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US4295002A Expired / Lapsed US ⏱️ 0.0 years remaining

Heterojunction V-groove multijunction solar cell

Assignee: International Business Machines Corp
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Filing: 1980-06-23
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Granted: 1981-10-13
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Expires: 2000-06-23
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Abstract

Abstract A solar cell is disclosed with V-grooves which are series connected, but electrically isolated, indirect bandgap solar cells which are responsive to different light frequencies on both sides of a semi-insulating optically transparent substrate. The device has a very high conversion efficiency of approximately 40% and high open-circuit voltage and low series resistance. An exemplary structure in accordance with this disclosure has a series of silicon V-groove cells on one side and another series of GaAlAs V-groove cells on the other side. The cells are of generally trapezoidal cross-section. The difference between the characteristics of the Si cell and the GaAlAs cell is matched by control of the number of V-grooves.

Inventors

  • 👤 Terry I. Chappell
  • 👤 Jerry M. Woodall

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 08:17
CPC Classifications
H; H10; H10F; H10F10/00; H10F10/10; H10F10/16; H10F10/161; H10F10/163; H10F10/164; H10F19/00; H10F19/10; H10F19/40; H10F77/00; H10F77/10; H10F77/14; H10F77/147; Y; Y02; Y02E; Y02E10/00; Y02E10/50; Y02E10/544

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 84 words
A solar energy converter comprising: a first solar cell comprising first multiple p-n heterojunctions in association with a first type of optically active semiconductor material on one side of an insulating substrate; and a second solar cell comprising second multiple p-n heterojunctions in association with a second type of optically active semiconductor material on the opposite side of the insulating substrate; said first type of semiconductor material is GaAlAs, said second type of semiconductor material is Si, and said insulating substrate is semi-insulating GaP.
Claim 2
Dependent Claim 84 words
A solar energy converter comprising: a first solar cell comprising first multiple p-n heterojunctions in association with a first type of optically active semiconductor material on one side of an insulating substrate; and a second solar cell comprising second multiple p-n heterojunctions in association with a second type of optically active semiconductor material on the opposite side of the insulating substrate; said first type of semiconductor material is GaAlAs, said second type of semiconductor material is Si, and said insulating substrate is semi-insulating GaP.
Claim 3
Dependent Claim 246 words
A solar energy converter comprising: a first solar cell comprising first multiple p-n heterojunctions in association with a first type of optically active semiconductor material A on one side of an insulating substrate; and a second solar cell comprising second multiple p-n heterojunctions in association with a second type of optically active semiconductor material B on the opposite side of the insulating substrate; wherein said material A has an indirect bandgap and carrier lifetime limited by Auger recombination, one side of A has a heterojunction with a material A n ' which is doped to n+ type conductivity, has a larger bandgap than A, and is lattice matched to A, the other side of A has a heterojunction with a material A p ' doped to p-type conductivity, and has a larger bandgap than A, and is lattice matched to A; wherein said insulating substrate comprises an insulation layer adjacent to A p ' whose bandgap is greater than or equal to the bandgap of said A material and whose interfaces between said first and second cells are atomically compatible; and wherein said material B has an indirect bandgap less than material A and carrier lifetime limited by Auger recombination, one side of B has a heterojunction with a material B n ' doped to n-type conductivity and lattice matched with B, and the other side of B has a heterojunction with a material B p ' doped to p-type conductivity and lattice matched with B.
Claim 4
Dependent Claim 246 words
A solar energy converter comprising: a first solar cell comprising first multiple p-n heterojunctions in association with a first type of optically active semiconductor material A on one side of an insulating substrate; and a second solar cell comprising second multiple p-n heterojunctions in association with a second type of optically active semiconductor material B on the opposite side of the insulating substrate; wherein said material A has an indirect bandgap and carrier lifetime limited by Auger recombination, one side of A has a heterojunction with a material A n ' which is doped to n+ type conductivity, has a larger bandgap than A, and is lattice matched to A, the other side of A has a heterojunction with a material A p ' doped to p-type conductivity, and has a larger bandgap than A, and is lattice matched to A; wherein said insulating substrate comprises an insulation layer adjacent to A p ' whose bandgap is greater than or equal to the bandgap of said A material and whose interfaces between said first and second cells are atomically compatible; and wherein said material B has an indirect bandgap less than material A and carrier lifetime limited by Auger recombination, one side of B has a heterojunction with a material B n ' doped to n-type conductivity and lattice matched with B, and the other side of B has a heterojunction with a material B p ' doped to p-type conductivity and lattice matched with B.
Claim 5
Dependent Claim 85 words
A solar energy converter as set forth in claim 2 wherein: said first material A is Ga 1-x Al x As, A'n is n-Ga 1-y Al y As, A'p is p-Ga 1-y Al 1-y As, said second material B is Si, one side of B has a heterojunction with material B n ' which is n-GaP and is lattice matched with B and the other side of B has a heterojunction with material B p ' which is p-GaP and is lattice matched with B.
Claim 6
Dependent Claim 49 words
A solar energy converter as set forth in claim 3 wherein: said first material A has an indirect bandgap lying lower in energy than its direct bandgap, thereby having a high carrier lifetime and also having high optical absorption of photons slightly greater in energy than said indirect bandgap.
Claim 7
Dependent Claim 32 words
A solar energy converter as set forth in claim 4 wherein said material A is a ternary semiconductor material compound of an indirect bandgap semiconductor material and a direct bandgap semiconductor material.
Claim 8
Dependent Claim 21 words
A solar energy converter as set forth in claim 5 wherein said material A is a group III-V ternary semiconductor material.
Claim 9
Dependent Claim 26 words
A solar energy converter as set forth in claim 6 wherein said first material A is Ga 1-x Al x As and x is approximately 0.5.
Claim 10
Dependent Claim 22 words
A solar energy converter as set forth in claim 6 wherein A is Ga 1-x Al x As and x is 0.4≦×≦0.6.
Claim 11
Dependent Claim 168 words
A solar energy converter comprising: a region of a first semiconductor material, which is responsive to light of a first frequency, having indirect bandgap and being carrier lifetime limited by Auger recombination, and having a first quantity of p-n heterojunctions with semiconductor material which has a larger bandgap than said first material and is lattice matched thereto. a region of a second semiconductor material, which is responsive to light of a second frequency, having indirect bandgap and being carrier lifetime limited by Auger combination and having a second quantity of p-n heterojunctions with a semiconductor material which has a larger bandgap than said second material and is lattice matched thereto, said first quantity of junctions and second quantity of junctions being operable to provide comparable electrical characteristics from the p-n heterojunctions in said first and said second semiconductor materials, said first and second regions being conterminous with and separated by a substrate having electrical isolation properties and being optically transparent at least to light of said second frequency.
Claim 12
Dependent Claim 168 words
A solar energy converter comprising: a region of a first semiconductor material, which is responsive to light of a first frequency, having indirect bandgap and being carrier lifetime limited by Auger recombination, and having a first quantity of p-n heterojunctions with semiconductor material which has a larger bandgap than said first material and is lattice matched thereto. a region of a second semiconductor material, which is responsive to light of a second frequency, having indirect bandgap and being carrier lifetime limited by Auger combination and having a second quantity of p-n heterojunctions with a semiconductor material which has a larger bandgap than said second material and is lattice matched thereto, said first quantity of junctions and second quantity of junctions being operable to provide comparable electrical characteristics from the p-n heterojunctions in said first and said second semiconductor materials, said first and second regions being conterminous with and separated by a substrate having electrical isolation properties and being optically transparent at least to light of said second frequency.
Claim 13
Dependent Claim 83 words
A solar energy converter having a first material A having indirect bandgap and carrier lifetime limited by Auger recombination, one side of A has a heterojunction with a material A n ' which is doped to n+ type conductivity, has a larger bandgap than A, and is lattice matched to A, the other side of A has a heterojunction with a material A p ' which is doped to p-type conductivity, has a larger bandgap than A, and is lattice matched to A.
Claim 14
Dependent Claim 83 words
A solar energy converter having a first material A having indirect bandgap and carrier lifetime limited by Auger recombination, one side of A has a heterojunction with a material A n ' which is doped to n+ type conductivity, has a larger bandgap than A, and is lattice matched to A, the other side of A has a heterojunction with a material A p ' which is doped to p-type conductivity, has a larger bandgap than A, and is lattice matched to A.
Claim 15
Dependent Claim 50 words
A solar energy converter as set forth in claim 10 wherein said first material A has an indirect bandgap lying lower in energy than its direct bandgap thereby having a high carrier lifetime and also having high optical absorption of photons just slightly greater in energy than said indirect bandgap.
Claim 16
Dependent Claim 33 words
A solar energy converter as set forth in claim 11 wherein said material A is a ternary semiconductor material compound comprised of an indirect bandgap semiconductor material and a direct bandgap semiconductor material.
Claim 17
Dependent Claim 21 words
A solar energy converter as set forth in claim 12 wherein said material A is a group III-V ternary semiconductor material.
Claim 18
Dependent Claim 26 words
A solar energy converter as set forth in claim 13 wherein said first material A is Ga 1-x Al x As and x is approximately 0.5.
Claim 19
Dependent Claim 22 words
A solar energy converter as set forth in claim 13 wherein A is Ga 1-x Al x As and x is 0.4≦×≦0.6.
Claim 20
Dependent Claim 72 words
A solar energy converter having a semiconductor material A with indirect bandgap and carrier lifetime limited by Auger recombination, one side of A has a heterojunction with semiconductor material A n doped to n-type conductivity and another side of A has a heterojunction with a semiconductor material A p which is doped to p-type conductivity, said material A n and said material A p having a larger bandgap than said material A.
Claim 21
Dependent Claim 72 words
A solar energy converter having a semiconductor material A with indirect bandgap and carrier lifetime limited by Auger recombination, one side of A has a heterojunction with semiconductor material A n doped to n-type conductivity and another side of A has a heterojunction with a semiconductor material A p which is doped to p-type conductivity, said material A n and said material A p having a larger bandgap than said material A.
Claim 22
Dependent Claim 42 words
A solar energy converter as set forth in claim 16 wherein: said semiconductor material A is silicon, said semiconductor material A n is gallium phosphide doped to n-type conductivity, and said semiconductor material A p is gallium phosphide doped to p-type conductivity.

References Cited (Backward Citations)

US4017332A Cited
US3995303A Cited
US3990101A Cited
US4094704A Cited
US4200472A Cited
US4158577A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-10-12 1985-04-13 1985-10-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-10-12 1989-04-13 1989-10-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-10-12 1993-04-13 1993-10-13 $7700.00 Window Closed / Lapsed

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