Patent US4301114A successfully refreshed from Google Patents.
US4301114A
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Molecular sieve trap for nitrogen compound detection
Assignee: Thermo Fisher Scientific Inc
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Filing: 1980-06-30
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Granted: 1981-11-17
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Expires: 2000-06-30
Abstract
Abstract A molecular sieve trap is disclosed for selective trapping of substances in a gas stream, the trap being particularly useful in systems for detecting nitrogen compounds such as N-nitrosamines or nitrogen oxides in a sample. The trap comprises a cartridge containing a packing of a granular adsorbent molecular sieve material with a carefully controlled pore size of about ten angstroms and a preference for adsorbing polar substances. The packing readily passes NO and NO 2 gases in a gas stream directed through the trap while trapping and retaining larger and/or more polar molecules such as those of double-bonded carbon compounds and sulfur compounds which could otherwise interfere with subsequent measurement of the NO or NO x content of the gas stream. An N-nitroso compound detection system incorporating the molecular sieve trap is described wherein the molecular sieve trap is interposed between a pyrolyzer and a chemiluminescent NO detector to selectively trap substances in the reactor effluent. Also disclosed is a NO x detection system having a molecular sieve trap in a sample inlet line of a NO x detector.
Inventors
- 👤 David P. Rounbehler
- 👤 John W. Reisch
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 13:14
CPC Classifications
G; G01; G01N; G01N21/00; G01N21/75; G01N21/76; G01N21/766; B; B01; B01D; B01D53/00; B01D53/02; Y; Y10; Y10T; Y10T436/00; Y10T436/17; Y10T436/170769; Y10T436/177692; Y10T436/179228
Claims Analysis
Total Claims: 24
Claim 1
Independent Claim
87 words
Apparatus for selectively trapping substances in a gas stream comprising a cartridge having an inlet at one end for receiving a gas stream, an outlet at the end opposite said inlet end, and a shell defining a chamber between said inlet and said outlet, said chamber containing a packing of a granular molecular sieve material permeable to the flow therethrough of NO gas and adapted to trap and hold substances therein which might otherwise interfere with measurement of the NO gas which has passed through said packing.
Claim 2
Dependent Claim
87 words
Apparatus for selectively trapping substances in a gas stream comprising a cartridge having an inlet at one end for receiving a gas stream, an outlet at the end opposite said inlet end, and a shell defining a chamber between said inlet and said outlet, said chamber containing a packing of a granular molecular sieve material permeable to the flow therethrough of NO gas and adapted to trap and hold substances therein which might otherwise interfere with measurement of the NO gas which has passed through said packing.
Claim 3
Dependent Claim
19 words
Apparatus as in claim 1 wherein said molecular sieve material has a nominal pore diameter of about 10 angstroms.
Claim 4
Dependent Claim
18 words
Apparatus as in claim 1 or 2 wherein said molecular sieve material is a crystalline sodium alumino-silicate material.
Claim 5
Dependent Claim
58 words
Apparatus as in claim 1 wherein said chamber contains, in addition to said packing of granular molecular sieve material, a second packing of a drying agent between said inlet and said packing of granular molecular sieve material, said drying agent being permeable to the flow therethrough of NO gas and adapted to remove water from the gas stream.
Claim 6
Dependent Claim
30 words
Apparatus as in claim 4 wherein said drying agent is a granular material selected from the group consisting of sodium sulfate, calcium sulfate, phosphorous pentachloride, aluminum silicates, and combinations thereof.
Claim 7
Dependent Claim
26 words
Apparatus as in claim 1 further including porous retainer means adjacent to the inlet and outlet of said cartridge for holding said packing in said chamber.
Claim 8
Dependent Claim
17 words
Apparatus as in claim 1 and 2 wherein said particles are of 60 to 80 mesh size.
Claim 9
Dependent Claim
141 words
Apparatus for measuring in a sample the amount of predetermined nitrogen compounds comprising: a chromatograph for receiving said sample and producing an effluent including, at separate intervals of time, a first portion containing said predetermined nitrogen compounds and a second portion without said compounds; a reactor for selectively liberating NO gas from the nitrogen compounds of said first portion, thereby producing a reactor effluent containing NO gas; a NO detector for measuring the amount of NO gas liberated in said reactor; and a trap between said reactor and said detector for selectively trapping substances from said reactor effluent, said trap including a packing of a granular molecular sieve material permeable to the flow therethrough of NO gas and effective to trap and hold substances whose presence in said detector might interfere with measurement of the NO gas liberated by said reactor.
Claim 10
Dependent Claim
141 words
Apparatus for measuring in a sample the amount of predetermined nitrogen compounds comprising: a chromatograph for receiving said sample and producing an effluent including, at separate intervals of time, a first portion containing said predetermined nitrogen compounds and a second portion without said compounds; a reactor for selectively liberating NO gas from the nitrogen compounds of said first portion, thereby producing a reactor effluent containing NO gas; a NO detector for measuring the amount of NO gas liberated in said reactor; and a trap between said reactor and said detector for selectively trapping substances from said reactor effluent, said trap including a packing of a granular molecular sieve material permeable to the flow therethrough of NO gas and effective to trap and hold substances whose presence in said detector might interfere with measurement of the NO gas liberated by said reactor.
Claim 11
Dependent Claim
74 words
Apparatus as in claim 8 wherein said predetermined nitrogen compounds are N-nitroso compounds having the general formula ##STR2## wherein R 1 and R 2 are the same or different organic radicals, including those radicals which together with the non-nitroso N of the depicted N--NO bond constitute a nitrogen heterocyclic radical; and wherein said reactor is operable to selectively liberate NO gas from said N-nitroso compounds by breaking the N--NO bonds of said N-nitroso compounds.
Claim 12
Dependent Claim
29 words
Apparatus as in claim 9 wherein said reactor comprises a pyrolyzer for heating the N-nitroso compounds with an amount of thermal energy effective to break the N--NO bonds thereof.
Claim 13
Dependent Claim
22 words
Apparatus as in claim 8 wherein said molecular sieve material comprises particles having pores with a nominal diameter of about 10 angstroms.
Claim 14
Dependent Claim
16 words
Apparatus as in claim 11 wherein said molecular sieve material is a crystalline sodium alumino-silicate material.
Claim 15
Dependent Claim
15 words
Apparatus as in claim 8 wherein said particles are of 60 to 80 mesh size.
Claim 16
Dependent Claim
31 words
Apparatus as in claim 8 wherein said chromatograph comprises a gas chromatograph including a column and means for driving a mixture of said sample and a carrier gas through said column.
Claim 17
Dependent Claim
80 words
Apparatus as in claim 8 wherein said trap comprises a cartridge having an inlet for receiving said reactor effluent, an outlet, and a cylindrical shell defining a chamber between said inlet and said outlet, said chamber containing said packing of molecular sieve material and also containing, between said inlet and said packing of molecular sieve material, a second packing of a drying agent permeable to the flow therethrough of NO gas and adapted to remove water from said reactor effluent.
Claim 18
Dependent Claim
131 words
Apparatus for measuring in a gaseous sample the concentration of at least one oxide of nitrogen comprising: a reaction chamber for permitting a chemiluminescent reaction therein of a selected constituent of the sample with a reagent; means for supplying said reagent and said gaseous sample to the reaction chamber; means for detecting the light produced in said chamber during a chemiluminescent reaction; and a trap for selectively removing substances from said gaseous sample prior to entry of said sample into said reaction chamber, said trap comprising a packing of a granular molecular sieve material permeable to the flow therethrough of NO and NO 2 gases and effective to trap and hold substances whose presence in said reaction chamber might interefere with measurement of NO or NO 2 gas in said sample.
Claim 19
Dependent Claim
131 words
Apparatus for measuring in a gaseous sample the concentration of at least one oxide of nitrogen comprising: a reaction chamber for permitting a chemiluminescent reaction therein of a selected constituent of the sample with a reagent; means for supplying said reagent and said gaseous sample to the reaction chamber; means for detecting the light produced in said chamber during a chemiluminescent reaction; and a trap for selectively removing substances from said gaseous sample prior to entry of said sample into said reaction chamber, said trap comprising a packing of a granular molecular sieve material permeable to the flow therethrough of NO and NO 2 gases and effective to trap and hold substances whose presence in said reaction chamber might interefere with measurement of NO or NO 2 gas in said sample.
Claim 20
Dependent Claim
22 words
Apparatus as in claim 16 wherein said molecular sieve material comprises particles having pores with a nominal diameter of about 10 angstroms.
Claim 21
Dependent Claim
20 words
Apparatus as in claim 16 wherein said reagent is ozone and said selected constituent of the sample is NO gas.
Claim 22
Dependent Claim
24 words
Apparatus as in claim 16 wherein said molecular sieve material comprises particles of a crystalline sodium alumino-silicate material of 60 to 80 mesh size.
Claim 23
Dependent Claim
48 words
Apparatus as in claim 19 wherein said trap further comprises a packing of a drying agent permeable to the flow therethrough of NO and NO 2 gases and operable to remove water from said sample prior to passage of said sample through said packing of molecular sieve material.
Claim 24
Dependent Claim
53 words
Apparatus as in claim 16 further including an NO 2 converter between, and in fluid communication with, said trap and said reaction chamber for converting NO 2 gas in said sample to NO gas, thereby to permit measurement of the total concentration of NO gas and NO 2 gas of said gaseous sample.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-11-16 | 1985-05-18 | 1985-11-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-11-16 | 1989-05-18 | 1989-11-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-11-16 | 1993-05-18 | 1993-11-17 | $7700.00 | Window Closed / Lapsed |