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US4296224A Expired / Lapsed US ⏱️ 0.0 years remaining

Perfluoroalkyl-acr[methacr]ylate, hydroxy-chloropropyl-acrylate polymer

Assignee: Daikin Industries Ltd
•
Filing: 1979-09-26
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Granted: 1981-10-20
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Expires: 1999-09-26
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Abstract

Abstract A water and oil repellent essentially consisting of a copolymer comprising units of (a) at least one of fluoroalkyl group-containing polymerizable compounds and of (b) at least one of 2-hydroxy-3-chloropropyl acrylate and methacrylate of the formula: CH2=CRCOOCH2CH(OH)CH2Cl wherein R is hydrogen or methyl, which is highly resistant to laundering and dry cleaning.

Inventors

  • 👤 Shosin Fukui
  • 👤 Tadashi Akazawa

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 13:11
CPC Classifications
D; D06; D06M; D06M15/00; D06M15/19; D06M15/21; D06M15/263; D06M15/277; D06M15/273

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 60 words
A water and oil repellent consisting essentially of a copolymer comprising units of (a) at least 25% by weight of at least one of perfluoroalkyl group-containing acrylates and methacrylates and of (b) from 0.1 to 10% by weight of at least one of 2-hydroxy-3-chloropropyl acrylate and methacrylate of the formula: CH.sub.2 ═CRCOOCH.sub.2 CH(OH)CH.sub.2 Cl wherein R is hydrogen or methyl.
Claim 2
Dependent Claim 60 words
A water and oil repellent consisting essentially of a copolymer comprising units of (a) at least 25% by weight of at least one of perfluoroalkyl group-containing acrylates and methacrylates and of (b) from 0.1 to 10% by weight of at least one of 2-hydroxy-3-chloropropyl acrylate and methacrylate of the formula: CH.sub.2 ═CRCOOCH.sub.2 CH(OH)CH.sub.2 Cl wherein R is hydrogen or methyl.
Claim 3
Dependent Claim 45 words
The water and oil repellent according to claim 1, wherein the copolymer comprises, in addition to the components (a) and (b), units of (c) at least one of other polymerizable compounds having no fluoroalkyl group in an amount of from 5 to 74.9% by weight.
Claim 4
Dependent Claim 60 words
A water and oil repellent composition which comprises a copolymer comprising units of (a) at least 25% by weight of at least one of perfluoroalkyl group-containing acrylates and methacrylates and of (b) from 0.1 to 10% by weight of at least one of 2-hydroxy-3-chloropropyl acrylate and methacrylate of the formula: CH.sub.2 ═CRCOOCH.sub.2 CH(OH)CH.sub.2 Cl wherein R is hydrogen or methyl.
Claim 5
Dependent Claim 60 words
A water and oil repellent composition which comprises a copolymer comprising units of (a) at least 25% by weight of at least one of perfluoroalkyl group-containing acrylates and methacrylates and of (b) from 0.1 to 10% by weight of at least one of 2-hydroxy-3-chloropropyl acrylate and methacrylate of the formula: CH.sub.2 ═CRCOOCH.sub.2 CH(OH)CH.sub.2 Cl wherein R is hydrogen or methyl.
Claim 6
Dependent Claim 39 words
The water and oil repellent composition according to claim 3, wherein the copolymer comprises additionally units of (c) at least one of other polymerizable compounds having no fluoroalkyl group in an amount of from 5 to 74.9% by weight.
Claim 7
Dependent Claim 24 words
The water and oil repellent according to claim 2, wherein the other polymerizable compounds having no fluoroalkyl group are stearyl acrylate and/or stearyl methacrylate.
Claim 8
Dependent Claim 24 words
The water and oil repellent according to claim 4, wherein the other polymerizable compounds having no fluoroalkyl group are stearyl acrylate and/or stearyl methacrylate.

References Cited (Backward Citations)

GB926283A Cited
US3514420A Cited
US3624139A Cited
US3645989A Cited
US3901864A Cited
US3944527A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-10-19 1985-04-20 1985-10-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-10-19 1989-04-20 1989-10-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-10-19 1993-04-20 1993-10-20 $7700.00 Window Closed / Lapsed

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