, ##STR10## where Y is ##STR11## and Y'is ##STR12## R is a C.sub.(1-8) alkyl radical, R 1 is selected from R, C.sub.(6-13) aryl radicals and halogenated derivatives thereof, R 2 is selected from hydrogen and R radicals, R 3 and R 5 are selected from C.sub.(6-13) aryl radicals, R 4 and R 6 are selected from hydrogen, R and R 3 radicals, Q is selected from--O--and ##STR13## a is an integer equal to 1 to 3 inclusive, b is a whole number equal to 0 to 2 inclusive and c is a whole number equal to 0 to 2 inclusive and the sum of a+b is equal to 1 to 3 inclusive.
Claim 2
Dependent Claim
123 words
Alkoxysilylacrylamides or alkoxysilylacrylates having the formula, ##STR9## and alkoxysilylmalonates having the formula, ##STR10## where Y is ##STR11## and Y'is ##STR12## R is a C.sub.(1-8) alkyl radical, R 1 is selected from R, C.sub.(6-13) aryl radicals and halogenated derivatives thereof, R 2 is selected from hydrogen and R radicals, R 3 and R 5 are selected from C.sub.(6-13) aryl radicals, R 4 and R 6 are selected from hydrogen, R and R 3 radicals, Q is selected from--O--and ##STR13## a is an integer equal to 1 to 3 inclusive, b is a whole number equal to 0 to 2 inclusive and c is a whole number equal to 0 to 2 inclusive and the sum of a+b is equal to 1 to 3 inclusive.
Claim 3
Dependent Claim
4 words
The compound (3-triethoxysilanepropyl)-β,β-diphenyl-α-cyanoacryl amide.
Claim 4
Dependent Claim
4 words
The compound (3-triethoxysilanepropyl)-β,β-diphenyl-α-cyanoacryl amide.
Claim 5
Dependent Claim
3 words
The compound (3-triethoxysilanepropyl)-β,β-diphenyl-α-cyanoacrylate.
Claim 6
Dependent Claim
3 words
The compound (3-triethoxysilanepropyl)-β,β-diphenyl-α-cyanoacrylate.
Claim 7
Dependent Claim
8 words
A benzylidene malonate compound having the formula, ##STR14##
Claim 8
Dependent Claim
8 words
A benzylidene malonate compound having the formula, ##STR14##
Claim 9
Independent Claim
145 words
A method for making an alkoxysilane of the formula, which comprises, (1) hydrolyzing a cyanoacrylate of the formula, ##STR15## in the presence of base, (2) converting the resulting cyanoacrylic acid to the corresponding acid halide, (3) effecting reaction between the resulting acrylic acid halide and an aminoalkyl alkoxysialne of the formula, (RO).sub.3 SiC(R.sup.2).sub.2 --CH(R.sup.2)--C(R.sup.2).sub.2 NH.sub.2 +C, where R is C.sub.(1-8) alkyl radical, R 1 is selected from R, C.sub.(6-13) aryl radicals and halogenated derivatives thereof, R 2 is selected from hydrogen and R radicals, R 3 is selected from C.sub.(6-13) aryl radicals, R 4 is selected from hydrogen, R and R 3 radicals, Y is ##STR16## Q is selected from --0--and ##STR17## a is an integer equal to 1 to 3 inclusive, b is a whole number equal to 0 to 2 inclusive and the sum of a+b is equal to 1 to 3 inclusive.
Claim 10
Independent Claim
145 words
A method for making an alkoxysilane of the formula, which comprises, (1) hydrolyzing a cyanoacrylate of the formula, ##STR15## in the presence of base, (2) converting the resulting cyanoacrylic acid to the corresponding acid halide, (3) effecting reaction between the resulting acrylic acid halide and an aminoalkyl alkoxysialne of the formula, (RO).sub.3 SiC(R.sup.2).sub.2 --CH(R.sup.2)--C(R.sup.2).sub.2 NH.sub.2 +C, where R is C.sub.(1-8) alkyl radical, R 1 is selected from R, C.sub.(6-13) aryl radicals and halogenated derivatives thereof, R 2 is selected from hydrogen and R radicals, R 3 is selected from C.sub.(6-13) aryl radicals, R 4 is selected from hydrogen, R and R 3 radicals, Y is ##STR16## Q is selected from --0--and ##STR17## a is an integer equal to 1 to 3 inclusive, b is a whole number equal to 0 to 2 inclusive and the sum of a+b is equal to 1 to 3 inclusive.
Claim 11
Independent Claim
141 words
A method for making alkoxysilanes of the formula, ##STR18## which comprises, (1) effecting reaction in the presence of base between a cyanoacrylate of the formula, ##STR19## and an allyl alcohol of the formula, HO--C(R.sup.2).sub.2 --C(R.sup.2)═C(R.sup.2).sub.2, (2) and effecting reaction between the resulting adduct of (1) and an alkoxysilane of the formula, ##STR20## in the presence of effective amount of platinum catalyst, where R is a C.sub.(1-8) alkyl radical, R 1 is selected from R, C.sub.(6-13) aryl radicals and halogenated derivatives thereof, R 3 is selected from C.sub.(6-13) aryl radicals, R 4 is selected from hydrogen, R and R 3 radicals, Y is ##STR21## Q is selected from--O--and ##STR22## a is an integer equal to 1 to 3 inclusive, b is a whole number equal to 0 to 2 inclusive and the sum of a+b is equal to 1 to 3 inclusive.
Claim 12
Independent Claim
141 words
A method for making alkoxysilanes of the formula, ##STR18## which comprises, (1) effecting reaction in the presence of base between a cyanoacrylate of the formula, ##STR19## and an allyl alcohol of the formula, HO--C(R.sup.2).sub.2 --C(R.sup.2)═C(R.sup.2).sub.2, (2) and effecting reaction between the resulting adduct of (1) and an alkoxysilane of the formula, ##STR20## in the presence of effective amount of platinum catalyst, where R is a C.sub.(1-8) alkyl radical, R 1 is selected from R, C.sub.(6-13) aryl radicals and halogenated derivatives thereof, R 3 is selected from C.sub.(6-13) aryl radicals, R 4 is selected from hydrogen, R and R 3 radicals, Y is ##STR21## Q is selected from--O--and ##STR22## a is an integer equal to 1 to 3 inclusive, b is a whole number equal to 0 to 2 inclusive and the sum of a+b is equal to 1 to 3 inclusive.
Claim 13
Independent Claim
125 words
A method for making alkoxysilanes of the formula, ##STR23## which comprises effecting reaction between an alkoxyaminosilane of the formula, (RO).sub.3 SiC(R.sup.2).sub.2 --CH(R.sup.2)--C(R.sup.2).sub.2 NH.sub.2, and a cyanoacrylate ester of the formula, ##STR24## in the presence of hydroxypyridene, where R is a C.sub.(1-8) alkyl radical, R 1 is selected from R, C.sub.(6-13) aryl radicals and hydrogenated drivatives thereof, R 2 is selected from hydrogen and R radicals, R 3 is selected from C.sub.(6-13) aryl radicals, R 4 is selected from hydrogen, R and R 3 radicals, Y is ##STR25## Q is selected from--O--and ##STR26## a is an integer equal to 1 to 3 inclusive, b is a whole number equal to 0 to 2 inclusive and the sum of a+b is equal to 1 to 3 inclusive.
Claim 14
Independent Claim
125 words
A method for making alkoxysilanes of the formula, ##STR23## which comprises effecting reaction between an alkoxyaminosilane of the formula, (RO).sub.3 SiC(R.sup.2).sub.2 --CH(R.sup.2)--C(R.sup.2).sub.2 NH.sub.2, and a cyanoacrylate ester of the formula, ##STR24## in the presence of hydroxypyridene, where R is a C.sub.(1-8) alkyl radical, R 1 is selected from R, C.sub.(6-13) aryl radicals and hydrogenated drivatives thereof, R 2 is selected from hydrogen and R radicals, R 3 is selected from C.sub.(6-13) aryl radicals, R 4 is selected from hydrogen, R and R 3 radicals, Y is ##STR25## Q is selected from--O--and ##STR26## a is an integer equal to 1 to 3 inclusive, b is a whole number equal to 0 to 2 inclusive and the sum of a+b is equal to 1 to 3 inclusive.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-12-21 | 1985-06-22 | 1985-12-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-12-21 | 1989-06-22 | 1989-12-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-12-21 | 1993-06-22 | 1993-12-22 | $7700.00 | Window Closed / Lapsed |