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US4294892A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for the operation of a fuel cell

Assignee: Electrochemische Energieconversie NV
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Filing: 1980-05-01
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Granted: 1981-10-13
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Expires: 2000-05-01
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Abstract

Abstract An improved method for operating a fuel cell employing porous gas diffusion electrodes. The method provides for the regeneration of the electrode by keeping the oxidizing or reducing gas temporarily at a reduced concentration level while substantially maintaining the pressure on the gas in situ of the electrode and while continuing power offtake at least for the period during which the concentration level is reduced.

Inventors

  • 👤 Marinus Alfenaar

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 23:15
CPC Classifications
H; H01; H01M; H01M8/00; H01M8/04; H01M8/04223; H01M8/04238; H01M8/04298; H01M8/043; H01M8/04303; H01M8/02; H01M8/0202; H01M8/0258; H01M8/04228; Y; Y02; Y02E; Y02E60/00; Y02E60/30; Y02E60/50

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 102 words
A method for operating a fuel cell with a porous gas diffusion electrode to which an oxidizing or reducing gas is fed, wherein the concentration level of the oxidizing or reducing gas, calculated as molecular oxygen or hydrogen respectively, in the gas phase in situ of the electrode in question is temporarily brought to a reduced level the terminal voltage being reduced to below 10% of its original value, the overall pressure of the gas phase in situ of this electrode being substantially maintained and the power offtake is continued for at least the period during which the concentration level is reduced.
Claim 2
Independent Claim 102 words
A method for operating a fuel cell with a porous gas diffusion electrode to which an oxidizing or reducing gas is fed, wherein the concentration level of the oxidizing or reducing gas, calculated as molecular oxygen or hydrogen respectively, in the gas phase in situ of the electrode in question is temporarily brought to a reduced level the terminal voltage being reduced to below 10% of its original value, the overall pressure of the gas phase in situ of this electrode being substantially maintained and the power offtake is continued for at least the period during which the concentration level is reduced.
Claim 3
Dependent Claim 47 words
A method according to claim 1 wherein the porous gas diffusion electrode is regularly regenerated by maintaining the concentration of the oxidizing or reducing gas in the gas phase in situ of the electrode at given intervals and for a given time at the said reduced level.
Claim 4
Dependent Claim 37 words
A method according to claim 2 wherein during operation of the fuel cell the step of reducing the concentration level occurs for a period of time ranging from about 1 to about 30 minutes every 10-200 hours.
Claim 5
Dependent Claim 13 words
A method according to claim 1 wherein the fuel cell becomes shut down.
Claim 6
Independent Claim 50 words
A method according to any of claims 1-4 wherein the concentration of the oxidizing or reducing gas in the gas phase in situ of the said electrode is decreased by replacing the normal feed gas by a feed gas with a reduced concentration level of the oxidizing or reducing gas.
Claim 7
Dependent Claim 27 words
A method according to claim 5 wherein the feed gas having the reduced concentration level is a gas that is inert under the conditions of the reaction.
Claim 8
Dependent Claim 12 words
A method according to claim 6 wherein the inert gas is nitrogen.
Claim 9
Independent Claim 52 words
A method according to any of claims 1-3 wherein the resistance of the gas discharge line on the cathode or anode side of the fuel cell is increased without at least proportionally increasing the resistance of the gas feed line in question, the composition of the gas feed not substantially being changed.
Claim 10
Independent Claim 48 words
A method according to any of claims 1, 2 or 3, wherein the electrode is comprised of a flat gas diffusion electrode including at least a catalytically active layer containing a catalytically active metal, carbon and a polymeric bonding agent and is porous to gas and the electrolyte.
Claim 11
Dependent Claim 20 words
A method according to claim 1 where operation is as a gas diffusion cathode wherein the oxidizing gas comprises oxygen.
Claim 12
Dependent Claim 15 words
A method according to claim 10 wherein air is employed as the normal feed gas.
Claim 13
Dependent Claim 21 words
A method according to claim 1 wherein the operation is as a gas diffusion anode with the reducing gas comprising hydrogen.

References Cited (Backward Citations)

US3395046A Cited
US3395045A Cited
US3379572A Cited
GB1215630A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-10-12 1985-04-13 1985-10-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-10-12 1989-04-13 1989-10-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-10-12 1993-04-13 1993-10-13 $7700.00 Window Closed / Lapsed

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