Thermosetting imide resins from dihydrazide

Claim 2

A thermosetting imide resin comprising the reaction product of (a) a mixture of an N,N'-bisimide of an unsaturated dicarboxylic acid of the general formula of ##STR10## and a monoimide of the general formula (II) ##STR11## wherein the residue A signifies a divalent organic group with at least two carbon atoms, E is selected from the group consisting of alkyl, cycloalkyl, and aryl groups and B a divalent organic group of the formulas indicated hereinbelow ##STR12## with (b) the dihydrazide of an organic dicarboxylic acid of the general formula (III) ##STR13## wherein D represents a divalent organic group, the molar proportion of the reaction between the unsaturated imide groups contained in the mixture and the hydrazide groups contained in the mixture ##EQU2## being between 1.1 and 100.

Claim 3

The imide resin of claim 1 wherein the bisimide is a bisimide selected from the group consisting of 1,2-bismaleimido ethane, 1,4-bismaleimido butane, 1,6-bismaleimido hexane, 1,12-bismaleimido dodecane, 1,6-bismaleimido-(2,2,4-trimethyl)hexane, 1,3-bismaleimido benzene, 1,4-bismaleimido benzene, 4,4'-bismaleimido diphenyl methane, 4,4'-bismaleimido diphenyl ether, 4,4'-bismaleimido diphenyl sulfide, 4,4'-bismaleimido diphenyl sulfone, 4,4'-bismaleimido dicyclohexyl methane, 2,4-bismaleimido toluene, 2,6-bismaleimido toluene, N,N'-m-xylylene bismaleimide, N,N'-p-xylylene bismaleimide, N,N'-m-phenylene biscitraconic acid imide, N,N'-4,4'-diphenylmethane citraconimide, and N,N-4,4'-diphenylmethane bisitaconimide.

Claim 4

The imide resin of claim 1 wherein the monoimide is a monoimide selected from the group consisting of N-methylmaleimide, N-ethylmaleimide, N-propylmaleimide, N-dodecylmaleimide, N-isobutylmaleimide, N-isopropylmaleimide, N-phenylmaleimide, N-phenylcitroconimide, N-phenylitaconimide, N-toluylmaleimide, N-mono-chlorophenylmaleimide, N-biphenylmaleimide, N-naphthylmaleimide, N-vinylmaleimide, N-allylmaleimide, and N-cyclohexylmaleimide.

Claim 5

The imide resin of claim 1 wherein the dicarboxylic acid dihydrazide is a dihydrazide selected from the group consisting of: oxalic acid dihydrazide, malonic acid dihydrazide, succinic acid dihydrazide, glutaric acid dihydrazide, adipic acid dihydrazide, pimelic acid dihydrazide, suberic acid dihydrazide, sebacic acid dihydrazide, cyclohexane dicarboxylic acid dehydrazide, terephthalic acid dihydrazide, isophthalic acid dihydrazide, 2,6-naphthalene dicarboxylic acid dihydrazide, 2,7-naphthalene dicarboxylic acid dihydrazide and mixtures of said dihydrazides.

Claim 6

The imide resin of claim 1, said resin being prepared by using a mixture of bisimides as the bisimide reactant.

Claim 7

The imide resin of claim 1, said resin being prepared by using a mixture of monoimides as the monoimide reactant.

Claim 8

The imide resin of claim 1, said resin being prepared by using a mixture of dicarboxylic acid dihydrazide as the dihydrazide reactant.

Claim 9

The imide resin of claim 1, said resin being prepared by reacting 4,4'-bismaleimido diphenylmethane, maleimidobenzene and isophthalic acid dihydrazide.

Claim 10

The imide resin of claim 1 containing an organic peroxide as curing catalyst.

Claim 11

The imide resin of claim 1 containing a curing inhibitor.

Claim 12

In a process of producing a thermosetting imide resin, the step which comprises heating (a) a mixture of an N,N'-bisimide of an unsaturated dicarboxylic acid of the general formula of ##STR14## and a monoimide of the general formula (II) ##STR15## wherein the residue A signifies a divalent organic group with at least two carbon atoms, E is selected from the group consisting of alkyl, cycloalkyl, and aryl groups and B a divalent organic group of the formulas indicated hereinbelow ##STR16## with (b) the dihydrazide of an organic dicarboxylic acid of the general formula (III) ##STR17## wherein D represents a divalent organic group, the molar proportion of the reaction between the unsaturated imide groups contained in the mixture and the hydrazide groups contained in the mixture ##EQU3## being between 1.1 and 100 in a molar proportion of imide groups to dihydrazide group between about 1.1 and about 100 in an organic diluent to a temperature not substantially exceeding about 180° C. for a period of time to yield a moldable and curable, thermosetting prepolymerized imide resin.

Claim 13

In a process of producing a thermosetting imide resin, the step which comprises heating (a) a mixture of an N,N'-bisimide of an unsaturated dicarboxylic acid of the general formula of ##STR14## and a monoimide of the general formula (II) ##STR15## wherein the residue A signifies a divalent organic group with at least two carbon atoms, E is selected from the group consisting of alkyl, cycloalkyl, and aryl groups and B a divalent organic group of the formulas indicated hereinbelow ##STR16## with (b) the dihydrazide of an organic dicarboxylic acid of the general formula (III) ##STR17## wherein D represents a divalent organic group, the molar proportion of the reaction between the unsaturated imide groups contained in the mixture and the hydrazide groups contained in the mixture ##EQU3## being between 1.1 and 100 in a molar proportion of imide groups to dihydrazide group between about 1.1 and about 100 in an organic diluent to a temperature not substantially exceeding about 180° C. for a period of time to yield a moldable and curable, thermosetting prepolymerized imide resin.

Claim 14

The process of claim 11, in which the diluent is an inert, polar organic solvent.

Claim 15

The process of claim 12, in which the inert, polar organic solvent is a solvent selected from the group consisting of dimethylformamide, dimethylacetamide, N-methylpyrrolidone, and tetramethyl urea.

Claim 16

The process of claim 11, comprising the additional step of hardening and curing the prepolymerized imide resin by further heating the same to a temperature between about 100° C. and about 350° C. to yield a substantially insoluble, infusible, cross-linked polymerized imide resin of high thermal stability.

Claim 17

The process of claim 14, in which the additional step is carried out with the addition of a curing accelerating catalyst.

Claim 18

The process of claim 11, in which the step of producing the prepolymerized imide resin is carried out with the addition of a curing inhibiting agent.

Claim 19

The solution of moldable and curable, thermosetting, prepolymerized imide resin of claim 1 in an inert, polar, organic solvent, said solution being stable on storage for a prolonged period of time without its viscosity substantially increasing during said storage.