Patent US4294939A successfully refreshed from Google Patents.
US4294939A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Coating composition
Assignee: Toray Industries Inc
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Filing: 1980-09-11
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Granted: 1981-10-13
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Expires: 2000-09-11
Abstract
Abstract Coating composition comprising (I) cross-linkable basic acrylic component, in which there are present, in polymerized form, (a) 2 to 10(A)% of at least one dialkylaminoalkyl acrylate, (b) 0.5 to 5(B)% of at least one acrylic amide, (c) 0.5 to 20(C)% of at least one hydroxyalkyl acrylate, (d) 35 to 95% of at least one alkyl acrylate, and (e) 0 to 50% of one or more other monomers, wherein the percentages A, B and C satisfy the relation: <IMAGE> and (II) cross-linking polyepoxide component having an epoxy equivalent of 400 or less, the ratio by gram atom of the basic nitrogen in (I) to the epoxy oxygen in (II) being from 0.3 to 3.0.
Inventors
- 👤 Eiji Taniguchi
- 👤 Susumu Akagi
- 👤 Seiichi Torimitsu
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 12:25
CPC Classifications
C; C09; C09D; C09D133/00; C09D133/04; C09D133/06; C09D133/062; C09D133/066; C08; C08L; C08L63/00
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
263 words
An organic solvent-based coating composition comprising: (I) a water-insoluble polymeric cross-linkable basic nitrogen atom-containing acrylic component comprising at least one film-forming acrylic copolymer containing basic nitrogen atoms, in which component there are present, based on the weight of said component: (a) 2 to 10% by weight of polymerized units derived from at least one basic nitrogen atom-containing acrylate selected from the group consisting of di(C 1-2 alkyl)amino C 1-3 alkyl acrylates and methacrylates, (b) 0.5 to 5% (B%) by weight of polymerized units derived from at least one acrylic amide selected from the group consisting of acrylamide and methacrylamide, (c) 0.5 to 20% (C%) by weight of polymerized units derived from at least one hydroxyl-containing acrylic monomer selected from the group consisting of hydroxy C 2-4 alkyl acrylates and methacrylates, (d) 35 to 95% by weight of polymerized units derived from at least one alkyl acrylate selected from the group consisting of C 1-4 alkyl acrylates and methacrylates, and (e) 0 to 50% by weight of polymerized units derived from one or more other copolymerizable ethylenically unsaturated monomers, said percentages A, B and C satisfying the relation: ##EQU5## (II) a cross-linking component comprising at least one polyepoxide compound having an epoxy equivalent of not more than 400 and containing at least two epoxy groups per molecule, said cross-linkable component (I) and cross-linking component (II) being present in said composition so that the ratio by gram atom of the basic nitrogen atom in said component (I) to the epoxy oxygen atom in said component (II) falls within the range of between 0.3 and 3.0.
Claim 2
Dependent Claim
263 words
An organic solvent-based coating composition comprising: (I) a water-insoluble polymeric cross-linkable basic nitrogen atom-containing acrylic component comprising at least one film-forming acrylic copolymer containing basic nitrogen atoms, in which component there are present, based on the weight of said component: (a) 2 to 10% by weight of polymerized units derived from at least one basic nitrogen atom-containing acrylate selected from the group consisting of di(C 1-2 alkyl)amino C 1-3 alkyl acrylates and methacrylates, (b) 0.5 to 5% (B%) by weight of polymerized units derived from at least one acrylic amide selected from the group consisting of acrylamide and methacrylamide, (c) 0.5 to 20% (C%) by weight of polymerized units derived from at least one hydroxyl-containing acrylic monomer selected from the group consisting of hydroxy C 2-4 alkyl acrylates and methacrylates, (d) 35 to 95% by weight of polymerized units derived from at least one alkyl acrylate selected from the group consisting of C 1-4 alkyl acrylates and methacrylates, and (e) 0 to 50% by weight of polymerized units derived from one or more other copolymerizable ethylenically unsaturated monomers, said percentages A, B and C satisfying the relation: ##EQU5## (II) a cross-linking component comprising at least one polyepoxide compound having an epoxy equivalent of not more than 400 and containing at least two epoxy groups per molecule, said cross-linkable component (I) and cross-linking component (II) being present in said composition so that the ratio by gram atom of the basic nitrogen atom in said component (I) to the epoxy oxygen atom in said component (II) falls within the range of between 0.3 and 3.0.
Claim 3
Dependent Claim
21 words
A coating composition in accordance with claim 1 wherein said polyepoxide compound has an epoxy equivalent of not more than 250.
Claim 4
Dependent Claim
40 words
A coating composition in accordance with claim 2 wherein said polyepoxide compound is a glycidyl ether of a polyhydric alcohol selected from the group consisting of ethylene glycol diglycidyl ether, glycerol polyglycidyl ethers, polyglycerol polyglycidyl ethers and sorbitol polyglycidyl ethers.
Claim 5
Dependent Claim
60 words
A coating composition in accordance with any one of the preceding claims wherein said cross-linkable component (I) and cross-linking component (II) are present in said composition such that the ratio by gram atom of the basic nitrogen atom in said component (I) to the epoxy oxygen atom in said component (II) falls within the range of between 0.5 and 1.5.
References Cited (Backward Citations)
US3488249A
Cited
US3509086A
Cited
US3786113A
Cited
US3939114A
Cited
US3943187A
Cited
US4006200A
Cited
US4065518A
Cited
US4129610A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-10-12 | 1985-04-13 | 1985-10-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-10-12 | 1989-04-13 | 1989-10-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-10-12 | 1993-04-13 | 1993-10-13 | $7700.00 | Window Closed / Lapsed |