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US4296008A Expired / Lapsed US ⏱️ 0.0 years remaining

Sealant composition

Assignee: Shell USA Inc
•
Filing: 1980-04-21
•
Granted: 1981-10-20
•
Expires: 2000-04-21
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Abstract

Abstract A sealant composition possessing an excellent balance of properties including good tack, low melt viscosity and a cohesive failure mechanism in the 180° peel test comprises a selectively hydrogenated monoalkenyl arene/conjugated diene block copolymer component having certain block molecular weights, tackifying resin, plasticizers and silane coupling agent.

Inventors

  • 👤 David J. St. Clair
  • 👤 Earle E. Ewins, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 14:11
CPC Classifications
C; C09; C09J; C09J153/00; C09J153/02; C09J153/025; C08; C08L; C08L2666/00; C08L2666/02; C08L2666/28

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 185 words
A sealant composition possessing excellent oxidative and UV stability along with improved tack, reduced melt viscosity, and a cohesive failure mechanism in the 180° peel test comprises: (a) 100 parts by weight of a selectively hydrogenated block copolymer component comprising an A'B' block copolymer and a multiblock copolymer having at least two end blocks A and at least one mid block B wherein the A' and A blocks are monoalkenyl arene polymer blocks and the B' and B blocks are substantially completely hydrogenated conjugated diene polymer blocks, the number average molecular weight of the A' and A blocks are between about 3,000 and about 7,000, and the monoalkenyl arene content of the multiblock copolymer is between about 7% and about 22% by weight, wherein the weight ratio between the A' B' block copolymer and the multiblock copolymer is 20:80 to about 60:40; about 50 to about 350 parts by weight of a tackifying resin compatible with block B; (c) about 0 to about 100 parts by weight of a plasticizer; and (d) about 0.1 to about 10 parts by weight of a silane coupling agent.
Claim 2
Dependent Claim 185 words
A sealant composition possessing excellent oxidative and UV stability along with improved tack, reduced melt viscosity, and a cohesive failure mechanism in the 180° peel test comprises: (a) 100 parts by weight of a selectively hydrogenated block copolymer component comprising an A'B' block copolymer and a multiblock copolymer having at least two end blocks A and at least one mid block B wherein the A' and A blocks are monoalkenyl arene polymer blocks and the B' and B blocks are substantially completely hydrogenated conjugated diene polymer blocks, the number average molecular weight of the A' and A blocks are between about 3,000 and about 7,000, and the monoalkenyl arene content of the multiblock copolymer is between about 7% and about 22% by weight, wherein the weight ratio between the A' B' block copolymer and the multiblock copolymer is 20:80 to about 60:40; about 50 to about 350 parts by weight of a tackifying resin compatible with block B; (c) about 0 to about 100 parts by weight of a plasticizer; and (d) about 0.1 to about 10 parts by weight of a silane coupling agent.
Claim 3
Dependent Claim 18 words
A composition according to claim 1 wherein said monoalkenyl arene is styrene and said conjugated diene is butadiene.
Claim 4
Dependent Claim 18 words
A composition according to claim 1 wherein said multiblock copolymer is a selectively hydrogenated linear polystyrene-polybutadiene-polystyrene block copolymer.
Claim 5
Dependent Claim 18 words
A composition according to claim 3 wherein said A'B' block copolymer is a selectively hydrogenated polystyrene-polybutadiene block copolymer.
Claim 6
Dependent Claim 18 words
A composition according to claim 3 wherein said A'B' block copolymer is a selectively hydrogenated polystyrene-polyisoprene block copolymer.
Claim 7
Dependent Claim 17 words
A composition according to claim 1 wherein said multiblock copolymer is a selectively hydrogenated polystyrene-polyisoprene-polystyrene block copolymer.
Claim 8
Dependent Claim 22 words
A composition according to claim 2 wherein said butadiene block has a 1,2 configuration of between about 35 and 65 mol percent.
Claim 9
Dependent Claim 27 words
A translucent composition according to claim 1 wherein the amount of silane coupling agent is between about 0.25 parts by weight and about 2.5 parts by weight.

References Cited (Backward Citations)

US3239478A Cited
US3772237A Cited
US4102835A Cited
US3955036A Cited
US4003843A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-10-19 1985-04-20 1985-10-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-10-19 1989-04-20 1989-10-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-10-19 1993-04-20 1993-10-20 $7700.00 Window Closed / Lapsed

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