Patent US4296190A successfully refreshed from Google Patents.
US4296190A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Photosensitive material for use in electrophotography with a radiation cured binder resin
Assignee: Ricoh Co Ltd
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Filing: 1979-06-11
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Granted: 1981-10-20
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Expires: 1999-06-11
Abstract
Abstract The present invention provides a photosensitive material for use in electrophotography which is superior in durability, resistance to solvents and light sensitivity, which comprises a photoconductive layer consisting essentially of an inorganic or organic photoconductor and an ionizing radiation-curable resin as formed on a conductive support, said photoconductive layer having been cured by applying said radiation.
Inventors
- 👤 Haruo Hasegawa
- 👤 Hiroyoshi Taniguchi
- 👤 Takao Igawa
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 11:42
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/05; G03G5/0528; G03G5/0592; G03G5/043; G03G5/047
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
254 words
An electrophotographic plate, comprising: an electrically conductive substrate; a first photoconductive layer coated over said substrate and having a thickness of from 0.1μ to 10μ, said first photoconductive layer consisting essentially of a mixture of an inorganic or organic first photoconductor and a resin that has been cured by ionizing radiation, said first photoconductive layer having been prepared by applying onto said substrate a liquid dispersion or solution of said first photoconductor and from 0.2 to 50 percent by weight, based on the weight of said first photoconductor, of a radiation-curable resin selected from the group consisting of non-modified maleic anhydride-type unsaturated polyester, silicone-modified, urethane-modified or acrylic urethane-modified maleic anhydride-type unsaturated polyester, polyester having maleyl group therein, acrylic polymer having maleyl group therein, epoxide resin having maleyl group therein, acrylic polymer having acryloyl group as a side chain thereof, telomerized polyester acrylate, telomerized polyamide acrylate, epoxyacrylate, urethane acrylate, silicone acrylate, and reactive allyl group-containing resin, and then applying ionizing radiation to said first photoconductive layer, in a solvent-free state, until said radiation-curable resin has been cured; and a second photoconductive layer coated over said first photoconductive layer and having a thickness of from 3μ to 50μ, said second photoconductive layer consisting essentially of an organic second photoconductor and a resin binder therefor, said second photoconductive layer having been prepared by applying a liquid dispersion or solution of said organic second photoconductor and said resin binder in an organic solvent onto said first photoconductive layer having said cured resin therein and then evaporating the solvent.
Claim 2
Dependent Claim
254 words
An electrophotographic plate, comprising: an electrically conductive substrate; a first photoconductive layer coated over said substrate and having a thickness of from 0.1μ to 10μ, said first photoconductive layer consisting essentially of a mixture of an inorganic or organic first photoconductor and a resin that has been cured by ionizing radiation, said first photoconductive layer having been prepared by applying onto said substrate a liquid dispersion or solution of said first photoconductor and from 0.2 to 50 percent by weight, based on the weight of said first photoconductor, of a radiation-curable resin selected from the group consisting of non-modified maleic anhydride-type unsaturated polyester, silicone-modified, urethane-modified or acrylic urethane-modified maleic anhydride-type unsaturated polyester, polyester having maleyl group therein, acrylic polymer having maleyl group therein, epoxide resin having maleyl group therein, acrylic polymer having acryloyl group as a side chain thereof, telomerized polyester acrylate, telomerized polyamide acrylate, epoxyacrylate, urethane acrylate, silicone acrylate, and reactive allyl group-containing resin, and then applying ionizing radiation to said first photoconductive layer, in a solvent-free state, until said radiation-curable resin has been cured; and a second photoconductive layer coated over said first photoconductive layer and having a thickness of from 3μ to 50μ, said second photoconductive layer consisting essentially of an organic second photoconductor and a resin binder therefor, said second photoconductive layer having been prepared by applying a liquid dispersion or solution of said organic second photoconductor and said resin binder in an organic solvent onto said first photoconductive layer having said cured resin therein and then evaporating the solvent.
Claim 3
Dependent Claim
35 words
An electrophotographic plate as claimed in claim 1 in which the thickness of said first photoconductive layer is from 0.5 to 3μ, and the thickness of said second photoconductive layer is from 6 to 20μ.
Claim 4
Dependent Claim
83 words
An electrophotographic plate as claimed in claim 1 in which said dispersion or solution applied for forming said first photoconductive layer also contains mixed therein at least one polymerizable monomer selected from the group consisting of styrene, methyl methacrylate, ethyl methacrylate, butyl methacrylate, dimethylaminoethyl methacrylate, tetrahydrofurfuryl methacrylate, butyl acrylate, 2-ethylhexyl acrylate and N-vinyl pyrrolidone, said first photoconductive layer consisting essentially of said first photoconductor and the reaction product obtained by applying ionizing radiation to the mixture of said radiation-curable resin and said monomer.
Claim 5
Dependent Claim
213 words
An electrophotographic plate, comprising: an electrically conductive substrate; a first photoconductive layer coated over said substrate and having a thickness of from 3μ to 50μ, said first photoconductive layer consisting essentially of an organic first photoconductor and a resin binder therefor; and a second photoconductive layer coated over said first photoconductive layer and having a thickness of from 0.1μ to 10μ, said second photoconductive layer consisting essentially of a mixture of an inorganic or organic second photoconductor and a resin that has been cured by ionizing radiation, said second photoconductive layer having been prepared by applying onto said first photoconductive layer a liquid dispersion or solution of said second photoconductor and from 0.2 to 50 percent by weight, based on the weight of said second photoconductor, of a radiation-curable resin selected from the group consisting of non-modified maleic anhydride-type unsaturated polyester, silicone-modified, urethane-modified or acrylic urethane-modified maleic anhydride-type unsaturated polyester, polyester having maleyl group therein, acrylic polymer having maleyl group therein, epoxide resin having maleyl group therein, acrylic polymer having acryloyl group as a side chain thereof, telomerized polyester acrylate, telomerized polyamide acrylate, epoxyacrylate, urethane acrylate, silicone acrylate, and reactive allyl group-containing resin and then applying ionizing radiation to said second photoconductive layer, in a solvent-free state, until said radiation-curable resin is cured.
Claim 6
Dependent Claim
213 words
An electrophotographic plate, comprising: an electrically conductive substrate; a first photoconductive layer coated over said substrate and having a thickness of from 3μ to 50μ, said first photoconductive layer consisting essentially of an organic first photoconductor and a resin binder therefor; and a second photoconductive layer coated over said first photoconductive layer and having a thickness of from 0.1μ to 10μ, said second photoconductive layer consisting essentially of a mixture of an inorganic or organic second photoconductor and a resin that has been cured by ionizing radiation, said second photoconductive layer having been prepared by applying onto said first photoconductive layer a liquid dispersion or solution of said second photoconductor and from 0.2 to 50 percent by weight, based on the weight of said second photoconductor, of a radiation-curable resin selected from the group consisting of non-modified maleic anhydride-type unsaturated polyester, silicone-modified, urethane-modified or acrylic urethane-modified maleic anhydride-type unsaturated polyester, polyester having maleyl group therein, acrylic polymer having maleyl group therein, epoxide resin having maleyl group therein, acrylic polymer having acryloyl group as a side chain thereof, telomerized polyester acrylate, telomerized polyamide acrylate, epoxyacrylate, urethane acrylate, silicone acrylate, and reactive allyl group-containing resin and then applying ionizing radiation to said second photoconductive layer, in a solvent-free state, until said radiation-curable resin is cured.
Claim 7
Dependent Claim
35 words
An electrophotographic plate as claimed in claim 4 in which the thickness of said second photoconductive layer is from 0.5 to 3μ, and the thickness of said first photoconductive layer is from 6 to 20μ.
Claim 8
Dependent Claim
83 words
An electrophotographic plate as claimed in claim 4 in which said dispersion or solution applied for forming said second photoconductive layer also contains mixed therein at least one polymerizable monomer selected from the group consisting of styrene, methyl methacrylate, ethyl methacrylate, butyl methacrylate, dimethylaminoethyl methacrylate, tetrahydrofurfuryl methacrylate, butyl acrylate, 2-ethylhexyl acrylate and N-vinyl pyrrolidone, said second photoconductive layer consisting essentially of said second photoconductor and the reaction product obtained by applying ionizing radiation to the mixture of said radiation-curable resin and said monomer.
Claim 9
Dependent Claim
170 words
An electrophotographic plate, comprising: an electrically conductive substrate; and a photoconductive layer coated over said substrate and having a thickness of from 3 to 80μ, said photoconductive layer consisting essentially of a mixture of an inorganic or organic photoconductor and a resin that has been cured by ionizing radiation, said photoconductive layer having been prepared by applying onto said substrate a liquid dispersion or solution of said photoconductor and from 0.2 to 50 percent by weight, based on the weight of said photoconductor, of a radiation-curable resin selected from the group consisting of non-modified maleic anhydride-type unsaturated polyester, silicone-modified, urethane-modified or acrylic urethane-modified maleic anhydride-type unsaturated polyester, polyester having maleyl group therein, acrylic polymer having maleyl group therein, epoxide resin having maleyl group therein, acrylic polymer having acryloyl group as a side chain thereof, telomerized polyester acrylate, telomerized polyamide acrylate, epoxyacrylate, urethane acrylate, silicone acrylate, and reactive allyl group-containing resin, and then applying ionizing radiation to said photoconductive layer, in a solvent-free state, until said radiation-curable resin has been cured.
Claim 10
Dependent Claim
170 words
An electrophotographic plate, comprising: an electrically conductive substrate; and a photoconductive layer coated over said substrate and having a thickness of from 3 to 80μ, said photoconductive layer consisting essentially of a mixture of an inorganic or organic photoconductor and a resin that has been cured by ionizing radiation, said photoconductive layer having been prepared by applying onto said substrate a liquid dispersion or solution of said photoconductor and from 0.2 to 50 percent by weight, based on the weight of said photoconductor, of a radiation-curable resin selected from the group consisting of non-modified maleic anhydride-type unsaturated polyester, silicone-modified, urethane-modified or acrylic urethane-modified maleic anhydride-type unsaturated polyester, polyester having maleyl group therein, acrylic polymer having maleyl group therein, epoxide resin having maleyl group therein, acrylic polymer having acryloyl group as a side chain thereof, telomerized polyester acrylate, telomerized polyamide acrylate, epoxyacrylate, urethane acrylate, silicone acrylate, and reactive allyl group-containing resin, and then applying ionizing radiation to said photoconductive layer, in a solvent-free state, until said radiation-curable resin has been cured.
Claim 11
Dependent Claim
79 words
An electrophotographic plate as claimed in claim 7 in which said dispersion or solution applied for forming said photoconductive layer also contains mixed therein at least one polymerizable monomer selected from the group consisting of styrene, methyl methacrylate, ethyl methacrylate, butyl methacrylate, dimethylaminoethyl methacrylate, tetrahydrofurfuryl methacrylate, butyl acrylate, 2-ethylhexyl acrylate and N-vinyl pyrrolidone, said layer consisting essentially of said photoconductor and the reaction product obtained by applying ionizing radiation to the mixture of said radiation-curable resin and said monomer.
Claim 12
Dependent Claim
30 words
An electrophotographic plate according to claim 7 in which said ionizing radiation is selected from the group consisting of accelerated electron beam, neutrons, α-rays, β-rays, γ-rays, X-rays, protons and deuterons.
Claim 13
Dependent Claim
71 words
An electrophotographic plate according to claim 9 in which said radiation-curable resin is selected from the group consisting of epoxide resin fumaric acid ester, urethanized fatty acid-modified unsaturated polyester resin, fatty acid modified saturated polyester resin, silicone modified maleic anhydride unsaturated polyester resin, copolymer of glycidyl methacrylate and methyl methacrylate mixed with propiolic acid and the reaction product of a copolymer of methyl methalcrylate and allyl glycidyl ether with allyl alcohol.
Claim 14
Dependent Claim
30 words
An electrophotographic plate according to claim 1 in which said ionizing radiation is selected from the group consisting of accelerated electron beam, neutrons, α-rays, β-rays, γ-rays, X-rays, protons and deuterons.
Claim 15
Dependent Claim
70 words
An electrophotographic plate according to claim 11 in which said resin is selected from the group consisting of epoxide resin fumaric acid ester, urethanized fatty acid-modified unsaturated polyester resin, fatty acid modified saturated polyester resin, silicone modified maleic anhydride unsaturated polyester resin, copolymer of glycidyl methacrylate and methyl methacrylate mixed with propiolic acid and the reaction product of a copolymer of methyl methacrylate and allyl glycidyl ether with allyl alcohol.
Claim 16
Dependent Claim
30 words
An electrophotographic plate according to claim 4 in which said ionizing radiation is selected from the group consisting of accelerated electron beam, neutrons, α-rays, β-rays, γ-rays, X-rays, protons and deuterons.
Claim 17
Dependent Claim
70 words
An electrophotographic plate according to claim 13 in which said resin is selected from the group consisting of epoxide resin fumaric acid ester, urethanized fatty acid-modified unsaturated polyester resin, fatty acid modified saturated polyester resin, silicone modified maleic anhydride unsaturated polyester resin, copolymer of glycidyl methacrylate and methyl methacrylate mixed with propiolic acid and the reaction product of a copolymer of methyl methacrylate and allyl glycidyl ether with allyl alcohol.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-10-19 | 1985-04-20 | 1985-10-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-10-19 | 1989-04-20 | 1989-10-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-10-19 | 1993-04-20 | 1993-10-20 | $7700.00 | Window Closed / Lapsed |