Patent US3431049A successfully refreshed from Google Patents.
US4101484A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Sealant based on thermoplastic elastomer and mixed modifying resins
Assignee: Phillips Petroleum Co
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Filing: 1976-10-04
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Granted: 1978-07-18
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Expires: 1996-10-04
Abstract
Abstract A sealant made up of (1) a block copolymer from at least one monovinyl-substituted aromatic compound and at least one conjugated diene, said block copolymer being a thermoplastic elastomer; (2) a poly(vinyl aromatic)-compatible component; and (3) a polydiene-compatible component; and (4) a filler.
Inventors
- 👤 Richard C. Doss
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 11:53
CPC Classifications
C; C08; C08L; C08L53/00; C08L53/02; C08K; C08K3/00; C08K3/01; C08K3/013; C08K5/00; C08L25/00; C08L25/02; C08L25/04; C08L25/06; C08L93/00; C08L93/04
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
200 words
A sealant composition which exhibits low surface tack after application comprising (1) a thermoplastic elastomer having the structure ABA or (AB) n Y, wherein A represents a block of a polymerized monovinyl-substituted aromatic compound, B represents a block of a polymerized conjugated diene, Y represents a residue of a polyfunctional coupling agent or a polyfunctional initiator, and n is an integer having a value of 2 to 4, said thermoplastic elastomer having a weight ratio of said monovinyl-substituted aromatic compound to said conjugated diene within the range of 50:50 to 5:95, said elastomer having the unsaturation normally associated with such polymers; (2) 10-15 parts by weight per 100 parts by weight of said thermoplastic elastomer of a poly(vinyl aromatic)-compatible modifying resin component which is an aromatic hydrocarbon; (3) 10-150 parts by weight per 100 parts by weight of said thermoplastic elastomer of a poly(conjugated diene)-compatible modifying resin component which is nonaromatic selected from normally solid modified and unmodified rosin and rosin esters of polyhydric alcohols, normally solid esters of polymerized rosin, polyterpene resins, and resinous polyolefins derived from aliphatic and cycloaliphatic olefins; and (4) 25-250 parts by weight per 100 parts by weight of said thermoplastic elastomer of a filler.
Claim 2
Dependent Claim
200 words
A sealant composition which exhibits low surface tack after application comprising (1) a thermoplastic elastomer having the structure ABA or (AB) n Y, wherein A represents a block of a polymerized monovinyl-substituted aromatic compound, B represents a block of a polymerized conjugated diene, Y represents a residue of a polyfunctional coupling agent or a polyfunctional initiator, and n is an integer having a value of 2 to 4, said thermoplastic elastomer having a weight ratio of said monovinyl-substituted aromatic compound to said conjugated diene within the range of 50:50 to 5:95, said elastomer having the unsaturation normally associated with such polymers; (2) 10-15 parts by weight per 100 parts by weight of said thermoplastic elastomer of a poly(vinyl aromatic)-compatible modifying resin component which is an aromatic hydrocarbon; (3) 10-150 parts by weight per 100 parts by weight of said thermoplastic elastomer of a poly(conjugated diene)-compatible modifying resin component which is nonaromatic selected from normally solid modified and unmodified rosin and rosin esters of polyhydric alcohols, normally solid esters of polymerized rosin, polyterpene resins, and resinous polyolefins derived from aliphatic and cycloaliphatic olefins; and (4) 25-250 parts by weight per 100 parts by weight of said thermoplastic elastomer of a filler.
Claim 3
Dependent Claim
20 words
A composition according to claim 1 wherein said monovinyl substituted aromatic compound is styrene and said conjugated diene is 1,3butadiend.
Claim 4
Dependent Claim
92 words
A composition according to claim 2 wherein said poly(vinyl aromatic)-compatible modifying resin is present in an amount within the range of 25 to 125 parts by weight per 100 parts by weight of said thermoplastic elastomer, said poly(conjugated diene)-compatible modifying resin is present in an amount within the range of 25 to 125 parts by weight per 100 parts by weight of said thermoplastic elastomer, and said filler is present in an amount within the range of 50 to 200 parts by weight per 100 parts by weight of said thermoplastic elastomer.
Claim 5
Dependent Claim
47 words
A composition according to claim 3 wherein said poly(vinyl aromatic)-compatible modifying resin is a vinyl toluene/α-methyl styrene copolymer and said poly(conjugated diene)-compatible modifying resin is selected from pentaerythritol ester of hydrogenated rosin, polymerized mixed olefins, polymerized olefins, polyterpene, mixed esters of polymerized rosin, and hydrocarbon-based polar resins.
Claim 6
Dependent Claim
10 words
A composition according to claim 4 dissolved in a solvent.
Claim 7
Dependent Claim
31 words
A composition according to claim 5 wherein the A/B weight ratio is within the range of 40/60 to 15/85, and wherein said composition contains in addition a plasticizer and a stabilizer.
Claim 8
Dependent Claim
17 words
A composition according to claim 6 wherein said poly(conjugated diene)-compatible component is pentaerythritol ester of hydrogenated rosin.
Claim 9
Dependent Claim
19 words
A composition according to claim 7 wherein said thermoplastic elastomer is a radial teleblock copolymer coupled with silicon tetrachloride.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-07-17 | 1982-01-16 | 1982-07-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-07-17 | 1986-01-16 | 1986-07-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-07-17 | 1990-01-16 | 1990-07-18 | $7700.00 | Window Closed / Lapsed |