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US4303549A Expired / Lapsed US ⏱️ 0.0 years remaining

Liquid defoamer and defoaming process

Assignee: Ashland Inc
•
Filing: 1980-03-31
•
Granted: 1981-12-01
•
Expires: 2000-03-31
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Abstract

Abstract A free flowing aqueous defoamer comprised of a solid alcohol, a solid fatty acid, a soap of a solid fatty acid and an anionic and/or non-ionic surfactant which prevents formation of a gelled mass of the solids and provides a free flowing dispersion of the solids in the water, with the solids contents being at least 5%, preferably at least 20%, all by weight, and with such solids having been treated to provide hydrophobic surfaces. A water soluble salt of a metal having a valence of greater than 1, such as aluminum, iron, magnesium, or calcium may be added to the composition to provide hydrophobic particle surfaces.

Inventors

  • 👤 Francis J. Boylan

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 05:11
CPC Classifications
B; B01; B01D; B01D19/00; B01D19/02; B01D19/04; B01D19/0404

Claims Analysis

Total Claims: 29
Claim 1
Independent Claim 210 words
A pumpable free flowing aqueous defoaming composition which can be stored in a ready to use form, comprising: (a) water; (b) at least one solid alcohol having from 14 to 28 carbon atoms; (c) at least one solid fatty acid; (d) at least one soap of a solid fatty acid, said components (b), (c) and (d) being present in the water in an effective defoaming amount and to provide a dispersed solids content in the water of at least 5%; (e) a surfactant comprised of at least one member selected from the group consisting of non-ionic surfactants and anionic surfactants selected from the group consisting of: alcohol sulfates alkaryl sulfonates ethoxylated alcohol sulfates sulfates and sulfonates of ethoxylated alkyl phenols sulfates of fatty esters sulfates and sulfonates of alkyl phenols sulfonates of condensed naphthalenes sulfonates of naphthalene sodium derivatives of sulfo-succinates alkali salts of petroleum sulfonates alkali phosphate esters sulfonated alkyl esters sodium polymeric carboxylic acid which surfactant prevents formation of a gelled mass of the solids to provide a pumpable free flowing dispersion of the solids in the water, said dispersed solids having been treated with at least one water soluble salt selected from the group consisting of calcium, iron, magnesium, barium and aluminum salts to provide hydrophobic surfaces.
Claim 2
Dependent Claim 210 words
A pumpable free flowing aqueous defoaming composition which can be stored in a ready to use form, comprising: (a) water; (b) at least one solid alcohol having from 14 to 28 carbon atoms; (c) at least one solid fatty acid; (d) at least one soap of a solid fatty acid, said components (b), (c) and (d) being present in the water in an effective defoaming amount and to provide a dispersed solids content in the water of at least 5%; (e) a surfactant comprised of at least one member selected from the group consisting of non-ionic surfactants and anionic surfactants selected from the group consisting of: alcohol sulfates alkaryl sulfonates ethoxylated alcohol sulfates sulfates and sulfonates of ethoxylated alkyl phenols sulfates of fatty esters sulfates and sulfonates of alkyl phenols sulfonates of condensed naphthalenes sulfonates of naphthalene sodium derivatives of sulfo-succinates alkali salts of petroleum sulfonates alkali phosphate esters sulfonated alkyl esters sodium polymeric carboxylic acid which surfactant prevents formation of a gelled mass of the solids to provide a pumpable free flowing dispersion of the solids in the water, said dispersed solids having been treated with at least one water soluble salt selected from the group consisting of calcium, iron, magnesium, barium and aluminum salts to provide hydrophobic surfaces.
Claim 3
Dependent Claim 29 words
The composition of claim 1 wherein the salt is added in an amount sufficient to react with from 15% to 25% of the fatty acid present in the composition.
Claim 4
Dependent Claim 15 words
The composition of claim 1 wherein the solids content is at least 20%, by weight.
Claim 5
Dependent Claim 13 words
The composition of claim 3 wherein the at least one salt is alum.
Claim 6
Dependent Claim 16 words
The composition of claim 1 wherein the solids content is no greater than 30%, by weight.
Claim 7
Dependent Claim 21 words
The composition of claim 1 wherein the solid alcohol is an aliphatic hydrocarbon alcohol having from 14 to 28 carbon atoms.
Claim 8
Dependent Claim 23 words
The composition of claim 6 wherein the solid fatty acid is an aliphatic hydrocarbon fatty acid having from 14 to 28 carbon atoms.
Claim 9
Dependent Claim 14 words
The composition of claim 7 wherein the surfactant is at least one non-ionic surfactant.
Claim 10
Dependent Claim 42 words
The composition of claim 8 wherein the non-ionic surfactant is a polyoxyethylene having more than two oxyethylene groups having at least one end group terminated by condensation with a member selected from the group consisting of alcohols, alkyl phenols and fatty acids.
Claim 11
Dependent Claim 15 words
The composition of claim 9 wherein the non-ionic surfactant contains at least 5 oxyethylene groups.
Claim 12
Dependent Claim 17 words
The composition of claim 10 wherein the at least one water soluble salt is an aluminum salt.
Claim 13
Dependent Claim 13 words
The composition of claim 10 wherein the at least one salt is alum.
Claim 14
Dependent Claim 37 words
The composition of claim 10 wherein the surfactant is present in an amount to provide at least 0.1 part by weight of surfactant per 1 part by weight of the total of components (b), (c) and (d).
Claim 15
Dependent Claim 23 words
The composition of claim 13 wherein the weight ratio of fatty acid to alcohol is at least 0.2:1 and no greater than 0.5:1.
Claim 16
Dependent Claim 20 words
The composition of claim 13 wherein the weight ratio of fatty acid soap to alcohol is from 0.1:1 to 0.5:1.
Claim 17
Dependent Claim 19 words
The composition of claim 15 wherein the oxyethylene polymer has one end group terminated by condensation with nonyl phenol.
Claim 18
Dependent Claim 12 words
The composition of claim 1 wherein the surfactant is an anionic surfactant.
Claim 19
Dependent Claim 12 words
The composition of claim 1 wherein the soap is an amine soap.
Claim 20
Dependent Claim 13 words
The composition of claim 18 wherein the soap is a soap of triethanolamine.
Claim 21
Dependent Claim 17 words
The composition of claim 1 wherein the at least one water soluble salt is an aluminum salt.
Claim 22
Dependent Claim 15 words
The composition of claim 20 wherein said at least one water soluble salt is alum.
Claim 23
Dependent Claim 20 words
The composition of claim 1 wherein the surfactant is an ethoxylated nonyl phenol having at least five ethylene oxide groups.
Claim 24
Dependent Claim 26 words
A process for defoaming in an aqueous system, comprising: adding to the aqueous system an effective defoaming amount of a composition as defined in claim 1.
Claim 25
Dependent Claim 23 words
The process of claim 23 wherein the composition is added to provide at least 1 ppm of the composition in the aqueous system.
Claim 26
Dependent Claim 15 words
The process of claim 23 wherein the at least one salt is an aluminum salt.
Claim 27
Dependent Claim 46 words
The process of claim 25 wherein the surfactant is a non-ionic surfactant which is a polyoxyethylene having more than two oxyethylene groups having at least one end group terminated by condensation with a member selected from the group consisting of alcohols, alkyl phenols and fatty acids.
Claim 28
Dependent Claim 13 words
The process of claim 23 wherein the at least one salt is alum.
Claim 29
Dependent Claim 13 words
The process of claim 23 wherein the aqueous system is paper machine stock.

References Cited (Backward Citations)

CA534604A Cited
US1831928A Cited
US2797198A Cited
US3215635A Cited
GB1402597A Cited
US4088601A Cited
US4087398A Cited
GB2038793A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-11-30 1985-06-01 1985-12-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-11-30 1989-06-01 1989-12-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-11-30 1993-06-01 1993-12-01 $7700.00 Window Closed / Lapsed

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