Abstract A method for producing coated, molded, fiber-reinforced thermoset plastic articles having an adherent coating in heated matched metal molds. The coating composition includes (A) a blocked polyisocyanate which is the reaction product, essentially free of unreacted --NCO radicals, of e-caprolactam and organic polyisocyanate; (B) a polyepoxide-polyacrylate which is the reaction product, essentially free of unreacted epoxy radicals of a polyepoxide and acrylic or methacrylic acid; (C) ethylenically unsaturated polyester resin; (D) copolymerizable alpha-beta ethylenically unsaturated monomer; (E) an initiator for addition polymerization; (F) a catalyst for the reaction of --NCO radicals and --OH radicals; (G) filters, such as inert particulate filled, pigments, mold release agents. The coating composition is applied in the matched metal mold after a fiber-reinforced thermoset plastic article has been shaped within the mold. The coating composition is applied by opening the mold and introducing the described coating composition, thereafter closing the mold and retaining the mold in the closed condition until the plastic article is further cured and the described coating composition is cured.
A storage stable composition for the in-mold coating of a molded, fiber-reinforced thermoset plastic article comprising a resin system including (A) a blocked polyisocyanate which is the reaction product, essentially free of unreacted -NCO radicals, of e-caprolactam and organic polyisocyanate; (B) a polyepoxide-polyacrylate which is the reaction product, essentially free of unreacted epoxy radicals of a polyepoxide and acrylic or methacrylic acid; (C) ethylenically unsaturated polyester resin; (D) copolymerizable alpha-beta ethylenically unsaturated monomer; wherein the said ethylenically unsaturated polyester resin and the said copolymerizable alpha-beta ethylenically unsaturated monomer comprise more than 50 weight percent of the said resin system and the said blocked isocyanate is present in sufficient quantity that the ratio of NCO/OH radicals in the resin system after unblocking of the said blocked polyisocyanate is from 0.2 to 0.8; said composition also including an initiator for addition polymerization; a catalyst for the reaction of --NCO radicals and --OH radicals; and fillers.
Claim 2
Dependent Claim
153 words
A storage stable composition for the in-mold coating of a molded, fiber-reinforced thermoset plastic article comprising a resin system including (A) a blocked polyisocyanate which is the reaction product, essentially free of unreacted -NCO radicals, of e-caprolactam and organic polyisocyanate; (B) a polyepoxide-polyacrylate which is the reaction product, essentially free of unreacted epoxy radicals of a polyepoxide and acrylic or methacrylic acid; (C) ethylenically unsaturated polyester resin; (D) copolymerizable alpha-beta ethylenically unsaturated monomer; wherein the said ethylenically unsaturated polyester resin and the said copolymerizable alpha-beta ethylenically unsaturated monomer comprise more than 50 weight percent of the said resin system and the said blocked isocyanate is present in sufficient quantity that the ratio of NCO/OH radicals in the resin system after unblocking of the said blocked polyisocyanate is from 0.2 to 0.8; said composition also including an initiator for addition polymerization; a catalyst for the reaction of --NCO radicals and --OH radicals; and fillers.