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US4298702A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the manufacture of flame retardant polystyrene foams

Assignee: BASF SE
•
Filing: 1980-08-04
•
Granted: 1981-11-03
•
Expires: 2000-08-04
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Abstract

Abstract This invention relates to a process of making flame-retardant polystyrene foams by an extrusion process in which a stabilizer of a dialkyl-tin carboxylate or a mixture of a dialkyl tin carboxylate and a barium and/or cadmium carboxylate is added to the extrusion melt.

Inventors

  • 👤 Klaus Hahn
  • 👤 Klaus Hinselmann
  • 👤 Klaus Halbritter
  • 👤 Walter Rebafka
  • 👤 Heinz Weber

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 19:12
CPC Classifications
C; C08; C08J; C08J9/00; C08J9/0014; C08J9/0052; C08J2325/00; C08J2325/02; C08J2325/04; Y; Y10; Y10S; Y10S260/00; Y10S260/24; Y10S521/00; Y10S521/907

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 122 words
In a process for the manufacture of a flame-retardant polystyrene foam by melting polystyrene in an extruder, mixing the polystyrene at a temperature over 180° C. with 5 weight percent to 20 weight percent, based on the weight of polystyrene, of a volatile blowing agent and 0.5 weight percent to 10 weight percent, based on the weight of polystyrene, of an organic halogen compound extruding the mixture into the surrounding atmosphere, and subsequently cooling the foam, the improvement which comprises adding from 0.01 weight percent to 5 weight percent, based on the weight of polystyrene, of a dialkyl-tin carboxylate, and 0.01 weight percent to 5 weight percent, based on the weight of polystyrene, of a barium and/or cadmium carboxylate to the mixture.
Claim 2
Dependent Claim 122 words
In a process for the manufacture of a flame-retardant polystyrene foam by melting polystyrene in an extruder, mixing the polystyrene at a temperature over 180° C. with 5 weight percent to 20 weight percent, based on the weight of polystyrene, of a volatile blowing agent and 0.5 weight percent to 10 weight percent, based on the weight of polystyrene, of an organic halogen compound extruding the mixture into the surrounding atmosphere, and subsequently cooling the foam, the improvement which comprises adding from 0.01 weight percent to 5 weight percent, based on the weight of polystyrene, of a dialkyl-tin carboxylate, and 0.01 weight percent to 5 weight percent, based on the weight of polystyrene, of a barium and/or cadmium carboxylate to the mixture.
Claim 3
Dependent Claim 13 words
The process of claim 1 in which the dialkyl-tin carboxylate is dibutyltin dilaurate.
Claim 4
Dependent Claim 13 words
The process of claim 1 in which the dialkyl-tin carboxylate is dibutyltin maleate.
Claim 5
Dependent Claim 13 words
The process of claim 1 in which the cadmium carboxylate is cadmium stearate.
Claim 6
Dependent Claim 13 words
The process of claim 1 in which the barium carboxylate is barium stearate.
Claim 7
Dependent Claim 13 words
The process of claim 1 in which the cadmium carboxylate is cadmium palmitate.
Claim 8
Dependent Claim 13 words
The process of claim 1 in which the barium carboxylate is barium palmitate.
Claim 9
Dependent Claim 47 words
The process of claim 1 in which 0.05 weight percent to 1 weight percent, based on the weight of polystyrene, of the dialkyl tin carboxylate, and 0.05 weight percent to 1 weight percent, based on the weight of polystyrene of a barium and/or cadmium carboxylate is added.
Claim 10
Dependent Claim 42 words
The process of claim 1 in which about 0.1 to 0.3 weight percent dialkyltin carboxylate, 0.03 to 0.07 weight percent of a cadmium carboxylate and 0.03 to 0.07 weight percent of a barium carboxylate are added to the mixture as a stabilizer.
Claim 11
Dependent Claim 22 words
The process of claim 1 in which about 0.3 weight percent dialkyltin carboxylate and about 0.1 weight percent cadmium carboxylate is added.

References Cited (Backward Citations)

US2590211A Cited
US2924532A Cited
US4089912A Cited
US4113672A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-11-02 1985-05-04 1985-11-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-11-02 1989-05-04 1989-11-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-11-02 1993-05-04 1993-11-03 $7700.00 Window Closed / Lapsed

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