Process for preparing polyarylates

Claim 2

A process for preparing polyarylate having a reduced viscosity of from about 0.5 to greater than 1.0 dl/gm and improved color which process comprises reacting, at a temperature of from about 260° to about 350° C.: (a) at least one diester derivative of a dihydric phenol having the following formula: ##STR7## wherein R is independently selected from an alkyl radical having from 1 to about 6 carbon atoms or cycloalkyl having from 4 to about 7 carbon atoms, y is independently selected from alkyl groups of 1 to 4 carbon atoms, chlorine, or bromine, z independently has a value of from 0 to 4, inclusive, and R' is independently selected from a divalent saturated aliphatic hydrocarbon radical having 1 to 8 carbon atoms, a cycloalkylene, or cycloalkylidene radical having up to and including 9 carbon atoms, O, S, SO, SO 2 , CO, x is 0 or 1; with (b) at least one aromatic dicarboxylic acid, in the presence of from about 10 to about 60 weight percent, based on the polyarylate produced, of at least one cycloaliphatic, substituted aromatic or heteroaromatic compound, which compounds contain at least one benzylic and/or tertiary hydrogen atom, and have a boiling point of about 150° to about 350° C. at atmospheric pressure.

Claim 3

A process as defined in claim 1 wherein the diester derivative of a dihydric phenol has the following formula: ##STR8##

Claim 4

A process as defined in claim 2 wherein each z is 0.

Claim 5

A process as defined in claim 1 wherein the aromatic dicarboxylic acid is a mixture of isophthalic acid and terephthalic acid.

Claim 6

A process as defined in claim 4 wherein the isophthalic acid to terephthalic acid ratio in the mixture is about 25:75 to about 100:0.

Claim 7

A process as defined in claim 1 wherein the temperature is between about 275° to about 295° C.

Claim 8

A process as defined in claim 1 wherein the cycloaliphatic compound is of the following formulae: ##STR9## wherein R 1 is independently alkyl of 1 to 6 carbon atoms, cycloalkyl of 6 to 18 carbon atoms, and a is an integer of 1 or 2.

Claim 9

A process as defined in claim 1 wherein the substituted aromatic compound is of the following formulae: ##STR10## wherein R 2 is independently alkyl of 1 to 6 carbon atoms, cycloalkyl of 6 to 18 carbon atoms and aralkyl or alkaryl of 7 to 18 carbon atoms and wherein the carbon atom of R 2 attached directly to the benzene nucleus has 1 or 2 attached hydrogen atoms, and b is an integer of 1 to 6; ##STR11## wherein R 3 is independently alkyl of 1 to 6 carbon atoms, cycloalkyl of 6 to 18 carbon atoms, c is an integer of 1 or 2, and n is an integer of 1 to 6.

Claim 10

A process as defined in claim 8 wherein the substituted aromatic compound is selected from xylene, cumene, diethylbenzene, diisopropyl benzene, tetrahydronaphthalene, or decahydronaphthalene.

Claim 11

A process as defined in claim 1 wherein the heteroaromatic compound is of the following formula: ##STR12## wherein A is S, O, or --CH═N--, R 4 is independently alkyl of 1 to 6 carbon atoms, or cycloalkyl of 6 to 18 carbon atoms wherein the carbon atom of R 4 attached directly to the heteroaromatic nucleus has 1 or 2 attached hydrogen atoms, and d is an integer of 1 or 2.

Claim 12

A process as defined in claim 1 wherein the polyarylate has a reduced viscosity of from about 0.6 to about 0.8.

Claim 13

A process as defined in claim 1 wherein the cycloaliphatic, substituted aromatic or heteroaromatic compound is present in an amount of from about 25 to about 40 weight percent.

Claim 14

A process for preparing a polyarylate having a reduced viscosity of from about 0.5 to greater than 1.0 dl/gm which process comprises reacting at a temperature of from about 260° to about 350° C.: (a) an acid anhydride based on an acid containing from 2 to 8 carbon atoms; (b) at least one dihydric phenol having the following formula: ##STR13## wherein y is independently selected from alkyl groups of 1 to 4 carbon atoms, chlorine or bromine, z independently has a value of from 0 to 4, inclusive, R' is independently selected from a divalent saturated hydrocarbon radical having 1 to 8 carbon atoms, a cycloalkylene or cycloalkylidene radical having up to and including 9 carbon atoms, O, S, SO, SO 2 , Co, x is 0 or 1; and (c) at least one aromatic dicarboxylic acid, in the presence of from about 10 to about 60 weight percent, based on the polyarylate produced, of at least one cycloaliphatic, substituted aromatic or heteroaromatic compound, which compounds contain at least one benzylic and/or tertiary hydrogen, and have a boiling point of about 150° to about 350° C. at atmospheric pressure.

Claim 15

A process for preparing a polyarylate having a reduced viscosity of from about 0.5 to greater than 1.0 dl/gm which process comprises reacting at a temperature of from about 260° to about 350° C.: (a) an acid anhydride based on an acid containing from 2 to 8 carbon atoms; (b) at least one dihydric phenol having the following formula: ##STR13## wherein y is independently selected from alkyl groups of 1 to 4 carbon atoms, chlorine or bromine, z independently has a value of from 0 to 4, inclusive, R' is independently selected from a divalent saturated hydrocarbon radical having 1 to 8 carbon atoms, a cycloalkylene or cycloalkylidene radical having up to and including 9 carbon atoms, O, S, SO, SO 2 , Co, x is 0 or 1; and (c) at least one aromatic dicarboxylic acid, in the presence of from about 10 to about 60 weight percent, based on the polyarylate produced, of at least one cycloaliphatic, substituted aromatic or heteroaromatic compound, which compounds contain at least one benzylic and/or tertiary hydrogen, and have a boiling point of about 150° to about 350° C. at atmospheric pressure.

Claim 16

A process for preparing a polyarylate having a reduced viscosity of from about 0.5 to greater than 1.0 dl/gm, which process comprises the following steps: I. forming a polyarylate prepolymer having a reduced viscosity of from about 0.1 to about 0.4 dl/gm, by reacting: (a) at least one diester derivative of a dihydric phenol having the following formula: ##STR14## wherein R is independently an alkyl radical having from 1 to about 6 carbon atoms, or cycloalkyl having from 4 to about 7 carbon atoms, y is independently selected from alkyl groups of 1 to 4 carbon atoms, chlorine, or bromine, z independently has a value of from 0 to 4, inclusive, and R' is independently selected from a divalent saturated aliphatic hydrocarbon radical having 1 to 8 carbon atoms, a cycloalkylene, or cycloalkylidene radical having up to and including 9 carbon atoms, O, S, SO, SO 2 , CO, x is 0 or 1; with (b) at least one aromatic dicarboxylic acid, in the presence of from about 10 to about 60 weight percent, based on the polyarylate produced, of at least one cycloaliphatic, substituted aromatic or heteroaromatic compound, which compounds contain at least one benzylic and/or tertiary hydrogen, and have a boiling point of about 150° to about 350° C. at atmospheric pressure. II. Heating the prepolymer so formed at a temperature of from about 300° to 350° C. for a period of time sufficient to form a polyarylate having a reduced viscosity of from about 0.5 to greater than 1.0 dl/g.

Claim 17

A process for preparing a polyarylate having a reduced viscosity of from about 0.5 to greater than 1.0 dl/gm, which process comprises the following steps: I. forming a polyarylate prepolymer having a reduced viscosity of from about 0.1 to about 0.4 dl/gm, by reacting: (a) at least one diester derivative of a dihydric phenol having the following formula: ##STR14## wherein R is independently an alkyl radical having from 1 to about 6 carbon atoms, or cycloalkyl having from 4 to about 7 carbon atoms, y is independently selected from alkyl groups of 1 to 4 carbon atoms, chlorine, or bromine, z independently has a value of from 0 to 4, inclusive, and R' is independently selected from a divalent saturated aliphatic hydrocarbon radical having 1 to 8 carbon atoms, a cycloalkylene, or cycloalkylidene radical having up to and including 9 carbon atoms, O, S, SO, SO 2 , CO, x is 0 or 1; with (b) at least one aromatic dicarboxylic acid, in the presence of from about 10 to about 60 weight percent, based on the polyarylate produced, of at least one cycloaliphatic, substituted aromatic or heteroaromatic compound, which compounds contain at least one benzylic and/or tertiary hydrogen, and have a boiling point of about 150° to about 350° C. at atmospheric pressure. II. Heating the prepolymer so formed at a temperature of from about 300° to 350° C. for a period of time sufficient to form a polyarylate having a reduced viscosity of from about 0.5 to greater than 1.0 dl/g.

Claim 18

A process as defined in claim 14 wherein the prepolymer is heated in step (II) in a vented extruder under vacuum.